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Investigation of the thermoluminescence properties Ti4+ doped MgO synthesized solid-state assisted solution combustion synthesis method

Yıl 2021, Cilt: 42 Sayı: 1, 164 - 169, 29.03.2021
https://doi.org/10.17776/csj.737307

Öz

In this study, undoped MgO and titanium (Ti4+) doped MgO ceramics were synthesized using the solid state-assisted solution combustion synthesis method. The structural characteristics were investigated using X-ray diffraction (XRD) and scanning electron microscope (SEM). TL curves of the MgO:Ti4+(0.1%wt) ceramic consist of three TL peaks located at 70, 250 and 290 oC with a heating rate of 2 oC/s after 1 Gy beta dose. Radioluminescence (RL) characteristic of the MgO:Ti4+(0.1%wt) ceramic was studied with excitations between 200 - 1000 nm. It was found to be the four emission bands the maximums located at 327 nm (~3.79 eV), 694 nm (~1.78 eV), 715 (~1.73 eV), and 745 (~1.66 eV). Some dosimetric characteristics such as TL curve, reusability, dose-response, of the ceramic were investigated using the thermoluminescence (TL) technique using beta radiation of 90Sr/90Y. Dose-response characteristics showed the integrated TL signals between 170-350 oC exhibited a linear up to 20 Gy. The experimental results showed that if it is developed of the MgO:Ti4+(0.1%wt) ceramic can be considered as a dosimetric material with suitable properties in personal and medical applications.


Destekleyen Kurum

North Atlantic Treaty Organization (NATO)

Teşekkür

This research was supported by the NATO Science for Peace and Security program (G5647).

Kaynakça

  • [1] Alajerami Y., Hashim S., Ghoshal S., Saleh S., Kadni T.,Saripan M., Alzimami K., Ibrahim Z., Bradley D., The effect of TiO2 and MgO on the thermoluminescence properties of a lithium potassium borate glass system, J. Phys. Chem. Solıds., 74 (2013) 1816-1822.
  • [2] Barrón V.R.O., Ochoa F.M.E,. Vázquez C.C., Bernal R., Thermoluminescence of novel MgO–CeO2 obtained by a glycine-based solution combustion method, Appl. Radıat. Isotopes., 117 (2016) 86-90.
  • [3] Guckan V., Altunal V. Ozdemir A., Yegingil. Z., Optically stimulated luminescence of MgO:Na,Li phosphor prepared using solution combustion method, J. Alloy. Compd., 835 (2020) 155253.
  • [4] Mofokeng S., Noto L., Mlotswa D., Orante-Barrón V., Dhlamini M., Thermoluminescence properties of MgO:Al3+,Li+ prepared by microwave-assisted solution combustion method, Physica B., (2020) 412008.
  • [5] Oliveira L., Yukihara E, Baffa O., Lanthanide-doped MgO: A case study on how to design new phosphors for dosimetry with tailored luminescent properties, J. Lumin., 209 (2019) 21-30.
  • [6] Rao R., Duley W., Preparation and luminescence of MgO:Tb phosphors, J. Mater. sci, 27 (1992) 5883-5886.
  • [7] Wang W., Qiao X., Chen J., Tan F., Li H., Influence of titanium doping on the structure and morphology of MgO prepared by coprecipitation method, Mater. Charac., 60 (2009) 858-862.
  • [8] Bokhimi X, Boldú J,Munoz E., Novaro O.,, López T, Hernández J., Gómez R., García-Ruiz A., Structure and composition of the nanocrystalline phases in a MgO− TiO2 system prepared via Sol− Gel technique, Chem. Mater., 11 (1999) 2716-2721.
  • [9] Orante-Barrón V., Oliveira L, Kelly J., Milliken E., Denis G, Jacobsohn L., Puckette J., Yukihara E., Luminescence properties of MgO produced by solution combustion synthesis and doped with lanthanides and Li, J. Lumin., 131 (2011) 1058-1065.
  • [10] Furetta C, Handbook of thermoluminescence, Singapore: World Scientific, (2010).
Yıl 2021, Cilt: 42 Sayı: 1, 164 - 169, 29.03.2021
https://doi.org/10.17776/csj.737307

Öz

Kaynakça

  • [1] Alajerami Y., Hashim S., Ghoshal S., Saleh S., Kadni T.,Saripan M., Alzimami K., Ibrahim Z., Bradley D., The effect of TiO2 and MgO on the thermoluminescence properties of a lithium potassium borate glass system, J. Phys. Chem. Solıds., 74 (2013) 1816-1822.
  • [2] Barrón V.R.O., Ochoa F.M.E,. Vázquez C.C., Bernal R., Thermoluminescence of novel MgO–CeO2 obtained by a glycine-based solution combustion method, Appl. Radıat. Isotopes., 117 (2016) 86-90.
  • [3] Guckan V., Altunal V. Ozdemir A., Yegingil. Z., Optically stimulated luminescence of MgO:Na,Li phosphor prepared using solution combustion method, J. Alloy. Compd., 835 (2020) 155253.
  • [4] Mofokeng S., Noto L., Mlotswa D., Orante-Barrón V., Dhlamini M., Thermoluminescence properties of MgO:Al3+,Li+ prepared by microwave-assisted solution combustion method, Physica B., (2020) 412008.
  • [5] Oliveira L., Yukihara E, Baffa O., Lanthanide-doped MgO: A case study on how to design new phosphors for dosimetry with tailored luminescent properties, J. Lumin., 209 (2019) 21-30.
  • [6] Rao R., Duley W., Preparation and luminescence of MgO:Tb phosphors, J. Mater. sci, 27 (1992) 5883-5886.
  • [7] Wang W., Qiao X., Chen J., Tan F., Li H., Influence of titanium doping on the structure and morphology of MgO prepared by coprecipitation method, Mater. Charac., 60 (2009) 858-862.
  • [8] Bokhimi X, Boldú J,Munoz E., Novaro O.,, López T, Hernández J., Gómez R., García-Ruiz A., Structure and composition of the nanocrystalline phases in a MgO− TiO2 system prepared via Sol− Gel technique, Chem. Mater., 11 (1999) 2716-2721.
  • [9] Orante-Barrón V., Oliveira L, Kelly J., Milliken E., Denis G, Jacobsohn L., Puckette J., Yukihara E., Luminescence properties of MgO produced by solution combustion synthesis and doped with lanthanides and Li, J. Lumin., 131 (2011) 1058-1065.
  • [10] Furetta C, Handbook of thermoluminescence, Singapore: World Scientific, (2010).
Toplam 10 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Klasik Fizik (Diğer)
Bölüm Natural Sciences
Yazarlar

Adnan ÖZDEMİR 0000-0002-2685-1562

Proje Numarası G5647
Yayımlanma Tarihi 29 Mart 2021
Gönderilme Tarihi 14 Mayıs 2020
Kabul Tarihi 19 Ocak 2021
Yayımlandığı Sayı Yıl 2021Cilt: 42 Sayı: 1

Kaynak Göster

APA ÖZDEMİR, A. (2021). Investigation of the thermoluminescence properties Ti4+ doped MgO synthesized solid-state assisted solution combustion synthesis method. Cumhuriyet Science Journal, 42(1), 164-169. https://doi.org/10.17776/csj.737307