Yıl 2014, Cilt 15 , Sayı 2, Sayfalar 137 - 146 2015-05-05

SULFONATED POLY(ARYLENE ETHER BENZIMIDAZOLE) COPOLYMER MEMBRANE SYNTHESIS AND CHARACTERIZATION
SULFONATED POLY(ARYLENE ETHER BENZIMIDAZOLE) COPOLYMER MEMBRANE SYNTHESIS AND CHARACTERIZATION

Çağla TOSUN [1] , Özgül GERÇEL [2] , Emre URAZ [3] , Hasan GERÇEL [4]


Fuel cells which are utilized to produce electrical energy from hydrogen are accepted as an alternative of environmentally friendly and efficient energy production. Perflorosulfonic acid based membranes such as Nafion, are used frequently in polymer electrolyte membrane fuel cells (PEMFCs). However researches on alternative polymer electrolyte membranes (PEMs) are continued because of decrement in proton conductivity at high temperatures and high prices of Nafion membranes. At the first stage of this study, disodium-3,3'-disulfonate-4,4'-dichlorodiphenylsulfone (S-DCDPS) and benzimidazole bisphenol (HPBI) monomers were synthesized. Then a sulfonated poly(arylene ether benzimidazole) copolymer was synthesized via nucleophilic aromatic polycondensation reaction of synthesized monomers. 1H NMR and FTIR analysis of synthesized monomers and 1H NMR, FTIR and thermogravimetric analysis (TGA) of the copolymer were performed. Copolymer synthesis was confirmed clearly by the results of the analysis. TGA curve showed that synthesized copolymer has a high thermal stability (~400 oC) and can be used for high temperature applications
Hidrojenden elektrik enerjisi üretiminde kullanılan yakıt hücreleri, geleceğin çevre dostu ve yüksek verimli enerji üretimine alternatif olarak kabul görmektedirler. Nafion gibi perflorosülfonik asit bazlı membranlar polimer elektrolit membran yakıt hücreleri (PEMHY)’nde sıklıkla kullanılmaktadırlar. Ancak Nafion membranların yüksek sıcaklıklarda proton iletkenliklerinin düşmesi ve fiyatlarının yüksek olması nedeniyle alternatif polimer elektrolit membran (PEM)’lar üzerine araştırmalar devam etmektedir. Bu çalışmanın ilk aşamasında, disodyum-3,3’-disülfonat-4,4’-diklorodifenilsülfon (SDCDPS) ve benzimidazol bisfenol (HPBI) monomerlerinin sentezi gerçekleştirilmiştir. Daha sonra sentezlenen monomerlerden nükleofilik aromatik polikondenzasyon reaksiyonu ile poli(arilen eter benzimidazol) kopolimeri sentezlenmiştir. Sentezlenen monomerlerin 1H NMR ve FTIR, kopolimerin ise 1H NMR, FTIR ve termogravimetrik analizleri (TGA) gerçekleştirilmiştir. Yapılan analizler sonucunda kopolimerin sentezlendiği açıkça ortaya konulmuştur. TGA eğrisi sentezlenen kopolimerin ısıl kararlılığının yüksek olduğunu (~400 oC) ve yüksek sıcaklık uygulamalarında kullanılabilirliğini göstermiştir
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Birincil Dil en
Bölüm Araştırma Makalesi
Yazarlar

Yazar: Çağla TOSUN

Yazar: Özgül GERÇEL

Yazar: Emre URAZ

Yazar: Hasan GERÇEL

Tarihler

Yayımlanma Tarihi : 5 Mayıs 2015

Bibtex @ { aubtda42236, journal = {Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering}, issn = {1302-3160}, eissn = {2146-0205}, address = {}, publisher = {Eskişehir Teknik Üniversitesi}, year = {2015}, volume = {15}, pages = {137 - 146}, doi = {10.18038/btd-a.50020}, title = {SULFONATED POLY(ARYLENE ETHER BENZIMIDAZOLE) COPOLYMER MEMBRANE SYNTHESIS AND CHARACTERIZATION}, key = {cite}, author = {TOSUN, Çağla and GERÇEL, Özgül and URAZ, Emre and GERÇEL, Hasan} }
APA TOSUN, Ç , GERÇEL, Ö , URAZ, E , GERÇEL, H . (2015). SULFONATED POLY(ARYLENE ETHER BENZIMIDAZOLE) COPOLYMER MEMBRANE SYNTHESIS AND CHARACTERIZATION. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering , 15 (2) , 137-146 . DOI: 10.18038/btd-a.50020
MLA TOSUN, Ç , GERÇEL, Ö , URAZ, E , GERÇEL, H . "SULFONATED POLY(ARYLENE ETHER BENZIMIDAZOLE) COPOLYMER MEMBRANE SYNTHESIS AND CHARACTERIZATION". Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 15 (2015 ): 137-146 <https://dergipark.org.tr/tr/pub/aubtda/issue/3041/42236>
Chicago TOSUN, Ç , GERÇEL, Ö , URAZ, E , GERÇEL, H . "SULFONATED POLY(ARYLENE ETHER BENZIMIDAZOLE) COPOLYMER MEMBRANE SYNTHESIS AND CHARACTERIZATION". Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 15 (2015 ): 137-146
RIS TY - JOUR T1 - SULFONATED POLY(ARYLENE ETHER BENZIMIDAZOLE) COPOLYMER MEMBRANE SYNTHESIS AND CHARACTERIZATION AU - Çağla TOSUN , Özgül GERÇEL , Emre URAZ , Hasan GERÇEL Y1 - 2015 PY - 2015 N1 - doi: 10.18038/btd-a.50020 DO - 10.18038/btd-a.50020 T2 - Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering JF - Journal JO - JOR SP - 137 EP - 146 VL - 15 IS - 2 SN - 1302-3160-2146-0205 M3 - doi: 10.18038/btd-a.50020 UR - https://doi.org/10.18038/btd-a.50020 Y2 - 2020 ER -
EndNote %0 Anadolu Üniversitesi Bilim Ve Teknoloji Dergisi A - Uygulamalı Bilimler ve Mühendislik SULFONATED POLY(ARYLENE ETHER BENZIMIDAZOLE) COPOLYMER MEMBRANE SYNTHESIS AND CHARACTERIZATION %A Çağla TOSUN , Özgül GERÇEL , Emre URAZ , Hasan GERÇEL %T SULFONATED POLY(ARYLENE ETHER BENZIMIDAZOLE) COPOLYMER MEMBRANE SYNTHESIS AND CHARACTERIZATION %D 2015 %J Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering %P 1302-3160-2146-0205 %V 15 %N 2 %R doi: 10.18038/btd-a.50020 %U 10.18038/btd-a.50020
ISNAD TOSUN, Çağla , GERÇEL, Özgül , URAZ, Emre , GERÇEL, Hasan . "SULFONATED POLY(ARYLENE ETHER BENZIMIDAZOLE) COPOLYMER MEMBRANE SYNTHESIS AND CHARACTERIZATION". Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 15 / 2 (Mayıs 2015): 137-146 . https://doi.org/10.18038/btd-a.50020
AMA TOSUN Ç , GERÇEL Ö , URAZ E , GERÇEL H . SULFONATED POLY(ARYLENE ETHER BENZIMIDAZOLE) COPOLYMER MEMBRANE SYNTHESIS AND CHARACTERIZATION. AUBTD-A. 2015; 15(2): 137-146.
Vancouver TOSUN Ç , GERÇEL Ö , URAZ E , GERÇEL H . SULFONATED POLY(ARYLENE ETHER BENZIMIDAZOLE) COPOLYMER MEMBRANE SYNTHESIS AND CHARACTERIZATION. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering. 2015; 15(2): 146-137.