Yeni Bor İçerikli Aromatik Ditiyofosfonato Nikel(II) Kompleksi: Sentez ve Yapı Aydınlatılması

Öz

Bilinen bir trans-[O-1-fenil-1-propil-(4-metoksifenil)ditiyofosfonato] nikel(II) dört koordinasyonlu kompleksinin difenilfosfino etanla (dppe), kovalent yapıdaki kompleksi sentezlendi ([(dppe)Ni(L)]). [(dppe)Ni(L)] ara ürünün, tetrafenilborat anyonuyla iyonik yapıda, yeni bor içerikli aromatik ditiyofosfonato Ni(II) kompleksi sentezlendi ([(dppe)Ni(L)]+[BPh4]-). Yeni kompleksin yapısı element analizi, FTIR ve 31P NMR analiz yöntemleriyle açıklandı.

Anahtar Kelimeler

• Ditiyofosfonik asitler
• Fosfonoditiyoato Ni(II) kompleksleri
• Bor Kompleksleri
• Fosfin Ligandları

Destekleyen Kurum

TÜBİTAK

Proje Numarası

TÜBİTAK 2209-A

Etik Beyan

Etik kurul onayına gerek yoktur.

Teşekkür

“Üniversite Öğrencileri Araştırma Projeleri Destekleme Programı” kapsamında finansal destekte bulunan, “TÜBİTAK 2209-A” projesine teşekkür ederler.

New Boron-containing Aromatic Dithiophosphonato Nickel(II) Complex: Synthesis and Structure Elucidation

Öz

Trans-[O-1-phenyl-1-propyl-(4-methoxyphenyl)dithiophosphonato] nickel(II) four-coordination complex which is known previously with diphenylphosphino ethane (dppe) was synthesised ([(dppe)Ni(L)], covalent structure). A new boron-containing aromatic dithiophosphonato Ni(II) complex of the [(dppe)Ni(L)] intermediate product with tetraphenylborate anion was synthesised ([(dppe)Ni(L)]+[BPh4]-) as ionic form. The structure of the new complex was elucidated by elemental analysis, FTIR and 31P NMR analysis methods.

Anahtar Kelimeler

• Dithiophosphonic acids
• Phosphonodithioato Ni(II) complexes
• Boron Complexes
• Phosphine Ligands

Destekleyen Kurum

TÜBİTAK

Proje Numarası

TÜBİTAK 2209-A

Etik Beyan

Ethics committee approval is not required.

Teşekkür

They would like to express their gratitude to the "TUBITAK 2209-A" project, which received financial support under the "University Students Research Projects Support Program".

Kaynakça

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