Investigation of Inhibition Effect of Morus Nigra Pendula Leaf Extract as Green Inhibitor on The Corrosion of Mild Steel in Acidic Solutions

Yıl 2019, Cilt: 34 Sayı: 1, 183 - 192, 31.03.2019

Ayşe Ongun Yüce

https://doi.org/10.21605/cukurovaummfd.601451

Cited By: 1

Öz

The inhibition behavior of Morus Nigra Pendula leave extract (MNPYE) as a green corrosion inhibitor in 0.5 M HCI solution at dissimilar concentrations for mild steel (MS) was investigated using methods such as linear polarization resistance (LPR), electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization techniques. EIS measurements have shown that the rising concentration of MNPYE in the acid solution increments the charge transfer resistance and diminishes the double layer capacitance. Polarization measurements have shown that MNPYE is a mixed-type inhibitor which dıminishes both anodic and cathodic current density values. The adsorption of MNPYE components on the MS surface was characterized by scanning electron microscopy (SEM) data.

Anahtar Kelimeler

Mild steel, EIS, Corrosion, Adsorption

Asidik Çözeltide Yumuşak Çeliğin Korozyonu Üzerine Yeşil İnhibitör Olarak Morus Nigra Pendula Yaprak Ekstraktının İnhibisyon Etkisinin İncelenmesi

Öz

Morus Nigra Pendula yaprağı ekstresinin (MNPYE) inhibisyon davranışı, 0,5 M HCI çözeltisi içinde farklı konsantrasyonlarda yeşil bir korozyon inhibitörü olarak yumuşak çelik (YÇ) için, doğrusal polarizasyon direnci (LPR), elektrokimyasal impedans spektroskopisi (EIS) ve potansiyodinamik polarizasyon teknikleri kullanılarak araştırılmıştır. EIS ölçümleri, asit çözeltisınde MNPYE’nin artan konsantrasyonuyla yük transfer direncinin arttığını ve çift tabaka kapasitansının azaldığını göstermiştir. Polarizasyon ölçümleri, MNPYE’nin hem anodik hem de katodik akım yoğunluğu değerlerini azaltan karışık tipte bir inhibitör olduğunu göstermiştir. MNPYE bileşenlerinin YÇ yüzeyindeki adsorpsiyonu, Taramalı Elektron Mikroskobu (SEM) verileri ile karakterize edildi.

Anahtar Kelimeler

Yumuşak çelik, EIS, Korozyon, Adsorpsiyon

Kaynakça

• 1. Raja, P.B., Qureshi, A.K., Rahim, A.A., Osman, H., Awang, K., 2013. Corros. Sci.: Neolamarckia Cadamba Alkaloids as Eco Friendly Corrosion Inhibitors for Mild Steel in 1 M HCl Media, 69, 292–301.
• 2. Bentrah, H., Rahali, Y., Chala, A., 2014. Corros. Sci.: Gum Arabic as an Eco-friendly Inhibitor for API 5L X42 Pipeline Steel in HCl Medyum, 82, 426–431.
• 3. Ansari, K.R., Quraishi, M.A., 2014. J. Ind. Eng. Chem.: Bis-Schiff Bases of Isatin as New Anda Environmentally Benign Corrosion Inhibitor for Mild Steel, 20, 2819–2829.
• 4. Pournazari, S.H., Moayed, M.H., Rahimizadeh, M., 2013. Corros. Sci.: In Situ Inhibitor Synthesis form Admixture of Benzaldehyde and Benzene-1,2-diamine Along with FeCl3 Catalyst as a New Corrosion Inhibitor for Mild Steel in 0.5 M sulphuric acid, 71, 20–31.
• 5. Dasami, P., Parameswari, K., Chitra, S., 2015. Measurement: Corrosion Inhibition of Mild Steel in 1 MH2SO4 by Thiadiazole Schiff Bases, 69, 195–201.
• 6. Verma, C., Ebenso, E.E., Bahadur, I., Obot, I.B., Quraishi, M.A., 2015. J. Mol. Liq.: Aryl Sulfonamidomethylphosphonates as New Class of Green Corrosion Inhibitors for Mild Steel in 1M HCl: Electrochemical, Surface and Quantum Chemical Investigation, 212, 209-218.
• 7. Noor, E.A., 2008. J. Eng. Appl. Sci.: Comparative Study on the Corrosion Inhibition of Mild Steel by Aqueous Extract of Fenugreek Seeds and Leaves in Acidic Solutions, 3, 23-30.
• 8. Okafor, P.C., Ikpi, M.E., Ekanem, U.I., Ebenso, E., 2013. Int. J. Electrochem. Sci.: Effects of Extracts from Nauclea Latifolia on the Dissolution of Carbon Steel in H2SO4 Solutions, 8, 12278–12286.
• 9. Patel, N.L., Jauhariand, S., Mehta, G.N., Al-Deyab, S.S., Warad, I., Hammouti, B., 2013. Int. J. Electrochem. Sci.: Mild Steel Corrosion Inhibition by Various Plant Extracts in 0.5 M Sulphuric Acid, 8, 2635–2655.
• 10. Mourya, P., Banerjee, S., Singh, M.M., 2014. Corros. Sci.: Corrosion Inhibition of Mild Steel in Acidic Solution by Tagetes Erecta (Marigold flower) Extract as a Green Inhibitor, 85, 352-363.
• 11. Singh, P., Makowska-Janusik, M., Slovensky, P., Quraishi, M.A., 2016. J. Mol. Liq.: Nicotinonitriles as Green Corrosion Inhibitors Formild Steel in Hydrochloric Acid: Electrochemical, Computational and Surface Morphological Studies, 220, 71–81.
• 12. Ituen, E., Akaranta, O., James, A., 2016. J. Mol. Liq.: Green Anticorrosive Oilfield Chemicals from 5-hydroxytryptophan and Synergistic Additives for X80 Steel Surface Protection in Acidic Well Treatment Fluids, 224, 408–419.
• 13. Alaneme, K.K., Olusegun, S.J., Adelowo, O.T., 2016. Alexandria Eng. J.: Corrosion Inhibition and Adsorption Mechanism Studies of Hunteria Umbellata Seed Husk Extracts on Mild Steel Immersed in Acidic Solutions, 55, 673–681.
• 14. Bellini, E., Giordani, E., Roger, J.P., 2000. Informatore Agrario: The Mulberry Tree for Fruit Production [Morus spp.]., 56, 89-93.
• 15. Gara, S., Jaisankar, P., Singh, J.K., Elango, A., 2012. Corros. Sci.: A Comprehensive Study on Crude–lice Extract of Artemisia pallens (Asteraceae) anda ita Active Component as Effective Corrosion Inhibitors of Mild Steel in Acil Solutions, 60, 193–204.
• 16. Li, X., Denge, S., Fu, H., Xie, X., 2014. Corros Sci.: Synergistic Inhibition Effects of Bamboo Leaf Extract/major Components anda Iodide Son on the Corrosion of Steel in H3PO4 Solutions, 78, 29–42.
• 17. Sanchez, C., Renard, D., Robert, P., Schmitt, C., Lefebvre, J., 2001. Food Hydrocoll: Structure and Rheological Properties of Acacia Gum Dispersions, 16, 257–267.
• 18. Umoren, S.A., Obot, I.B., Ebenso, E.E., Okafor, P.C., Ogbobe, O., Oguzie, E.E., 2006. Mater. Des.: Gum Arabic as a Potential Corrosion Inhibitor for Aluminium in Alkaline Medium and its Adsorption Characteristics, Anti-corros Methods, 53(5), 277.
• 19. Umoren, S.A., 2008. Cellulose: Inhibition of Aluminium and Mild Steel Corrosion in Acidic Medium Using Gum Arabic, 15, 751–761.
• 20. Hamdy, A., El-Gendy, N.Sh., 2013. Egypt. J. Pet.: Thermodynamic, Adsorption and Electrochemical Studies for Corrosion Inhibition of Carbon Steel by Henna Extract in Acid Medium, 22, 17–25.
• 21. Lebrini, M., Legrenee, M., Vezin, H., Traisnel, M., Bentiss, F., 2007. Experimental and Theoretical Study for Corrosion Inhibition of Mild Steel in Normal Hydrochloric Acid Solution by Some New Macrocyclic Polyether Compounds, 49, 2254–2269.
• 22. Reisde, F.M., Melo, H.G., Costa, I., 2006. Electrochim. Acta: EIS Investigation on Al 5052 Alloy Surfacepreparation for Self Assembling Monolayer, 51, 1780–1788.
• 23. Roy, P., Karfa, P., Adhikari, U., Sukul, D., 2014. Corros. Sci.: Corrosion Inhibition of Mild Steel in Acidic Medium by Polyacrylamide Grafted Guar Gum with Various Grafting Percentage: Effect of Intramolecular Synergism, 88, 246–253.
• 24. El Achouri, M., Kertit, S., Gouttaya, H.M., Nciri, B., Bensouda, Y., Perez, L., Infante, M.R., Elkacemi, K., 2001. Prog. Org. Coat.: Corrosion Inhibition of Iron in 1 M HCl by Some Gemini Surfactants in the Series of Alkanediyl-α, ω-bis-(Dimethyl Tetradecyl Ammonium Bromide), 43, 267–273.
• 25. Yadav, D.K., Quraishi, M.A., 2012. Ind. Eng. Chem. Res.: Electrochemical Investigation of Substituted Pyranopyrazoles Adsorption on Mild Steel in Acid Solution, 51, 8194–8210.
• 26. Verma, C., Quraishi, M.A., Singh, A., 2015. J. Taiwan. Ins.Chem. Eng.: 2-Aminobenzene-1,3-Dicarbonitriles as Green Corrosion Inhibitor for Mild Steel in 1 M HCl: Electrochemical, Thermodynamic, Surface and Quantum Chemical Investigation, 49, 229–239.
• 27. Odewunmi, N.A., Umoren, S.A., Gasem, Z.M., 2015. Journal of Environmental Chemical Engineering.: Watermelonwaste Products as Green Corrosion Inhibitors for Mild Steel in HCl Solution, 3, 286–296.
• 28. Hazwan Hussin, M., Abdul Rahim, A., Ibrahim, M.N., Brosse, N., 2016. The Capability of Ultrafiltrated Alkaline and Organosolv Oil Palm (Elaeis Guineensis) Fronds Lignin as Green Corrosion Inhibitor for Mild Steel in 0.5 M HCl Solution, Measurement, 78, 90–103.
• 29. Khaled, K., 2003. Electrochim. Açta: The Inhibition of Benzimidazole Derivatives on Corrosion of Iron in1 M HCl Solutions, 48, 2493–2503.
• 30. Nesakumar, T., Edison, J.I., Atchudan, R., Pugazhendhi, A., Lee, Y.R., Sethuraman, M.G., 2018. J. Mol. Liq.: Corrosion Inhibition Performance of Spermidine on Mild Steel in Acid Media, 264, 483–489.
• 31. Satapathy, A.K., Gunasekaran, G., Sahoo, S.C., Amit, K., Rodrigues, P.V., 2009. Corros. Sci.: Corrosion Inhibition by Justicia Gendarussa Plant Extract in Hydrochloric Acid Solution, 51, 2848–2856.
• 32. Elayyachy, M., El Idrissi, A., Hammouti, B., 2006. Corros. Sci.: New thio-compounds as Corrosion Inhibitor for Steel in 1 M HCl, 48, 2470-2479.
• 33. Morad, M.S., 2008. Corros. Sci.: Inhibition of iron Corrosion in Acid Solutions by Cefatrexyl: Behaviour Near and at the Corrosion Potential, 50, 436–448.
• 34. Ansari, K.R., Quraishi, M.A., Singh, A., 2014. Corros. Sci.: Schiff’s Base of Pyridyl Substitutedtriazoles as New and Effective Corrosion Inhibitors for Mild Steel Inhydrochloric Acid Solution, 79, 5–15.
• 35. Ahamad, I., Prasad, R., Quraishi, M.A., 2010. Corros. Sci.: Thermodynamic, Electrochemical Andquantum Chemical Investigation of Some Schiff Bases as Corrosion Inhibitorsfor Mild Steel in Hydrochloric Acid Solutions, 52, 933–942.
• 36. Li, W., He, Q., Zhang, S., Pei, C., Hou, B., 2008. J. Appl. Electrochem.: Some New Triazole Derivatives Asinhibitors for Mild Steel Corrosion in Acidic Medium, 38, 289–295.
• 37. Zhang, X., Zheng, Y., Wang, X., Yan, Y., Wu, W., 2014. Ind. Eng. Chem. Res.: Corrosion Inhibition of N80 Steel Using Novel Diquaternary Ammonium Salts in 15% Hydrochloric Acid, 53, 14199–14207.