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Thermoluminescence Study of Natural CaCO₃ Mineral from Konya, Türkiye: Effect of Annealing on Signal Quality

Yıl 2026, Cilt: 9 Sayı: 2, 864 - 871, 15.03.2026
https://doi.org/10.34248/bsengineering.1867100
https://izlik.org/JA49WY97RA

Öz

In this study, thermoluminescence analyses were performed on natural CaCO₃ mineral sample obtained from Konya region after exposure to beta irradiation. Examining the thermoluminescence curve of the un-annealed sample, it was determined that there is a maximum at 100 °C and a tail extension around 250 °C. To detect the presence of deep traps, annealing was performed at temperatures between 400-800°C. It was decided that the optimum annealing temperature was 700°C, with a duration of 60 minutes. The characteristics of dose sensitivity, linearity, and reusability were analyzed to identify the effective thermoluminescence (TL) maximum on the high-temperature side of the spectrum. The whole TL glow curve was investigated through the Tm-Tstop experiment. Tm-Tstop experiment analysis determined that the luminescence curve of the natural CaCO3 mineral sample is complex.

Kaynakça

  • Artioli, G. (2010). Scientific methods and cultural heritage: An introduction to the application of materials science to archaeometry and conservation science. Oxford University Press. https://doi.org/10.1093/acprof:oso/9780199548262.001.0001
  • Avcı, H., Bulcar, K., Oğlakçı, M., & Atav, Ü. (2024). Dose rate calibration of β radiation source in Risø TL/OSL-DA-20 reader device. International Journal of Computational and Experimental Science and Engineering, 10(1). https://doi.org/10.22399/ijcesen.299
  • Boronat, C., Correcher, V., Virgos, M. D., & Garcia-Guinea, J. (2017). Ionising radiation effect on the luminescence emission of inorganic and biogenic calcium carbonates. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 401, 1–7. https://doi.org/10.1016/j.nimb.2017.04.035
  • Chen, R., & McKeever, S. W. S. (1997). Theory of thermoluminescence and related phenomena. World Scientific. https://doi.org/10.1142/2781
  • Çobanoğlu, İ., & Çelik, S. B. (2020). Evaluation of the use of an alternative mixture for pore filling material on travertine slabs. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, 26(8), 1373–1378.
  • Correcher, V., Boronat, C., Virgos, M. D., & Garcia-Guinea, J. (2020). UV-induced thermoluminescence of natural Ca-rich carbonates. Journal of Applied Spectroscopy, 86(6), 1004–1009. https://doi.org/10.1007/s10812-020-00931-5
  • Coy-Yll, R., Calderon, T., & Aguilar, M. (1988). Thermoluminescence and radioluminescence in aragonite. Mineralogy and Petrology, 39(1), 39–53. https://doi.org/10.1007/BF01226261
  • Declet, A., Rodriguez, E., & Suarez, O. M. (2016). Calcium carbonate precipitation: A review of the carbonate crystallization process and applications in bioinspired composites. Reviews on Advanced Materials Science, 44, 36–52.
  • Doebelin, N., & Kleeberg, R. (2015). Profex: A graphical user interface for the Rietveld refinement program BGMN. Journal of Applied Crystallography, 48(5), 1573–1580. https://doi.org/10.1107/S1600576715014685
  • Ercan, B., Oral, Ç. M., & Kapusuz, D. (2019). Enhanced vaterite and aragonite crystallization at controlled ethylene glycol concentrations. Sakarya University Journal of Science, 23(2), 129–138. https://doi.org/10.16984/saufenbilder.433985
  • Furetta, C. (2003). Handbook of thermoluminescence. World Scientific. https://doi.org/10.1142/5167
  • Garlick, G. F. J., & Gibson, A. F. (1948). The electron trap mechanism of luminescence in sulphide and silicate phosphors. Proceedings of the Physical Society, 60(6), 574–590. https://doi.org/10.1088/0959-5309/60/6/308
  • Hemingway, J. D., & Henkes, G. A. (2021). A disordered kinetic model for clumped isotope bond reordering in carbonates. Earth and Planetary Science Letters, 566, 116962. https://doi.org/10.1016/j.epsl.2021.116962
  • Lippmann, F. (1973). Crystal chemistry of sedimentary carbonate minerals. In F. Lippmann (Ed.), Sedimentary carbonate minerals (pp. 5–96). Springer Berlin Heidelberg. https://doi.org/10.1007/978-3-642-65474-9_2
  • Lowenstam, H. A., & Weiner, S. (1989). On biomineralization. Oxford University Press. https://doi.org/10.1093/oso/9780195049770.001.0001
  • McConnell, J. D. C. (1960). Vaterite from Ballycraigy, Larne, Northern Ireland. Mineralogical Magazine and Journal of the Mineralogical Society, 32(250), 535–544. https://doi.org/10.1180/minmag.1960.032.250.03
  • McKeever, S. W. S. (1980). On the analysis of complex thermoluminescence. Glow-curves: Resolution into individual peaks. Physica Status Solidi (a), 62(1), 331–340. https://doi.org/10.1002/pssa.2210620139
  • Medlin, W. L. (1959). Thermoluminescent properties of calcite. Journal of Chemical Physics, 30, 451–458. https://doi.org/10.1063/1.1729973
  • Medlin, W. L. (1961). Thermoluminescence in aragonite and magnesite. The Journal of Physical Chemistry, 65(7), 1172–1177. https://doi.org/10.1021/j100825a018
  • Medlin, W. L. (1963). Emission centers in thermoluminescent calcite, dolomite, magnesite, aragonite, and anhydrite. Journal of the Optical Society of America, 53(11), 1276. https://doi.org/10.1364/JOSA.53.001276
  • Nan, Z., Chen, X., Yang, Q., Wang, X., Shi, Z., & Hou, W. (2008). Structure transition from aragonite to vaterite and calcite by the assistance of SDBS. Journal of Colloid and Interface Science, 325(2), 331–336. https://doi.org/10.1016/j.jcis.2008.05.045
  • Pagonis, V., Kitis, G., & Furetta, C. (2006). Numerical and practical exercises in thermoluminescence. Springer New York. https://doi.org/10.1007/0-387-30090-2
  • Pöllmann, H. (Ed.). (2017). Cementitious materials. De Gruyter. https://doi.org/10.1515/9783110473728
  • Sahadat Hossain, Md., & Ahmed, S. (2023). Crystallographic characterization of naturally occurring aragonite and calcite phase: Rietveld refinement. Journal of Saudi Chemical Society, 27(3), 101649. https://doi.org/10.1016/j.jscs.2023.101649
  • Sato, M., & Matsuda, S. (1969). Structure of vaterite and infrared spectra. Zeitschrift Fur Kristallographie, 129, 405–410.
  • Schüler, T., & Tremel, W. (2011). Versatile wet-chemical synthesis of non-agglomerated CaCO3 vaterite nanoparticles. Chemical Communications, 47(18), 5208. https://doi.org/10.1039/c0cc05717g
  • Takada, N., Suzuki, A., Ishii, H., Hironaka, K., & Hironiwa, T. (2017). Thermoluminescence of coral skeletons: A high-sensitivity proxy of diagenetic alteration of aragonite. Scientific Reports, 7(1), 17969. https://doi.org/10.1038/s41598-017-18269-y
  • Tatumi, S. H., Nagatomo, T., Matsuoka, M., & Watanabe, S. (1993). Thermoluminescence and ESR in an aragonite speleothem. Journal of Physics D: Applied Physics, 26(9), 1482–1486. https://doi.org/10.1088/0022-3727/26/9/022
  • Townsend, P. D., Luff, B. J., & Wood, R. A. (1994). Mn2+ transitions in the TL emission spectra of calcite. Radiation Measurements, 23(2), 433–440. https://doi.org/10.1016/1350-4487(94)90076-0
  • Vichaidid, T., & Saeingjaew, P. (2022). Thermoluminescence and electron spin resonance dating of freshwater fossil shells from Pa Toh Roh Shelter archaeological site in southern Thailand. Heliyon, 8(9), e10555. https://doi.org/10.1016/j.heliyon.2022.e10555
  • Watanabe, S., Cano, N. F., Carvalho-Júnior, A. B., Ayala-Arenas, J. S., Gonzales-Lorenzo, C. D., & Rao, T. K. G. (2019). Dating of carbonate covering cave paintings at Peruaçu, Brazil by TL and EPR methods. Applied Radiation and Isotopes, 153, 108847. https://doi.org/10.1016/j.apradiso.2019.108847
  • Yalçınalp, B., Ersoy, H., Ersoy, A. F., & Keke, C. (2007). Bahçecik Gümüşhane travertenlerinin jeolojik ve jeoteknik özellikleri. Jeoloji Mühendisliği Dergisi, 31(2), 25–34.
  • Yukihara, E. G., McKeever, S. W. S., Andersen, C. E., Bos, A. J. J., Bailiff, I. K., Yoshimura, E. M., Sawakuchi, G. O., Bossin, L., & Christensen, J. B. (2022). Luminescence dosimetry. Nature Reviews Methods Primers, 2(1), 26. https://doi.org/10.1038/s43586-022-00102-0

Thermoluminescence Study of Natural CaCO₃ Mineral from Konya, Türkiye: Effect of Annealing on Signal Quality

Yıl 2026, Cilt: 9 Sayı: 2, 864 - 871, 15.03.2026
https://doi.org/10.34248/bsengineering.1867100
https://izlik.org/JA49WY97RA

Öz

In this study, thermoluminescence analyses were performed on natural CaCO₃ mineral sample obtained from Konya region after exposure to beta irradiation. Examining the thermoluminescence curve of the un-annealed sample, it was determined that there is a maximum at 100 °C and a tail extension around 250 °C. To detect the presence of deep traps, annealing was performed at temperatures between 400-800°C. It was decided that the optimum annealing temperature was 700°C, with a duration of 60 minutes. The characteristics of dose sensitivity, linearity, and reusability were analyzed to identify the effective thermoluminescence (TL) maximum on the high-temperature side of the spectrum. The whole TL glow curve was investigated through the Tm-Tstop experiment. Tm-Tstop experiment analysis determined that the luminescence curve of the natural CaCO3 mineral sample is complex.

Kaynakça

  • Artioli, G. (2010). Scientific methods and cultural heritage: An introduction to the application of materials science to archaeometry and conservation science. Oxford University Press. https://doi.org/10.1093/acprof:oso/9780199548262.001.0001
  • Avcı, H., Bulcar, K., Oğlakçı, M., & Atav, Ü. (2024). Dose rate calibration of β radiation source in Risø TL/OSL-DA-20 reader device. International Journal of Computational and Experimental Science and Engineering, 10(1). https://doi.org/10.22399/ijcesen.299
  • Boronat, C., Correcher, V., Virgos, M. D., & Garcia-Guinea, J. (2017). Ionising radiation effect on the luminescence emission of inorganic and biogenic calcium carbonates. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 401, 1–7. https://doi.org/10.1016/j.nimb.2017.04.035
  • Chen, R., & McKeever, S. W. S. (1997). Theory of thermoluminescence and related phenomena. World Scientific. https://doi.org/10.1142/2781
  • Çobanoğlu, İ., & Çelik, S. B. (2020). Evaluation of the use of an alternative mixture for pore filling material on travertine slabs. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, 26(8), 1373–1378.
  • Correcher, V., Boronat, C., Virgos, M. D., & Garcia-Guinea, J. (2020). UV-induced thermoluminescence of natural Ca-rich carbonates. Journal of Applied Spectroscopy, 86(6), 1004–1009. https://doi.org/10.1007/s10812-020-00931-5
  • Coy-Yll, R., Calderon, T., & Aguilar, M. (1988). Thermoluminescence and radioluminescence in aragonite. Mineralogy and Petrology, 39(1), 39–53. https://doi.org/10.1007/BF01226261
  • Declet, A., Rodriguez, E., & Suarez, O. M. (2016). Calcium carbonate precipitation: A review of the carbonate crystallization process and applications in bioinspired composites. Reviews on Advanced Materials Science, 44, 36–52.
  • Doebelin, N., & Kleeberg, R. (2015). Profex: A graphical user interface for the Rietveld refinement program BGMN. Journal of Applied Crystallography, 48(5), 1573–1580. https://doi.org/10.1107/S1600576715014685
  • Ercan, B., Oral, Ç. M., & Kapusuz, D. (2019). Enhanced vaterite and aragonite crystallization at controlled ethylene glycol concentrations. Sakarya University Journal of Science, 23(2), 129–138. https://doi.org/10.16984/saufenbilder.433985
  • Furetta, C. (2003). Handbook of thermoluminescence. World Scientific. https://doi.org/10.1142/5167
  • Garlick, G. F. J., & Gibson, A. F. (1948). The electron trap mechanism of luminescence in sulphide and silicate phosphors. Proceedings of the Physical Society, 60(6), 574–590. https://doi.org/10.1088/0959-5309/60/6/308
  • Hemingway, J. D., & Henkes, G. A. (2021). A disordered kinetic model for clumped isotope bond reordering in carbonates. Earth and Planetary Science Letters, 566, 116962. https://doi.org/10.1016/j.epsl.2021.116962
  • Lippmann, F. (1973). Crystal chemistry of sedimentary carbonate minerals. In F. Lippmann (Ed.), Sedimentary carbonate minerals (pp. 5–96). Springer Berlin Heidelberg. https://doi.org/10.1007/978-3-642-65474-9_2
  • Lowenstam, H. A., & Weiner, S. (1989). On biomineralization. Oxford University Press. https://doi.org/10.1093/oso/9780195049770.001.0001
  • McConnell, J. D. C. (1960). Vaterite from Ballycraigy, Larne, Northern Ireland. Mineralogical Magazine and Journal of the Mineralogical Society, 32(250), 535–544. https://doi.org/10.1180/minmag.1960.032.250.03
  • McKeever, S. W. S. (1980). On the analysis of complex thermoluminescence. Glow-curves: Resolution into individual peaks. Physica Status Solidi (a), 62(1), 331–340. https://doi.org/10.1002/pssa.2210620139
  • Medlin, W. L. (1959). Thermoluminescent properties of calcite. Journal of Chemical Physics, 30, 451–458. https://doi.org/10.1063/1.1729973
  • Medlin, W. L. (1961). Thermoluminescence in aragonite and magnesite. The Journal of Physical Chemistry, 65(7), 1172–1177. https://doi.org/10.1021/j100825a018
  • Medlin, W. L. (1963). Emission centers in thermoluminescent calcite, dolomite, magnesite, aragonite, and anhydrite. Journal of the Optical Society of America, 53(11), 1276. https://doi.org/10.1364/JOSA.53.001276
  • Nan, Z., Chen, X., Yang, Q., Wang, X., Shi, Z., & Hou, W. (2008). Structure transition from aragonite to vaterite and calcite by the assistance of SDBS. Journal of Colloid and Interface Science, 325(2), 331–336. https://doi.org/10.1016/j.jcis.2008.05.045
  • Pagonis, V., Kitis, G., & Furetta, C. (2006). Numerical and practical exercises in thermoluminescence. Springer New York. https://doi.org/10.1007/0-387-30090-2
  • Pöllmann, H. (Ed.). (2017). Cementitious materials. De Gruyter. https://doi.org/10.1515/9783110473728
  • Sahadat Hossain, Md., & Ahmed, S. (2023). Crystallographic characterization of naturally occurring aragonite and calcite phase: Rietveld refinement. Journal of Saudi Chemical Society, 27(3), 101649. https://doi.org/10.1016/j.jscs.2023.101649
  • Sato, M., & Matsuda, S. (1969). Structure of vaterite and infrared spectra. Zeitschrift Fur Kristallographie, 129, 405–410.
  • Schüler, T., & Tremel, W. (2011). Versatile wet-chemical synthesis of non-agglomerated CaCO3 vaterite nanoparticles. Chemical Communications, 47(18), 5208. https://doi.org/10.1039/c0cc05717g
  • Takada, N., Suzuki, A., Ishii, H., Hironaka, K., & Hironiwa, T. (2017). Thermoluminescence of coral skeletons: A high-sensitivity proxy of diagenetic alteration of aragonite. Scientific Reports, 7(1), 17969. https://doi.org/10.1038/s41598-017-18269-y
  • Tatumi, S. H., Nagatomo, T., Matsuoka, M., & Watanabe, S. (1993). Thermoluminescence and ESR in an aragonite speleothem. Journal of Physics D: Applied Physics, 26(9), 1482–1486. https://doi.org/10.1088/0022-3727/26/9/022
  • Townsend, P. D., Luff, B. J., & Wood, R. A. (1994). Mn2+ transitions in the TL emission spectra of calcite. Radiation Measurements, 23(2), 433–440. https://doi.org/10.1016/1350-4487(94)90076-0
  • Vichaidid, T., & Saeingjaew, P. (2022). Thermoluminescence and electron spin resonance dating of freshwater fossil shells from Pa Toh Roh Shelter archaeological site in southern Thailand. Heliyon, 8(9), e10555. https://doi.org/10.1016/j.heliyon.2022.e10555
  • Watanabe, S., Cano, N. F., Carvalho-Júnior, A. B., Ayala-Arenas, J. S., Gonzales-Lorenzo, C. D., & Rao, T. K. G. (2019). Dating of carbonate covering cave paintings at Peruaçu, Brazil by TL and EPR methods. Applied Radiation and Isotopes, 153, 108847. https://doi.org/10.1016/j.apradiso.2019.108847
  • Yalçınalp, B., Ersoy, H., Ersoy, A. F., & Keke, C. (2007). Bahçecik Gümüşhane travertenlerinin jeolojik ve jeoteknik özellikleri. Jeoloji Mühendisliği Dergisi, 31(2), 25–34.
  • Yukihara, E. G., McKeever, S. W. S., Andersen, C. E., Bos, A. J. J., Bailiff, I. K., Yoshimura, E. M., Sawakuchi, G. O., Bossin, L., & Christensen, J. B. (2022). Luminescence dosimetry. Nature Reviews Methods Primers, 2(1), 26. https://doi.org/10.1038/s43586-022-00102-0
Toplam 33 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Atomik, Moleküler ve Optik Fizik (Diğer)
Bölüm Araştırma Makalesi
Yazarlar

Hamide Avcı 0000-0003-2097-6054

Gönderilme Tarihi 19 Ocak 2026
Kabul Tarihi 20 Şubat 2026
Yayımlanma Tarihi 15 Mart 2026
DOI https://doi.org/10.34248/bsengineering.1867100
IZ https://izlik.org/JA49WY97RA
Yayımlandığı Sayı Yıl 2026 Cilt: 9 Sayı: 2

Kaynak Göster

APA Avcı, H. (2026). Thermoluminescence Study of Natural CaCO₃ Mineral from Konya, Türkiye: Effect of Annealing on Signal Quality. Black Sea Journal of Engineering and Science, 9(2), 864-871. https://doi.org/10.34248/bsengineering.1867100
AMA 1.Avcı H. Thermoluminescence Study of Natural CaCO₃ Mineral from Konya, Türkiye: Effect of Annealing on Signal Quality. BSJ Eng. Sci. 2026;9(2):864-871. doi:10.34248/bsengineering.1867100
Chicago Avcı, Hamide. 2026. “Thermoluminescence Study of Natural CaCO₃ Mineral from Konya, Türkiye: Effect of Annealing on Signal Quality”. Black Sea Journal of Engineering and Science 9 (2): 864-71. https://doi.org/10.34248/bsengineering.1867100.
EndNote Avcı H (01 Mart 2026) Thermoluminescence Study of Natural CaCO₃ Mineral from Konya, Türkiye: Effect of Annealing on Signal Quality. Black Sea Journal of Engineering and Science 9 2 864–871.
IEEE [1]H. Avcı, “Thermoluminescence Study of Natural CaCO₃ Mineral from Konya, Türkiye: Effect of Annealing on Signal Quality”, BSJ Eng. Sci., c. 9, sy 2, ss. 864–871, Mar. 2026, doi: 10.34248/bsengineering.1867100.
ISNAD Avcı, Hamide. “Thermoluminescence Study of Natural CaCO₃ Mineral from Konya, Türkiye: Effect of Annealing on Signal Quality”. Black Sea Journal of Engineering and Science 9/2 (01 Mart 2026): 864-871. https://doi.org/10.34248/bsengineering.1867100.
JAMA 1.Avcı H. Thermoluminescence Study of Natural CaCO₃ Mineral from Konya, Türkiye: Effect of Annealing on Signal Quality. BSJ Eng. Sci. 2026;9:864–871.
MLA Avcı, Hamide. “Thermoluminescence Study of Natural CaCO₃ Mineral from Konya, Türkiye: Effect of Annealing on Signal Quality”. Black Sea Journal of Engineering and Science, c. 9, sy 2, Mart 2026, ss. 864-71, doi:10.34248/bsengineering.1867100.
Vancouver 1.Hamide Avcı. Thermoluminescence Study of Natural CaCO₃ Mineral from Konya, Türkiye: Effect of Annealing on Signal Quality. BSJ Eng. Sci. 01 Mart 2026;9(2):864-71. doi:10.34248/bsengineering.1867100

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