Araştırma Makalesi
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Aubergine-based Biosorbents for Heavy Metal Extraction

Yıl 2022, Cilt: 5 Sayı: 2, 198 - 205, 31.12.2022
https://doi.org/10.55117/bufbd.1131122

Öz

In this study, an alternative inexpensive and eco-friendly Aubergine (Eggplant)-based biosorbents were synthesized for removing Cu2+, Ni2+, and Co2+ heavy metal ions from the aquatic region. Moreover, how the physical properties and water treatment performance were affected by their corn starch and oil contents were investigated. Their extraction capacity was evaluated by performing Flame atomic absorption spectroscopy (FAAS). ASTM D 792 standard was complied with to calculate biosorbent density. Indeed, the untreated eggplant stalk-based biosorbent adsorbed 5.36 mg of Co2+ ions and 4.99 mg of Ni2+ ions, and 4.84 mg of Cu2+ ions from 25 mL of initial solution that contained 7.00 ppm of each ion for 30 minutes, at room temperature with 175 rpm agitation speed by Eggplant-based biosorbents.

Destekleyen Kurum

Yok

Proje Numarası

Yok

Teşekkür

The authors thank the biology department of Zakho University that allowing to use of the microscope for the visualization of biosorbent surfaces.

Kaynakça

  • M.A.U. Martines L. Caetano, A.D. Santos, P.M. Padilha, and G.R. Castro, “Sediment grain size distribution and heavy metals determination in a dam on the Paraná River at Ilha Solteira, Brazil,” Journal of Environmental Science and Health, Part A, Vol.44, no 9, pp. 861–865, 2009.
  • M.C.S. Minello, A.L. Pac, R.S.D. Castro, L. Caetano, P.M. Padilha, G. Ferreira, M.A.U. Martines, and G.R. Castro, “Evaluation of heavy metal availability in contaminated sediments from the ilha solteira hydroelectric dam on the parana river at ilha solteira SP, Brazil,” Fresenius Environmental Bulletin, Vol. 19, pp. 2210, 2010.
  • N. Abdullah, N. Yusof, W.J. Lau, J. Jaafar, and A.F. Ismail, “Recent trends of heavy metal removal from water/wastewater by membrane technologies,” Journal of Industrial and Engineering Chemistry, Vol. 76, pp. 17–38, 2019.
  • J.O. Duruibe, M.O.C. Ogwuegbu, and J.N. Egwurugwu, “Heavy metal pollution and human biotoxic effects,” International Journal of Physical Science, Vol. 2, pp. 112–118, 2007.
  • S.O. Lesmana, N., Febriana, F.E, Soetaredjo, J, Sunarso, and S. Ismadji. “Studies on potential applications of biomass for the separation of heavy metals from water and wastewater,” Biochemistry Engineering Journal, Vol. 44, pp. 19–41, 2009.
  • F. Fu, and Q. Wang, “Removal of heavy metal ions from wastewaters: A review,” Journal of Environment Management, Vol. 92, pp. 407–418, 2011. Environ Res Tec, Vol. 5, Issue. 1, pp. 50–55, March 2022 55
  • D. Purkayastha, U. Mishra, S. Biswas. “A comprehensive review on Cd(II) removal from aqueous solution,” Journal of Water Process Engineering, Vol. 2, 105–128, 2014.
  • N.P. Raval, P.U. Shah, and N.K. Shah, “Adsorptive removal of nickel (II) ions from aqueous environment: A review,” Journal of Environment Management, Vol. 179, pp. 1–20, 2016.
  • M. Gavrilescu, “Removal of heavy metals from the environment by biosorption,” Engineering Life Science, Vol. 4, 219–232, 2004.
  • C.L. Massocatto, E.C. Paschoal, N. Buzinaro, T.F. Oliveria, C.R.T. Tarley, J. Caetano, A.C. Gonçalves, D.C. Dragunski, and K.M. Diniz, “Preparation and evaluation of kinetics and thermodynamics studies of lead adsorption onto chemically modified banana peels,” Desalination Water Treatment, Vol. 51, 5682– 5691, 2013.
  • J. Anwar, U. Shafique, W. Zaman, M. Salman, A. Dar, and S. Anwar. “Removal of PB (II) and CD (II) from water by adsorption on peels of banana,” Bioresearch Technology, Vol. 101 pp. 1752–1755, 2010.
  • J.R. Memona, S.Q. Memonb, M.I. Bhangera, G.Z. Memonc, A. El-Turki, and G.C. Allend, “Characterization of banana peel by scanning electron microscopy and FT-IR spectroscopy and its use for cadmium removal,” Colloids and Surfaces B: Biointerfaces, Vol. 66, pp. 260–265, 2008.
  • Q. Yu, and P. Kaewsarn, “Binary adsorption of copper (ii) and cadmium (ii) from aqueous solutions by biomass of marine algadurvillaea potatorum,” Separation Science and Technology, Vol. 34, pp. 1595– 1605, 1999.
  • R. Apiratikul and P. Pavasant, “Batch and column studies of biosorption of heavy metals by Caulerpa lentillifera,” Bioresource Technology, Vol. 99, 2766– 2777, 2008.
  • F. Özdemir, and D. Ramazanoğlu, “Production of wood-based eco-friendly bioplastic composites using waste banana peel, pepper stalk and red pine wood flour,” Turkish Journal of Forestry, Vol. 20, pp. 267–273, 2019.
  • F. Özdemir, and D. Ramazanoğlu, “Production of bioplastic composite and wood bioplastic composite with starch from different biomasses,” Journal of Bartin Faculty of Forestry, Vol. 21, pp. 377–385, 2019.
  • D. Ramazanoğlu, Z.A. Mohammed, & K.A. Maher, (2022). “Extraction of some heavy metal ions from aquatic solution by banana peel-based biosorbents,” Environmental Research and Technology, 5 (1), 50-55. DOI: 10.35208/ert.1009790.
  • B. B., Mishra, S., Gautam, & A. Sharma, (2012). “Browning of fresh-cut eggplant: Impact of cutting and storage,” Postharvest Biology and Technology, 67, 44–51.
  • X., Yang, J., Sun, F., Cui, J., Ji, L., Wang, Y., Zhang, & X. Sun, (2020). “An eco-friendly sensor based on CQD@MIPs for detection of N-acylated homoserine lactones and its 3D printing applications,” Talanta, 219, 121343.
  • Ichiyanagi, T., Kashiwada, Y., Shida, Y., Ikeshiro, Y., Kaneyuki, T., & Konishi, T. (2005). “Nasunin from Eggplant Consists of Cis−Trans Isomers of Delphinidin 3-[4-(p-Coumaroyl)-l-rhamnosyl (1→6)glucopyranoside]-5-glucopyranoside,” Journal of Agricultural and Food Chemistry, 53(24), 9472–9477.
  • M. J., Zaro, A. R., Chaves, A. R., Vicente, & A. Concellón, (2014). “Distribution, stability and fate of phenolic compounds in white and purple eggplants (Solanum melongena L.),” Postharvest Biology and Technology, 92, 70–78.
  • N. Gontard, S. Guilbert, and J.L. Cuq. “Edible wheat gluten films: influence of the main process variables on film properties using response surface methodology,” Journal of Food Science and Technology, Vol. 57, pp. 190–195, 1992.
  • ASTM D 792 2004. “Density and specific gravity (relative density) of plastics by displacement, ASTM International,” West Conshohocken, PA.

Ağır Metal Ekstraksiyonu için Patlıcan Bazlı Biyosorbentler

Yıl 2022, Cilt: 5 Sayı: 2, 198 - 205, 31.12.2022
https://doi.org/10.55117/bufbd.1131122

Öz

Bu araştırmada, çözeltiden Cu2+, Ni2+ ve Co2+ ağır metal iyonlarını uzaklaştırmak için üretilmiş, ucuz ve çevre dostu yeni bir alternatif Patlıcan (Patlıcan) sapı bazlı biyosorbentler geliştirilmiştir. Ayrıca mısır nişastası ve yağ içeriğinin yoğunluk, ağır metal ekstraksiyon performansı, su alımı ve çözünürlük gibi fiziksel özellikleri nasıl etkilediği belirlenmiştir. Biyosorbent ekstraksiyon performansının belirlenmesi için kullanılan alevli atomik absorpsiyon spektroskopisi (FAAS). Biyosorbentlerin yoğunluğu ASTM D 792 standartlarına göre belirlenmiştir. Sonuç olarak, işlenmemiş patlıcan sapı bazlı biyosorbent, 5,36 mg Co2+ iyonlarını, 4,99 mg Ni2+ iyonlarını adsorbe etti. Ayrıca, 4.84 mg Cu2+ iyonları, 25 ml 7 ppm ağır metal iyonu çözeltilerinden, 30 dakika boyunca, oda sıcaklığında, 175 rpm karıştırma hızında, Patlıcan bazlı biyosorbentler ile ekstrakte edildi.

Proje Numarası

Yok

Kaynakça

  • M.A.U. Martines L. Caetano, A.D. Santos, P.M. Padilha, and G.R. Castro, “Sediment grain size distribution and heavy metals determination in a dam on the Paraná River at Ilha Solteira, Brazil,” Journal of Environmental Science and Health, Part A, Vol.44, no 9, pp. 861–865, 2009.
  • M.C.S. Minello, A.L. Pac, R.S.D. Castro, L. Caetano, P.M. Padilha, G. Ferreira, M.A.U. Martines, and G.R. Castro, “Evaluation of heavy metal availability in contaminated sediments from the ilha solteira hydroelectric dam on the parana river at ilha solteira SP, Brazil,” Fresenius Environmental Bulletin, Vol. 19, pp. 2210, 2010.
  • N. Abdullah, N. Yusof, W.J. Lau, J. Jaafar, and A.F. Ismail, “Recent trends of heavy metal removal from water/wastewater by membrane technologies,” Journal of Industrial and Engineering Chemistry, Vol. 76, pp. 17–38, 2019.
  • J.O. Duruibe, M.O.C. Ogwuegbu, and J.N. Egwurugwu, “Heavy metal pollution and human biotoxic effects,” International Journal of Physical Science, Vol. 2, pp. 112–118, 2007.
  • S.O. Lesmana, N., Febriana, F.E, Soetaredjo, J, Sunarso, and S. Ismadji. “Studies on potential applications of biomass for the separation of heavy metals from water and wastewater,” Biochemistry Engineering Journal, Vol. 44, pp. 19–41, 2009.
  • F. Fu, and Q. Wang, “Removal of heavy metal ions from wastewaters: A review,” Journal of Environment Management, Vol. 92, pp. 407–418, 2011. Environ Res Tec, Vol. 5, Issue. 1, pp. 50–55, March 2022 55
  • D. Purkayastha, U. Mishra, S. Biswas. “A comprehensive review on Cd(II) removal from aqueous solution,” Journal of Water Process Engineering, Vol. 2, 105–128, 2014.
  • N.P. Raval, P.U. Shah, and N.K. Shah, “Adsorptive removal of nickel (II) ions from aqueous environment: A review,” Journal of Environment Management, Vol. 179, pp. 1–20, 2016.
  • M. Gavrilescu, “Removal of heavy metals from the environment by biosorption,” Engineering Life Science, Vol. 4, 219–232, 2004.
  • C.L. Massocatto, E.C. Paschoal, N. Buzinaro, T.F. Oliveria, C.R.T. Tarley, J. Caetano, A.C. Gonçalves, D.C. Dragunski, and K.M. Diniz, “Preparation and evaluation of kinetics and thermodynamics studies of lead adsorption onto chemically modified banana peels,” Desalination Water Treatment, Vol. 51, 5682– 5691, 2013.
  • J. Anwar, U. Shafique, W. Zaman, M. Salman, A. Dar, and S. Anwar. “Removal of PB (II) and CD (II) from water by adsorption on peels of banana,” Bioresearch Technology, Vol. 101 pp. 1752–1755, 2010.
  • J.R. Memona, S.Q. Memonb, M.I. Bhangera, G.Z. Memonc, A. El-Turki, and G.C. Allend, “Characterization of banana peel by scanning electron microscopy and FT-IR spectroscopy and its use for cadmium removal,” Colloids and Surfaces B: Biointerfaces, Vol. 66, pp. 260–265, 2008.
  • Q. Yu, and P. Kaewsarn, “Binary adsorption of copper (ii) and cadmium (ii) from aqueous solutions by biomass of marine algadurvillaea potatorum,” Separation Science and Technology, Vol. 34, pp. 1595– 1605, 1999.
  • R. Apiratikul and P. Pavasant, “Batch and column studies of biosorption of heavy metals by Caulerpa lentillifera,” Bioresource Technology, Vol. 99, 2766– 2777, 2008.
  • F. Özdemir, and D. Ramazanoğlu, “Production of wood-based eco-friendly bioplastic composites using waste banana peel, pepper stalk and red pine wood flour,” Turkish Journal of Forestry, Vol. 20, pp. 267–273, 2019.
  • F. Özdemir, and D. Ramazanoğlu, “Production of bioplastic composite and wood bioplastic composite with starch from different biomasses,” Journal of Bartin Faculty of Forestry, Vol. 21, pp. 377–385, 2019.
  • D. Ramazanoğlu, Z.A. Mohammed, & K.A. Maher, (2022). “Extraction of some heavy metal ions from aquatic solution by banana peel-based biosorbents,” Environmental Research and Technology, 5 (1), 50-55. DOI: 10.35208/ert.1009790.
  • B. B., Mishra, S., Gautam, & A. Sharma, (2012). “Browning of fresh-cut eggplant: Impact of cutting and storage,” Postharvest Biology and Technology, 67, 44–51.
  • X., Yang, J., Sun, F., Cui, J., Ji, L., Wang, Y., Zhang, & X. Sun, (2020). “An eco-friendly sensor based on CQD@MIPs for detection of N-acylated homoserine lactones and its 3D printing applications,” Talanta, 219, 121343.
  • Ichiyanagi, T., Kashiwada, Y., Shida, Y., Ikeshiro, Y., Kaneyuki, T., & Konishi, T. (2005). “Nasunin from Eggplant Consists of Cis−Trans Isomers of Delphinidin 3-[4-(p-Coumaroyl)-l-rhamnosyl (1→6)glucopyranoside]-5-glucopyranoside,” Journal of Agricultural and Food Chemistry, 53(24), 9472–9477.
  • M. J., Zaro, A. R., Chaves, A. R., Vicente, & A. Concellón, (2014). “Distribution, stability and fate of phenolic compounds in white and purple eggplants (Solanum melongena L.),” Postharvest Biology and Technology, 92, 70–78.
  • N. Gontard, S. Guilbert, and J.L. Cuq. “Edible wheat gluten films: influence of the main process variables on film properties using response surface methodology,” Journal of Food Science and Technology, Vol. 57, pp. 190–195, 1992.
  • ASTM D 792 2004. “Density and specific gravity (relative density) of plastics by displacement, ASTM International,” West Conshohocken, PA.
Toplam 23 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Çevre Mühendisliği
Bölüm Araştırma Makaleleri
Yazarlar

Doğu Ramazanoğlu 0000-0002-6356-5792

Zaman Adnan Mohammed 0000-0002-3457-3953

Idrees Khalo 0000-0002-5672-4150

Khalid Maher 0000-0002-5927-2209

Proje Numarası Yok
Erken Görünüm Tarihi 28 Aralık 2022
Yayımlanma Tarihi 31 Aralık 2022
Yayımlandığı Sayı Yıl 2022 Cilt: 5 Sayı: 2

Kaynak Göster

APA Ramazanoğlu, D., Mohammed, Z. A., Khalo, I., Maher, K. (2022). Aubergine-based Biosorbents for Heavy Metal Extraction. Bayburt Üniversitesi Fen Bilimleri Dergisi, 5(2), 198-205. https://doi.org/10.55117/bufbd.1131122
AMA Ramazanoğlu D, Mohammed ZA, Khalo I, Maher K. Aubergine-based Biosorbents for Heavy Metal Extraction. Bayburt Üniversitesi Fen Bilimleri Dergisi. Aralık 2022;5(2):198-205. doi:10.55117/bufbd.1131122
Chicago Ramazanoğlu, Doğu, Zaman Adnan Mohammed, Idrees Khalo, ve Khalid Maher. “Aubergine-Based Biosorbents for Heavy Metal Extraction”. Bayburt Üniversitesi Fen Bilimleri Dergisi 5, sy. 2 (Aralık 2022): 198-205. https://doi.org/10.55117/bufbd.1131122.
EndNote Ramazanoğlu D, Mohammed ZA, Khalo I, Maher K (01 Aralık 2022) Aubergine-based Biosorbents for Heavy Metal Extraction. Bayburt Üniversitesi Fen Bilimleri Dergisi 5 2 198–205.
IEEE D. Ramazanoğlu, Z. A. Mohammed, I. Khalo, ve K. Maher, “Aubergine-based Biosorbents for Heavy Metal Extraction”, Bayburt Üniversitesi Fen Bilimleri Dergisi, c. 5, sy. 2, ss. 198–205, 2022, doi: 10.55117/bufbd.1131122.
ISNAD Ramazanoğlu, Doğu vd. “Aubergine-Based Biosorbents for Heavy Metal Extraction”. Bayburt Üniversitesi Fen Bilimleri Dergisi 5/2 (Aralık 2022), 198-205. https://doi.org/10.55117/bufbd.1131122.
JAMA Ramazanoğlu D, Mohammed ZA, Khalo I, Maher K. Aubergine-based Biosorbents for Heavy Metal Extraction. Bayburt Üniversitesi Fen Bilimleri Dergisi. 2022;5:198–205.
MLA Ramazanoğlu, Doğu vd. “Aubergine-Based Biosorbents for Heavy Metal Extraction”. Bayburt Üniversitesi Fen Bilimleri Dergisi, c. 5, sy. 2, 2022, ss. 198-05, doi:10.55117/bufbd.1131122.
Vancouver Ramazanoğlu D, Mohammed ZA, Khalo I, Maher K. Aubergine-based Biosorbents for Heavy Metal Extraction. Bayburt Üniversitesi Fen Bilimleri Dergisi. 2022;5(2):198-205.

Taranılan Dizinler