The Investigation of Structural, Magnetic and Magnetocaloric Properties of (La0.9Er0.1)0.85K0.15MnO3 Manganite Compound
Yıl 2019,
Cilt: 34 Sayı: 1, 139 - 144, 31.03.2019
Gönül Akça
,
Selda Kılıç Çetin
Öz
In this study, the structural, magnetic and magnetocaloric properties of the polycrystalline (La0.9Er0.1)0.85K0.15MnO3 manganite compound synthesized by sol-gel method have been studied. X-ray diffraction measurement at room temperature shows that the sample crystallizes in rhombohedral structure. The temperature dependence of magnetization measurement reveals that the sample undergoes ferromagnetic-paramagnetic phase transition with increasing temperature. Maximum magnetic entropy change (∆SMmax) of the sample has been calculated as 2.30 Jkg-1K-1 for magnetic field change of 5 T from isothermal magnetization curves.
Kaynakça
- 1. Brück, E., 2005. Developments in magnetocaloric refrigeration. Journal of Physics D: Applied Physics, 38, R381-R391.
- 2. Tishin, A.M., Spichkin, Y.I. Zverev, V.I, Egolf, P.W., 2016. A Review and New Perspectives for the Magnetocaloric Effect: New Materials and local heating and cooling inside the human body. International Journal of Refrigeration 68, 177-186.
- 3. Phan, M.H, Yu, S.C., 2007. Review of the Magnetocaloric Effect in Manganite Materials, Journal of Magnetism and Magnetic Materials 308, 325-340.
- 4. Thang, N.V., Miao, X.F., van Dijk, N.H., Brück, E., 2016. Structural and Magnetocaloric Properties of (Mn,Fe)2(P,Si) Materials with Added Nitrogen. Journal of Alloys and Compounds, 670, 123-127.
- 5. Anwar, M.S., Ahmed, F., Koo, B.H., 2015. Influence of Ce Addition on the Structural, Magnetic and Magnetocaloric Properties in La0.7-xCexSr0.3MnO3 (0≤x≤0.3) Ceramic Compound. Ceramics International, 41, 5821-5829.
- 6. Spichkin, Y.I., Tishin, A.M., 2005. Thermodynamic Model of the Magnetocaloric Effect Near the First-order Magnetic Phase Transitions. Journal of Magnetism and Magnetic Materials 290-291, 700-702.
- 7. Akça, G., Kılıç Çetin, S., Ekicibil, A., 2017. Structural, Magnetic and Magnetocaloric Properties of (La1-xSmx)0.85K0.15MnO3 (x = 0.0, 0.1, 0.2 and 0.3) perovskite manganites. Ceramics International, 43, 15811-15820.
- 8. Thaljaoui, R., Boujelben, W., Pȩkała, M., Pȩkała, K., Antonowicz, J., Fagnard, J.F., Vanderbemden, P., Dąbrowska, S., Mucha, J., 2014. Structural, Magnetic and Magneto- Transport Properties of Monovalent Doped Manganite Pr0.55K0.05Sr0.4MnO3. J. Alloy. Comp. 611, 427–432.
- 9. Akça, G., Kılıç Çetin, S., Güneş, M., Ekicibil, A., 2016. Magnetocaloric Properties of (La1-xPrx)0.85K0.15MnO3 (x=0.0, 0.1, 0.3 and 0.5) Perovskite Manganites. Ceramics International, 42, 19097-19104.
- 10. Kallel, N., Kallel, S., Peňa, O., Oumezzine, M., 2009. Structural and Magnetic Properties of Hole Doped (La0.56Ce0.14)Sr0.30MnO3 Perovskite. Solid State Sciences 11, 1494-1498.
- 11. Wang, Z., Xu, Q., Chen, K., 2012. Maximum Magnetic Entropy Change Modulated Toward Room Temperature in Perovskite Manganites La0.7-xNdx(Ca,Sr)0.3MnO3, Current Applied Physics, 12, 1153-1157.
- 12. Dhahri, A., Jemmali, M., Hussein, M., Dhahri, E., Koumina, A., Hlil, E.K., 2015. Critical Behavior Near the Ferromagnetic to Paramagnetic Phase Transition Temperature in Polycrystalline La0.7Ca0.2Sr0.1Mn1-xCrxO3 (x= 0.15 and 0.2). Journal of Alloys and Compounds 618, 788–794.
- 13. Lakshami, Y.K., Venkataiah, G. Vithal, M., Reddy, P.V., 2008. Magnetic and Electrical Behavior of La1-xAxMnO3 (A = Li, Na, K and Rb) Manganites. Physica B, 403, 3059-3066.
- 14. Yang, J., Song, W.H., Ma, Y.Q, Zhang, R.L., Zhao, B.C., Sheng, Z.G., Zheng, G.H., Dai, J.M., Sun,Y.P., 2004. Structural, Magnetic and Transport Properties in the Pr-doped Manganites La0.9-xPrxTe0.1MnO3 (0≤x≤0.9). Physical Review B 70, 144421.
- 15. Kılıç Ç.S., Ekicibil, A., 2017. Determination of Magnetocaloric Effect in La0.67Ba0.33MnO3 from Direct and Indirect Measurements, Çukurova University, Journal of the Faculty of Engineering and Architecture 32(1), 141-145.
- 16. Tishin, A.M., Spichkin, Y.I., 2003. The Magnetocaloric Effect and its Applications, IOP Publishing LTD.
- 17. Mansouri, M., Omrani, H. Cheikhrouhou-Koubaa, W., Koubaa, M., Madouri, A., Cheikhrouhou, A., 2016. Effect of Vanadium Doping on Structural, Magnetic and Magnetocaloric Properties of La0.5Ca0.5MnO3, Journal of Magnetism and Magnetic Materials 401, 593-599.
- 18. Banerjee, B.K., 1964. On a Generalised Approach to First and Second Order Magnetic Transitions, Phys. Lett. 12, 16-17.
(La0.9Er0.1)0.85K0.15MnO3 Manganit Bileşiğinin Yapısal, Manyetik ve Manyetokalorik Özelliklerinin Araştırılması
Yıl 2019,
Cilt: 34 Sayı: 1, 139 - 144, 31.03.2019
Gönül Akça
,
Selda Kılıç Çetin
Öz
Bu çalışmada, sol-jel yöntemi ile sentezlenen polikristal (La0.9Er0.1)0.85K0.15MnO3 manganit bileşiğinin yapısal, manyetik ve manyetokalorik özellikleri çalışılmıştır. Oda sıcaklığında x-ışını kırınımı ölçümü, numunenin rhombohedral yapıda kristalleştiğini göstermektedir. Sıcaklığa bağlı manyetizasyon ölçümleri, artan sıcaklıkla numunenin ferromanyetik-paramanyetik faz geçişi sergilediğini göstermektedir. Numunenin maksimum manyetik entropi değişimi (∆SMmak.) izotermal mıknatıslanma eğrilerinden 5 T manyetik alan değişimi için 2.30 Jkg-1K-1 olarak hesaplanmıştır.
Kaynakça
- 1. Brück, E., 2005. Developments in magnetocaloric refrigeration. Journal of Physics D: Applied Physics, 38, R381-R391.
- 2. Tishin, A.M., Spichkin, Y.I. Zverev, V.I, Egolf, P.W., 2016. A Review and New Perspectives for the Magnetocaloric Effect: New Materials and local heating and cooling inside the human body. International Journal of Refrigeration 68, 177-186.
- 3. Phan, M.H, Yu, S.C., 2007. Review of the Magnetocaloric Effect in Manganite Materials, Journal of Magnetism and Magnetic Materials 308, 325-340.
- 4. Thang, N.V., Miao, X.F., van Dijk, N.H., Brück, E., 2016. Structural and Magnetocaloric Properties of (Mn,Fe)2(P,Si) Materials with Added Nitrogen. Journal of Alloys and Compounds, 670, 123-127.
- 5. Anwar, M.S., Ahmed, F., Koo, B.H., 2015. Influence of Ce Addition on the Structural, Magnetic and Magnetocaloric Properties in La0.7-xCexSr0.3MnO3 (0≤x≤0.3) Ceramic Compound. Ceramics International, 41, 5821-5829.
- 6. Spichkin, Y.I., Tishin, A.M., 2005. Thermodynamic Model of the Magnetocaloric Effect Near the First-order Magnetic Phase Transitions. Journal of Magnetism and Magnetic Materials 290-291, 700-702.
- 7. Akça, G., Kılıç Çetin, S., Ekicibil, A., 2017. Structural, Magnetic and Magnetocaloric Properties of (La1-xSmx)0.85K0.15MnO3 (x = 0.0, 0.1, 0.2 and 0.3) perovskite manganites. Ceramics International, 43, 15811-15820.
- 8. Thaljaoui, R., Boujelben, W., Pȩkała, M., Pȩkała, K., Antonowicz, J., Fagnard, J.F., Vanderbemden, P., Dąbrowska, S., Mucha, J., 2014. Structural, Magnetic and Magneto- Transport Properties of Monovalent Doped Manganite Pr0.55K0.05Sr0.4MnO3. J. Alloy. Comp. 611, 427–432.
- 9. Akça, G., Kılıç Çetin, S., Güneş, M., Ekicibil, A., 2016. Magnetocaloric Properties of (La1-xPrx)0.85K0.15MnO3 (x=0.0, 0.1, 0.3 and 0.5) Perovskite Manganites. Ceramics International, 42, 19097-19104.
- 10. Kallel, N., Kallel, S., Peňa, O., Oumezzine, M., 2009. Structural and Magnetic Properties of Hole Doped (La0.56Ce0.14)Sr0.30MnO3 Perovskite. Solid State Sciences 11, 1494-1498.
- 11. Wang, Z., Xu, Q., Chen, K., 2012. Maximum Magnetic Entropy Change Modulated Toward Room Temperature in Perovskite Manganites La0.7-xNdx(Ca,Sr)0.3MnO3, Current Applied Physics, 12, 1153-1157.
- 12. Dhahri, A., Jemmali, M., Hussein, M., Dhahri, E., Koumina, A., Hlil, E.K., 2015. Critical Behavior Near the Ferromagnetic to Paramagnetic Phase Transition Temperature in Polycrystalline La0.7Ca0.2Sr0.1Mn1-xCrxO3 (x= 0.15 and 0.2). Journal of Alloys and Compounds 618, 788–794.
- 13. Lakshami, Y.K., Venkataiah, G. Vithal, M., Reddy, P.V., 2008. Magnetic and Electrical Behavior of La1-xAxMnO3 (A = Li, Na, K and Rb) Manganites. Physica B, 403, 3059-3066.
- 14. Yang, J., Song, W.H., Ma, Y.Q, Zhang, R.L., Zhao, B.C., Sheng, Z.G., Zheng, G.H., Dai, J.M., Sun,Y.P., 2004. Structural, Magnetic and Transport Properties in the Pr-doped Manganites La0.9-xPrxTe0.1MnO3 (0≤x≤0.9). Physical Review B 70, 144421.
- 15. Kılıç Ç.S., Ekicibil, A., 2017. Determination of Magnetocaloric Effect in La0.67Ba0.33MnO3 from Direct and Indirect Measurements, Çukurova University, Journal of the Faculty of Engineering and Architecture 32(1), 141-145.
- 16. Tishin, A.M., Spichkin, Y.I., 2003. The Magnetocaloric Effect and its Applications, IOP Publishing LTD.
- 17. Mansouri, M., Omrani, H. Cheikhrouhou-Koubaa, W., Koubaa, M., Madouri, A., Cheikhrouhou, A., 2016. Effect of Vanadium Doping on Structural, Magnetic and Magnetocaloric Properties of La0.5Ca0.5MnO3, Journal of Magnetism and Magnetic Materials 401, 593-599.
- 18. Banerjee, B.K., 1964. On a Generalised Approach to First and Second Order Magnetic Transitions, Phys. Lett. 12, 16-17.