Araştırma Makalesi
BibTex RIS Kaynak Göster

Hekzagonal bor nitrür takviyeli akımsız nikel kaplamanın özelliklerine ısıl işlemin etkisi

Yıl 2019, Cilt: 4 Sayı: 3, 119 - 127, 30.09.2019
https://doi.org/10.30728/boron.578022

Öz

Bu çalışmada, 1050 alüminyum alaşım yüzeyine hekzagonal bor nitrür
(h-BN) ilaveli akımsız nikel-fosfor (Ni-P) kompozit kaplama uygulanmış ve
400°C’de 1 saat süreyle yapılan ısıl işlemin kaplama yapısına etkisi
incelenmiştir. Kompozit kaplamalar, üç farklı miktarda (1, 5 ve 10 g/L) h-BN içeren
çözeltide yapılmıştır. Kaplamalara, Taramalı Elektron Mikroskobu (SEM), X-ışını
spektroskopisi (EDS), X-ışını kırınımı (XRD) analizleri yapılmıştır. Bunlara
ilaveten yüzey pürüzlülükleri, sertlikleri ölçülmüş ve %3,5 sodyum klorür (NaCl)
çözeltisi içinde elektrokimyasal korozyon deneyleri yapılmıştır. Amorf yapıdaki
nikel matrisin ısıl işlem ile kristalin yapıya dönüştüğü tespit edilmiştir.
Isıl işlem sonucu sertlik değerleri artmış ve en yüksek sertlik değerine (1015
±
41
HV0,05), 10
g/L h-BN içerikli çözeltide yapılan kaplamada ulaşılmıştır. Elektrokimyasal
deneylerde ise ısıl işlemin kompozit kaplamaların korozyon direncini azalttığı
belirlenmiştir. 

Destekleyen Kurum

TÜBİTAK

Proje Numarası

114M063

Teşekkür

Bu çalışma, Yıldız Teknik Üniversitesi Bilimsel Araştırma Projeleri Koordinatörlüğü’nün 2014-07-02-DOP02 numaralı projesi ile desteklenmiştir. Çalışma, TÜBİTAK’ın 114M063 numaralı araştırma projesi ve 1059B14140108 numaralı bursu tarafından da ayrıca desteklenmiştir.

Kaynakça

  • [1] Roy M., Surface Engineering for Enhanced Performance against Wear, Springer, New York, 2013.
  • [2] Sha W., Wu X., Keong K. G., Electroless Copper and Nickel-Phosphorus Plating: Processing, Characterisation and Modelling, Woodhead Publishing Limited, Cambridge, 2011.
  • [3] Sudagar J., Lian J., Sha W., Electroless nickel, alloy, composite and nano coatings - A critical review, J. Alloys Compd., 571, 183-204, 2013.
  • [4] 4. Agarwala R. C., Agarwala V., Electroless alloy/composite coatings : A review, Sadhana, 475, 93, 2003.
  • [5] Kocabaş M., Ön işlemli akımsız nikel ve bor nitrür takviyeli akımsız nikel kaplanmış anodize alüminyum yüzeylerin özellikleri, Doktora Tezi, Yıldız Teknik Üniversitesi Fen Bilimleri Enstitüsü, İstanbul, 2017.
  • [6] Rabizadeh T., Allahkaram S. R., Corrosion resistance enhancement of Ni-P electroless coatings by incorporation of nano-SiO2 particles, Mater. Des., 32 (1), 133-8, 2011.
  • [7] Wang H. L., Liu L. Y., Dou Y., Zhang W. Z., Jiang W. F., Preparation and corrosion resistance of electroless Ni-P/SiC functionally gradient coatings on AZ91D magnesium alloy, Appl. Surf. Sci., 286, 319-27, 2013.
  • [8] Islam M., Azhar M. R., Khalid Y., Khan R., Abdo H. S., Dar M. A., Electroless Ni-P/SiC nanocomposite coatings with small amounts of SiC nanoparticles for superior corrosion resistance and hardness, J. Mater. Eng. Perform., 24 (12), 4835-43. 2015.
  • [9] Islam M., Azhar M. R., Fredj N., Burleigh T. D., Oloyede O. R., Almajid A. A., Influence of SiO2 nanoparticles on hardness and corrosion resistance of electroless Ni-P coatings, Surf. Coat. Technol., 261, 141-8, 2015.
  • [10] Dong D., Chen X. H., Xiao W. T., Yang G. B., Zhang P. Y., Preparation and properties of electroless Ni-P-SiO2 composite coatings, Appl. Surf. Sci., 255 (15), 7051–5, 2009.
  • [11] Lee C. K., Chang C. S., Tan A. H., Yang C. Y., Lee S. L., Preparation of electroless nickel-phosphorous-TiO2 composite coating for improvement of wear and stress corrosion cracking resistance of AA7075 in 3.5% NaCl, Key Eng. Mater., 74-79, 656-657, 2015.
  • [12] Tamilarasan T. R., Rajendran R., Siva Shankar M., Sanjith U., Rajagopal G., Sudagar J., Wear and scratch behaviour of electroless Ni-P-nano-TiO2: Effect of surfactants, Wear, 346-347, 148-57, 2016.
  • [13] Balaraju J. N., Kalavati., Rajam K. S., Influence of particle size on the microstructure, hardness and corrosion resistance of electroless Ni-P-Al2O3 composite coatings, Surf. Coat. Technol., 200 (12-13), 3933-41, 2006.
  • [14] Alirezaei S., Vaghefi S. M., Urgen M., Saatchi A., Kazmanli K., Evaluation of structure and mechanical properties of Ni-P-Al2O3 nanocomposite coatings, J. Compos. Mater., 47, 3323-9, 2012.
  • [15] Leon O. A., Staia M. H., Hintermann H. E., Influence of the heat treatment on the tribological behavior of a Ni-P-BN(h) autocatalytic composite coating, Surf. Coat. Technol., 120-121, 641-5, 1999.
  • [16] Leon O. A., Staia M. H., Hintermann H. E., Deposition of Ni-P-BN (h) composite autocatalytic coatings, Surf. Coat. Technol., 108-109, 461-5, 1998.
  • [17] Leon O. A., Staia M. H., Hintermann H. E., Wear mechanism of Ni-P-BN(h) composite autocatalytic coatings. Surf. Coat. Technol., 200 (5–6), 1825-9, 2005.
  • [18] Leon O. A., Staia M. H., Hintermann H. E., High temperature wear of an electroless Ni-P-BN (h) composite coating, Surf. Coat. Technol., 164, 578-84, 2003.
  • [19] Farrokhzad M. A., High temperature oxidation behaviour of autocatalytic Ni-P-BN (h) coatings. Surf. Coat. Technol., 309, 390-400, 2017.
  • [20] Hsu C-I., Wang G-L. L. Ger M-D., Hou K-H., Corrosion Behaviour of Electroless Deposited Ni–P/BN(h) Composite Coating. Int. J. Electrochem. Sci., 11, 4352-61, 2016.
  • [21] Hsu C-II., Hou K-H., Ger M-D., Wang G-L. L., The effect of incorporated self-lubricated BN(h) particles on the tribological properties of Ni-P/BN(h) composite coatings, Appl. Surf. Sci., 357, 1727-35, 2015.
  • [22] Kocabaş M., Örnek C., Curioni M., Cansever N., Nickel fluoride as a surface activation agent for electroless nickel coating of anodized AA1050 aluminum alloy, Surf. Coat. Technol., 364, 231-8, 2019.
  • [23] Vitry V., Kanta A. F., Delaunois F., Application of nitriding to electroless nickel-boron coatings: Chemical and structural effects; mechanical characterization; corrosion resistance, Mater Des., 39, 269-78, 2012.
  • [24] Wu Y., Shen B., Liu L., Hu W., The tribological behaviour of electroless Ni-P-Gr-SiC composite, Wear, 261 (2), 201-7, 2006.
  • [25] Yin Z., Chen F., Effect of nickel immersion pretreatment on the corrosion performance of electroless deposited Ni-P alloys on aluminium, Surf. Coatings Technol., 228, 34-40, 2013.
  • [26] Alishahi M., Monirvaghefi S. M., Saatchi A., Hosseini S. M., The effect of carbon nanotubes on the corrosion and tribological behavior of electroless Ni-P-CNT composite coating, Appl. Surf. Sci., 258 (7), 2439-46, 2012.

Heat treatment effect of hexagonal boron nitride reinforced electroless nickel coatings

Yıl 2019, Cilt: 4 Sayı: 3, 119 - 127, 30.09.2019
https://doi.org/10.30728/boron.578022

Öz

In this study, surfaces of 1050 aluminium alloy
were coated with hexagonal boron nitride (h-BN) reinforced electroless nickel-phosphorus
(Ni-P) composite coating and the effect of heat treatment on the coating
structure for 1 hour at 400°C was investigated. Composite coatings were performed
in solutions which consist of three different compositions (1, 5 and 10 g/L) of
h-BN. A scanning electron microscope (SEM), X-ray spectroscopy (EDS) and X-ray
diffraction (XRD) analysis were
performed on the composite coatings. Additionally, surface roughness and
hardness were measured and finally, electrochemical corrosion experiments were
conducted in 3.5% sodium chloride (NaCl) solution. The heat treatment process
has identified a transition from amorphous structure to crystalline in the
nickel matrix. The result of heat treatment, hardness values increased and the
highest value of hardness (1015
± 41 HV0.05)
was achieved with the specimen coated in 10 g/L h-BN solution. In the
electrochemical experiments, a reduction in corrosion resistance of the
composite coatings was determined the result of heat treatment. 

Proje Numarası

114M063

Kaynakça

  • [1] Roy M., Surface Engineering for Enhanced Performance against Wear, Springer, New York, 2013.
  • [2] Sha W., Wu X., Keong K. G., Electroless Copper and Nickel-Phosphorus Plating: Processing, Characterisation and Modelling, Woodhead Publishing Limited, Cambridge, 2011.
  • [3] Sudagar J., Lian J., Sha W., Electroless nickel, alloy, composite and nano coatings - A critical review, J. Alloys Compd., 571, 183-204, 2013.
  • [4] 4. Agarwala R. C., Agarwala V., Electroless alloy/composite coatings : A review, Sadhana, 475, 93, 2003.
  • [5] Kocabaş M., Ön işlemli akımsız nikel ve bor nitrür takviyeli akımsız nikel kaplanmış anodize alüminyum yüzeylerin özellikleri, Doktora Tezi, Yıldız Teknik Üniversitesi Fen Bilimleri Enstitüsü, İstanbul, 2017.
  • [6] Rabizadeh T., Allahkaram S. R., Corrosion resistance enhancement of Ni-P electroless coatings by incorporation of nano-SiO2 particles, Mater. Des., 32 (1), 133-8, 2011.
  • [7] Wang H. L., Liu L. Y., Dou Y., Zhang W. Z., Jiang W. F., Preparation and corrosion resistance of electroless Ni-P/SiC functionally gradient coatings on AZ91D magnesium alloy, Appl. Surf. Sci., 286, 319-27, 2013.
  • [8] Islam M., Azhar M. R., Khalid Y., Khan R., Abdo H. S., Dar M. A., Electroless Ni-P/SiC nanocomposite coatings with small amounts of SiC nanoparticles for superior corrosion resistance and hardness, J. Mater. Eng. Perform., 24 (12), 4835-43. 2015.
  • [9] Islam M., Azhar M. R., Fredj N., Burleigh T. D., Oloyede O. R., Almajid A. A., Influence of SiO2 nanoparticles on hardness and corrosion resistance of electroless Ni-P coatings, Surf. Coat. Technol., 261, 141-8, 2015.
  • [10] Dong D., Chen X. H., Xiao W. T., Yang G. B., Zhang P. Y., Preparation and properties of electroless Ni-P-SiO2 composite coatings, Appl. Surf. Sci., 255 (15), 7051–5, 2009.
  • [11] Lee C. K., Chang C. S., Tan A. H., Yang C. Y., Lee S. L., Preparation of electroless nickel-phosphorous-TiO2 composite coating for improvement of wear and stress corrosion cracking resistance of AA7075 in 3.5% NaCl, Key Eng. Mater., 74-79, 656-657, 2015.
  • [12] Tamilarasan T. R., Rajendran R., Siva Shankar M., Sanjith U., Rajagopal G., Sudagar J., Wear and scratch behaviour of electroless Ni-P-nano-TiO2: Effect of surfactants, Wear, 346-347, 148-57, 2016.
  • [13] Balaraju J. N., Kalavati., Rajam K. S., Influence of particle size on the microstructure, hardness and corrosion resistance of electroless Ni-P-Al2O3 composite coatings, Surf. Coat. Technol., 200 (12-13), 3933-41, 2006.
  • [14] Alirezaei S., Vaghefi S. M., Urgen M., Saatchi A., Kazmanli K., Evaluation of structure and mechanical properties of Ni-P-Al2O3 nanocomposite coatings, J. Compos. Mater., 47, 3323-9, 2012.
  • [15] Leon O. A., Staia M. H., Hintermann H. E., Influence of the heat treatment on the tribological behavior of a Ni-P-BN(h) autocatalytic composite coating, Surf. Coat. Technol., 120-121, 641-5, 1999.
  • [16] Leon O. A., Staia M. H., Hintermann H. E., Deposition of Ni-P-BN (h) composite autocatalytic coatings, Surf. Coat. Technol., 108-109, 461-5, 1998.
  • [17] Leon O. A., Staia M. H., Hintermann H. E., Wear mechanism of Ni-P-BN(h) composite autocatalytic coatings. Surf. Coat. Technol., 200 (5–6), 1825-9, 2005.
  • [18] Leon O. A., Staia M. H., Hintermann H. E., High temperature wear of an electroless Ni-P-BN (h) composite coating, Surf. Coat. Technol., 164, 578-84, 2003.
  • [19] Farrokhzad M. A., High temperature oxidation behaviour of autocatalytic Ni-P-BN (h) coatings. Surf. Coat. Technol., 309, 390-400, 2017.
  • [20] Hsu C-I., Wang G-L. L. Ger M-D., Hou K-H., Corrosion Behaviour of Electroless Deposited Ni–P/BN(h) Composite Coating. Int. J. Electrochem. Sci., 11, 4352-61, 2016.
  • [21] Hsu C-II., Hou K-H., Ger M-D., Wang G-L. L., The effect of incorporated self-lubricated BN(h) particles on the tribological properties of Ni-P/BN(h) composite coatings, Appl. Surf. Sci., 357, 1727-35, 2015.
  • [22] Kocabaş M., Örnek C., Curioni M., Cansever N., Nickel fluoride as a surface activation agent for electroless nickel coating of anodized AA1050 aluminum alloy, Surf. Coat. Technol., 364, 231-8, 2019.
  • [23] Vitry V., Kanta A. F., Delaunois F., Application of nitriding to electroless nickel-boron coatings: Chemical and structural effects; mechanical characterization; corrosion resistance, Mater Des., 39, 269-78, 2012.
  • [24] Wu Y., Shen B., Liu L., Hu W., The tribological behaviour of electroless Ni-P-Gr-SiC composite, Wear, 261 (2), 201-7, 2006.
  • [25] Yin Z., Chen F., Effect of nickel immersion pretreatment on the corrosion performance of electroless deposited Ni-P alloys on aluminium, Surf. Coatings Technol., 228, 34-40, 2013.
  • [26] Alishahi M., Monirvaghefi S. M., Saatchi A., Hosseini S. M., The effect of carbon nanotubes on the corrosion and tribological behavior of electroless Ni-P-CNT composite coating, Appl. Surf. Sci., 258 (7), 2439-46, 2012.
Toplam 26 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Konular Mühendislik
Bölüm Research Makaleler
Yazarlar

Mustafa Kocabaş 0000-0003-2179-5183

Halil Yılmaz 0000-0003-3585-0665

Nurhan Cansever Bu kişi benim

Proje Numarası 114M063
Yayımlanma Tarihi 30 Eylül 2019
Kabul Tarihi 10 Eylül 2019
Yayımlandığı Sayı Yıl 2019 Cilt: 4 Sayı: 3

Kaynak Göster

APA Kocabaş, M., Yılmaz, H., & Cansever, N. (2019). Hekzagonal bor nitrür takviyeli akımsız nikel kaplamanın özelliklerine ısıl işlemin etkisi. Journal of Boron, 4(3), 119-127. https://doi.org/10.30728/boron.578022

© 2016 Her Hakkı Saklıdır.
TENMAK Bor Araştırma Enstitüsü