Kolemanit, tinkal, üleksit ve bor atığında atomik absorpsiyon spektroskopi yöntemi ile Fe, Ni, Co ve Zn eser elementlerinin tayini

Yıl 2020, Cilt: 5 Sayı: 4, 176 - 182, 29.12.2020

Argun Türker Orhan Acar

https://doi.org/10.30728/boron.756254

Öz

Bu çalışmada, Türkiye’de en bol bulunan bazı bor minerallerinde (kolemanit, tinkal ve üleksit) ve bor atığında Cu, Fe, Ni, Co ve Zn eser elementleri alevli atomik absorpsiyon spektrometresi kullanılarak tayin edilmiştir. Bor minerallerinin çözülmesi için uygun çözücü belirlendikten sonra numuneler çözülmüş ve numune çözeltilerinde elementler tayin edilmiştir. Yöntemin geçerli kılınması amacıyla yöntemin doğruluğu ve kesinliği standart referans maddeler (NIST Montana soil 2711 ve NIST Estuarine sediment 1646a) analiz edilerek kontrol edilmiştir. Ayrıca yöntem için çalışılan her elemente ait doğrusal çalışma aralığı, gözlenebilme sınırı (LOD) ve tayin sınırı (LOQ) değerleri de belirlenmiştir.

Anahtar Kelimeler

Kolemanit, Tinkal, Üleksit, Bor atığı, Eser elementler

Teşekkür

Bor mineralleri ve bor atığının temini konusunda katkılarından dolayı Ulusal Bor araştırma Enstitüsüne (BOREN) teşekkür ederiz.

Determination of Fe, Ni, Co and Zn trace elements in colemanite, tinkal, ulexite and boron waste by atomic absorption spectroscopy method

Öz

In this study, Cu, Fe, Ni, Co and flame Zn trace elements were determined in boron minerals most abundant in Turkey (colemanite, tinkal and ulexite) and boron waste using atomic absorption spectrometry. After determining the suitable solvent for the dissolution of boron minerals, the samples were dissolved and the elements were determined in the sample solutions. In order to validate the method, the accuracy and precision of the method was checked by analyzing standard reference materials (NIST Montana soil 2711 and NIST Estuarine sediment 1646a). In addition,linear working range, limit of detection (LOD) and limit of quantification (LOQ) values for each element studied were determined for the method. The concentration ranges of the elements determined in boron minerals and boron waste are 111 μg/g and 

Anahtar Kelimeler

Atomic absorption spectroscopy, Boron waste, Colemanite, Tinkal, Ulexite

Kaynakça

• [1] Silva C. D., Santana G. P., Paz S. P. A., Determination of La, Ce, Nd, Sm, and Gd in mineral waste from cassiterite beneficiation by wavelength-dispersive X-ray fluorescence spectrometry, Talanta, 206, Article number: 120254, 2020.
• [2] Leng C. B., Wang W., Ye L., Zhang X. C., Genesis of the late Ordovician Kukaazi Pb-Zn deposit in the western Kunlun orogen, NW China: New insights from in-situ trace elemental compositions of base metal sulfides. J. Asian Earth Sci., 184, 103995, 2019.
• [3] Vanderschueren R., Montalvo D., De Ketelaere B., Delcour J.A., Smolders E., The elemental composition of chocolates is related to cacao content and origin: A multi-element fingerprinting analysis of single origin chocolates, J. Food Compos. Anal. 83, 103277, 2019.
• [4] Smrzka D., Zwicker J., Bach W., Feng D., Himmler T., Chen D., Peckmann J., The behavior of trace elements in seawater, sedimentary pore water, and their incorporation into carbonate minerals: a review, Facies, 65(4), 41-88, 2019. [5] World Health Organization, Trace-Elements in Human Nutrition. WHO Expert Committee. Geneva, Switzerland, 9-46, 1973.
• [6] Bogden J. D., The Essential Trace Elements and Minerals. In: Bogden J.D., Klevay L.M. (eds) Clinical Nutrition of the Essential Trace Elements and Minerals. Nutrition and Health. Humana Press, Totowa, NJ, 2000.
• [7] Bhattacharya P. T., Misra S. R., Hussain, M., Nutritional Aspects of Essential Trace Elements in Oral Health and Disease: An Extensive Review, Scientifica (Cairo), Article number: 5464373, 2016.
• [8] Jaime S. M., Bruno M. S., Carlos F. F. A., Leonir A. C., Ednei G. P., Marcia F. M., Fabio A., Duarte Determination of trace elements in Sergio mirim: an evaluation of sample preparation methods and detection techniques, Environ. Sci. Pollut. Res., 27, 21914–21923, 2020.
• [9] Özzeybek G., Alacakoç B., Kocabas M. Y., Bakırdere E. G., Chormey D. S., Bakırdere S., Trace determination of nickel in water samples by slotted quartz tube-flame atomic absorption spectrometry after dispersive assisted simultaneous complexation and extraction strategy, Environ. Monit. Assess. Article number: 498, 190, 2018.
• [10] Kılıç H. D., Deveci S., Dönmez K. B., Çetinkaya E., Karadağ S., Doğu M., Application of stripping voltammetry method for the analysis of available copper, zinc and manganese contents in soil samples, Intern. J. Environ. Anal. Chem. 98, 308-322, 2018.
• [11] Koçak, İ., Koç Ş., Major and trace element geochemistry of the Bigadiç Borate deposit, Balikesir, Turkiye. Geochem. Int., 50 (11), 926–951, 2012.
• [12] Ertan B., Erdoğan Y., Emet - Espey bölgesindeki borlu killerde eser element tayini, Dumlupınar Üniver. Fen Bilim. Ens. Derg., 33, 25-32, 2014.
• [13] Özmal F., Hisarcık-ESPEY Bölgesinde Bor Endüstri Atıklarında Eser Elementlerin Tayini ve Lityumun Değerlendirilmesi, Doktora Tezi, Dumlupınar Üniversitesi Fen Bilimleri Enstitüsü, Kütahya, 2012.
• [14] Helvacı C., Mordoğan H., Çolak M., Gündoğan I., Presence and distribution of lithium in borate deposits and some recent lake waters of west-central Turkey. Int. Geol. Rev., 46(2), 177-190, 2004.
• [15] Erdoğan Y., Mecit A., Demirbaş A., Abalı Y., Analyses of boronic ores and sludges and solubilities of boron minerals in CO2-saturated water. Resour. Conserv. Recycy., 24, 275–283, 1998.
• [16] Durak H., Genel Y., Alban T. C., Kuşlu S., Çolak S., Optimization of the dissolution of tincal ore in phosphoric acid solutions at high temperatures. Chem. Eng. Commun., 202, 245–251, 2015.
• [17] Türker A., Türker A. R., A critical review on the determination of boron in various matrices, J. Boron, 4(1), 31-38, 2019.
• [18] Kmiecik E., Tomaszewska B., Wator K., Bodzek M., Selected problems with boron determination in water treatment processes. Part I: comparison of the reference methods for ICP-MS and ICP-OES determinations, Environ. Sci. Res., 23, 11658-11667, 2016.
• [19] Peng G.L., He Q., Li H., Mmereki D., Lu Y., Zheng Y., Zhong Z., Lin J., Determination of boron in water samples by dispersive liquid-liquid microextraction based on the solidification of a floating organic drop coupled with a fluorimetric method, Analyst, 141, 2313-2318, 2016.
• [20] Floquet C. F. A., Lindvig T., Sieben V. J., MacKay B. A., Mostowfi F., Rapid determination of boron in oilfield water using a microfluidic instrument. Anal. Methods, 9, 1948-1955, 2017.
• [21] Abad C., Florek S., Becker-Ross H., Huang M. D., Heinrich H. J., Recknagel S., Vogl J., Jakubowski N., Panne U., Determination of boron isotope ratios by high-resolution continuum source molecular absorption spectrometry using graphite furnace vaporizers, Spectrochim. Acta B, 136,116-122, 2017.
• [22] Liv L., Nakiboglu N., Voltammetric Determination of boron using poly xylenol orange-modified pencil graphite electrode, Anal. Lett., 51, 170-185, 2018.
• [23] Erdoğan Y., Yenikaya C., Büyükkıdan N., Kalfa O. M., Determination of the elements in ulexite, tincal and colemanite by ICP-OES spectrometer, Uluslararası Bor Sempozyumu, Eskişehir Türkiye, 541-543, 23-25 Eylül 2004.
• [24] Erdoğan Y., Yenikaya C., Büyükkidan N., Atar N., Özmal F., Determination of elements ın boron ındustry wastes by ICP-OES spectrometer, II. Uluslararası Bor Sempozyumu, Osmangazi Üniversitesi, Eskişehir, Türkiye, 23-25 Eylül 525-526, 2004.
• [25] Kılıç E., Eti Maden Kırka Bor İşletmesi Atıklarının Analizi ve Sınıflandırılması, Yüksek Lisans Tezi, Dumlupınar Üniversitesi, Fen Bilimleri Enstitüsü, Kütahya, 2010.
• [26] Çelik A. G., Yörükoğlu A., Sürdem S., Türker A., Erdoğan Y., Bor katkılı pomza tuğla üretimi, fizikomekanik ve kimyasal özelliklerinin belirlenmesi, J. Boron, 4(2), 107-118, 2019.
• [27] Trindade A.C., Araújo S.A., Amorium F.A.C., Silva D.S., Alves J.P.S., Trindade J.S., Aguiar R.M., Bezerra M.A., Development of a method based on slurry sampling for determining Ca, Fe and Zn in coffee samples by flame atomic absorption spectrometry. Food Anal. Methods 13:203 – 211, 2020.
• [28] Çelik A. G., Yörükoğlu A., Sürdem S., Türker A., Erdoğan Y., Bor katkılı pomza tuğla üretimi, fizikomekanik ve kimyasal özelliklerinin belirlenmesi, Boron, 4 (2), 107-118, 2019.
• [29] Acar O., Determination of cadmium, chromium, copper and lead in sediments and soil samples by electrothermal atomic absorption spectrometry using zirconium containing chemical modifiers, Anal. Sci., 22, 731-735, 2006.
• [30] Trindade A. C., Araújo S. A., Amorium F. A. C., Silva D. S., Alves J. P. S., Trindade J. S., Aguiar R. M., et al., Development of a method based on slurry sampling for determining Ca, Fe and Zn in coffee samples by flame atomic absorption spectrometry. Food Anal. Methods, 13, 203-211, 2020.