Araştırma Makalesi

Enhanced Photocatalytic Degradation of Methyl Red Dye Via Hydrothermally Synthesized Manganese Tungstate

Cilt: 8 Sayı: 5 15 Eylül 2025
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Enhanced Photocatalytic Degradation of Methyl Red Dye Via Hydrothermally Synthesized Manganese Tungstate

Öz

In this study, MnWO₄ nanoparticles were successfully synthesized via a CTAB-assisted hydrothermal method and evaluated for their photocatalytic degradation performance against Methyl Red (MR) dye under UV-C irradiation. Structural and morphological characterizations were performed using XRD, FTIR, SEM, and UV-DRS techniques, confirming the formation of highly crystalline monoclinic MnWO₄ with defect-rich surfaces. The photocatalytic experiments were conducted under UV-C light (254 nm) with a catalyst dosage of 0.5 g/L, initial MR concentration of 20 mg/L, and solution pH of 6.5. The synthesized MnWO₄ exhibited excellent degradation efficiency, achieving 98% MR removal within 90 minutes, outperforming several conventional photocatalysts. This work addresses a critical gap in the literature by demonstrating the enhanced activity of CTAB-modified MnWO₄ under UV-C light, offering a promising route for azo dye remediation. The findings suggest that morphology control and surface defect engineering significantly influence photocatalytic performance, making MnWO₄ a viable candidate for environmental applications.

Anahtar Kelimeler

Etik Beyan

Ethics committee approval was not required for this study because of there was no study on animals or humans.

Kaynakça

  1. Ahmad MA, Ahmad N, Bello OS. 2015. Modified durian seed as adsorbent for the removal of methyl red dye from aqueous solutions. Appl Water Sci, 5(4): 407–423. https://doi.org/10.1007/s13201-014-0208-4
  2. Ahmad MA, Ahmed NB, Adegoke KA, Bello OS. 2019. Sorption studies of methyl red dye removal using lemon grass (Cymbopogon citratus). Chem Data Collect, 22: 100249. https://doi.org/10.1016/j.cdc.2019.100249
  3. Alharbi AA, Aldaghri O, El-Badry BA, Ibnaouf KH, Alfadhl F, Albadri A, Modwi A. 2024. Degradation of methyl red dye via fabricated Y₂O₃–MgO/g-C₃N₄ nanostructures: modification of band gap and photocatalysis under visible light. Opt Mater, 152: 115443. https://doi.org/10.1016/j.optmat.2024.115443
  4. Allabakshi SM, Srikar PSNSR, Gangwar RK, Maliyekkal SM. 2025. Nonthermal plasma technology for degradation of dyes in wastewater. In: Hamdaoui O (Ed.), Innovative and Hybrid Advanced Oxidation Processes for Water Treatment. Elsevier, pp: 255–278. https://doi.org/10.1016/B978-0-443-14100-3.00001-6
  5. Almeida MAP, Cavalcante LS, Varela JA, Li MS, Longo E. 2012. Effect of different surfactants on the shape, growth and photoluminescence behavior of MnWO₄ crystals synthesized by the microwave-hydrothermal method. Adv Powder Technol, 23(1): 124–128. https://doi.org/10.1016/j.apt.2011.10.004
  6. Berradi M, Hsissou R, Khudhair M, Assouag M, Cherkaoui O, El Bachiri A, El Harfi A. 2019. Textile finishing dyes and their impact on aquatic environs. Heliyon, 5(11): e02711. https://doi.org/10.1016/j.heliyon.2019.e02711
  7. Chakraborty AK, Ganguli S, Kebede MA. 2012. Photocatalytic degradation of 2-propanol and phenol using Au loaded MnWO₄ nanorod under visible light irradiation. J Cluster Sci, 23(2): 437–448. https://doi.org/10.1007/s10876-012-0450-6
  8. Gaim YT, Tesfamariam GM, Nigussie GY, Ashebir ME. 2019. Synthesis, characterization and photocatalytic activity of N-doped Cu₂O/ZnO nanocomposite on degradation of methyl red. J Compos Sci, 3(4): 93. https://doi.org/10.3390/jcs3040093

Ayrıntılar

Birincil Dil

İngilizce

Konular

Fotokimya, Kataliz ve Reaksiyon Mekanizmaları, İnorganik Yeşil Kimya, Kristalografi, Malzemelerin Optik Özellikleri

Bölüm

Araştırma Makalesi

Erken Görünüm Tarihi

11 Eylül 2025

Yayımlanma Tarihi

15 Eylül 2025

Gönderilme Tarihi

3 Temmuz 2025

Kabul Tarihi

8 Eylül 2025

Yayımlandığı Sayı

Yıl 2025 Cilt: 8 Sayı: 5

Kaynak Göster

APA
Kayhan, M. (2025). Enhanced Photocatalytic Degradation of Methyl Red Dye Via Hydrothermally Synthesized Manganese Tungstate. Black Sea Journal of Engineering and Science, 8(5), 1577-1584. https://doi.org/10.34248/bsengineering.1733519
AMA
1.Kayhan M. Enhanced Photocatalytic Degradation of Methyl Red Dye Via Hydrothermally Synthesized Manganese Tungstate. BSJ Eng. Sci. 2025;8(5):1577-1584. doi:10.34248/bsengineering.1733519
Chicago
Kayhan, Mehmet. 2025. “Enhanced Photocatalytic Degradation of Methyl Red Dye Via Hydrothermally Synthesized Manganese Tungstate”. Black Sea Journal of Engineering and Science 8 (5): 1577-84. https://doi.org/10.34248/bsengineering.1733519.
EndNote
Kayhan M (01 Eylül 2025) Enhanced Photocatalytic Degradation of Methyl Red Dye Via Hydrothermally Synthesized Manganese Tungstate. Black Sea Journal of Engineering and Science 8 5 1577–1584.
IEEE
[1]M. Kayhan, “Enhanced Photocatalytic Degradation of Methyl Red Dye Via Hydrothermally Synthesized Manganese Tungstate”, BSJ Eng. Sci., c. 8, sy 5, ss. 1577–1584, Eyl. 2025, doi: 10.34248/bsengineering.1733519.
ISNAD
Kayhan, Mehmet. “Enhanced Photocatalytic Degradation of Methyl Red Dye Via Hydrothermally Synthesized Manganese Tungstate”. Black Sea Journal of Engineering and Science 8/5 (01 Eylül 2025): 1577-1584. https://doi.org/10.34248/bsengineering.1733519.
JAMA
1.Kayhan M. Enhanced Photocatalytic Degradation of Methyl Red Dye Via Hydrothermally Synthesized Manganese Tungstate. BSJ Eng. Sci. 2025;8:1577–1584.
MLA
Kayhan, Mehmet. “Enhanced Photocatalytic Degradation of Methyl Red Dye Via Hydrothermally Synthesized Manganese Tungstate”. Black Sea Journal of Engineering and Science, c. 8, sy 5, Eylül 2025, ss. 1577-84, doi:10.34248/bsengineering.1733519.
Vancouver
1.Mehmet Kayhan. Enhanced Photocatalytic Degradation of Methyl Red Dye Via Hydrothermally Synthesized Manganese Tungstate. BSJ Eng. Sci. 01 Eylül 2025;8(5):1577-84. doi:10.34248/bsengineering.1733519

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