Pr3+ Katkılı ZnO Nanoparçacıkların Hidrotermal Yöntemle Sentezi ve Karakterizasyonu

Sevim Demirözü Şenol; Melike İmamoğlu

doi:10.29130/dubited.816181

Araştırma Makalesi

Synthesis and Characterization of Pr3+doped ZnO Nanoparticles by Hydrothermal Method

Yıl 2021, , 393 - 405, 29.05.2021

Sevim Demirözü Şenol , Melike İmamoğlu

https://doi.org/10.29130/dubited.816181

Öz

In this study, Pr dopedZnO [Zn1-x PrxO (where x = 0.01,0.02,0.03,0.04,0.05)] nanoparticles with praseodymium (Pr3+) doped were synthesized by hydrothermal technique. The hydrothermal technique for the preparation of Pr doped ZnO nanostructures at different concentrationsis to an easy, fast and efficient method. The crystal structures, crystal morphologies and optical properties of synthesized nanoparticles were characterized by X-ray diffraction (XRD), Energy dispersive X-ray (EDX), surface morphology scanning electronmicroscope (SEM) and DiffusereflactanceUV-VIS spectroscopy.XRD studies showed that all Pr doped ZnO samples had hexagona lcrystal structure and Pr3+ ions were successfully incorporated into ZnO nanostructures, and there were nopeaks of Pr or praseodymiumoxide diffraction peaks in the pattern. From the SEM images, it was seen that ZnO becomes denser and more compact as the Pr concentrationin creases in the crystal structure. In the EDX results, the presence of Zn, O and Pr peaks in the composition of the synthesized samples were detected. Energy band gaps were calculated from the optical measurements of all samples and it was observed that the calculated energy band gap values increased with the praseodymium concentration.

Anahtar Kelimeler

Zincoxide, Hydrothermal method, Optical properties, DRS_UV-VIS

Kaynakça

[1] R. S. Sreedharan, R. Vinokumar, I. Navas, R. Prabhu ve V. P. MahadevanPillai, “Influence of Pr doping on thestructural, morphological, optical, luminescentandnon-linearopticalproperties of RF-sputtered ZnO films,” The Minerals, Metals and Mater. Society c. 68, s.1, ss. 341-350, 2016.
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Pr3+ Katkılı ZnO Nanoparçacıkların Hidrotermal Yöntemle Sentezi ve Karakterizasyonu

Yıl 2021, , 393 - 405, 29.05.2021

Sevim Demirözü Şenol , Melike İmamoğlu

https://doi.org/10.29130/dubited.816181

Öz

Bu çalışmada Praseodimyum(Pr3+) katkılı ZnO [Zn1-xPrxO(x=0.01,0.02,0.03,0.04,0.05)] nanoparçacıklar kolay, hızlı ve verimli bir yöntem olan hidrotermal yöntem ile sentezlenmiştir. Sentezlenen nanoparçacıkların, kristal yapıları X-ışını kırınımıyla (XRD), yüzey morfolojileri taramalı elektron mikroskobu (SEM) ve enerji dağıtıcı X-ışını dağılımlarıyla (EDX), optik özellikleri ise dağılma yansıma (DRS UV-VIS) spektroskopisi kullanılarak karakterize edilmiştir. XRD karakterizasyonunda tüm Pr3+katkılı ZnO örneklerinin hekzagonal (wurzite) yapıda oluştuğu, praseodimyum veya praseodimyumoksit’e ait herhangi bir kırınım pikinin oluşmadığı gözlemlenmiştir. SEM görüntülerinden ZnO'in kristal yapısında Pr konsantrasyonu arttıkça daha yoğun ve daha kompakt halde olduğu görülmüştür. EDX sonuçlarından ise, sentezlenen örneklerin bileşiminde Zn, O ve Pr piklerinin varlığı tespit edilmiştir. Tüm numunelerin optik ölçümlerinden enerji bant aralıkları hesaplanmış ve hesaplanan enerji bant aralığı değerlerinin, praseodimyum konsantrasyonu ile arttığı görülmüştür.

Anahtar Kelimeler

Çinko oksit, Hidrotermal metot, Optik özellikler, DRS_UV-VIS.

Kaynakça

[1] R. S. Sreedharan, R. Vinokumar, I. Navas, R. Prabhu ve V. P. MahadevanPillai, “Influence of Pr doping on thestructural, morphological, optical, luminescentandnon-linearopticalproperties of RF-sputtered ZnO films,” The Minerals, Metals and Mater. Society c. 68, s.1, ss. 341-350, 2016.
[1] R. S. Sreedharan, R. Vinokumar, I. Navas, R. Prabhu ve V. P. MahadevanPillai, “Influence of Pr doping on thestructural, morphological, optical, luminescentandnon-linearopticalproperties of RF-sputtered ZnO films,” The Minerals, Metals and Mater. Society c. 68, s.1, ss. 341-350, 2016.
[2] D. Kouyate, J. C. R. Haret ve J. Kossanyi “Electroluminescence of rareearths-doped semi conducting zincoxide electrodes: Kinetic aspects of the energy transfer between Sm3+and Eu3+”J. Lumin., c. 55, ss. 209-216,1993.
[2] D. Kouyate, J. C. R. Haret ve J. Kossanyi “Electroluminescence of rareearths-doped semi conducting zincoxide electrodes: Kinetic aspects of the energy transfer between Sm3+and Eu3+”J. Lumin., c. 55, ss. 209-216,1993.
[3] Y. Hayashi, H. Narahara, T. Uchida, T. Noguchi ve S. Ibuki, “Photoluminescence of Eu-doped znophosphors,” Jpn. J. Appl. Phys., c. 34, ss. 1878, 1995.
[3] Y. Hayashi, H. Narahara, T. Uchida, T. Noguchi ve S. Ibuki, “Photoluminescence of Eu-doped znophosphors,” Jpn. J. Appl. Phys., c. 34, ss. 1878, 1995.
[4] S. Bachir, K. Azuma, J. Kossanyi, P. Valat ve J.C.R. Haret, “Photoluminescence of polycrystalline zincoxideco-activated with trivalent rare earth ion sandlithium. Insertion of rare-earthionsintozincoxide,” J. Lumin., c. 75, ss. 35, 1997.
[4] S. Bachir, K. Azuma, J. Kossanyi, P. Valat ve J.C.R. Haret, “Photoluminescence of polycrystalline zincoxideco-activated with trivalent rare earth ion sandlithium. Insertion of rare-earthionsintozincoxide,” J. Lumin., c. 75, ss. 35, 1997.
[5] S. Bhushan, A. N. Pandey ve B. R. Kaza, “Photo- and electroluminescence of undoped and rare earth doped ZnO electroluminors,” J. Lumin., c. 20, ss. 29, 1979.
[5] S. Bhushan, A. N. Pandey ve B. R. Kaza, “Photo- and electroluminescence of undoped and rare earth doped ZnO electroluminors,” J. Lumin., c. 20, ss. 29, 1979.
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[7] R. Zamiri, A. Kaushal, A. Rebelo ve J. M. F. Ferreira,“Er doped ZnO nanoplates: Synthesis, optical and dielectricproperties,” Ceramics International, c. 40, s. 1B, ss.1635-1639, 2014.
[7] R. Zamiri, A. Kaushal, A. Rebelo ve J. M. F. Ferreira,“Er doped ZnO nanoplates: Synthesis, optical and dielectricproperties,” Ceramics International, c. 40, s. 1B, ss.1635-1639, 2014.
[8] R. Zamiri, A. F. Lemos, A. Rebelo, H. A. Ahangarb ve J. M. F. Ferreiraa, “Effects of rare-earth (Er, La and Yb) doping on morphology and structureproperties of ZnO nanostructures prepared by wetchemical method,” Ceramics International, c. 40, s. 1A, ss. 523-529, 2014.
[8] R. Zamiri, A. F. Lemos, A. Rebelo, H. A. Ahangarb ve J. M. F. Ferreiraa, “Effects of rare-earth (Er, La and Yb) doping on morphology and structureproperties of ZnO nanostructures prepared by wetchemical method,” Ceramics International, c. 40, s. 1A, ss. 523-529, 2014.
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[24] S. M. C. Miranda, M. Peres, T. Monteiro, E. Alves, H. D. Sun, T. Geruschke, R. Vianden ve K. Lorenz, “Rapid thermal annealing of rare earth implanted ZnO epitaxial layers,” Opt.Mater., c. 33, ss. 1139–1142, 2011.
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[25] M. Balestrieri, M. Gallart, M. Ziegler, P. F. Bazylewski, G. Ferblantier, G. Schmerber, G. S. Chang, P. Gilliot, D. Muller, A. Slaoui, S. Colis ve A. Dinia, “Luminescent propertiesand energy transfer in Pr3+ doped and Pr3+-Yb3+ co-doped ZnO thin films,” J. Phys. Chem.C, c. 118, ss. 13775–13780, 2014.
[26] K. Mukae, A. Ohi ve A. Tanaka, “Electronic interface states at grain boundaries in ZnO:Pr varistors by single grain boundary measurements,” J. Eur. Ceram. Soc.,c. 2, ss.1871–1874, 2001.
[26] K. Mukae, A. Ohi ve A. Tanaka, “Electronic interface states at grain boundaries in ZnO:Pr varistors by single grain boundary measurements,” J. Eur. Ceram. Soc.,c. 2, ss.1871–1874, 2001.
[27] W. J. Sun, R. Yang, X. Qu, M. H. Wang ve H. P. Zhang, “Microstructure and varistor properties of Pr–Coco-doped ZnO ceramics obtained by sol–gel method,” Journal of MaterialsScience: Materials in Electronics, c. 28, ss.10166–10172, 2017.
[27] W. J. Sun, R. Yang, X. Qu, M. H. Wang ve H. P. Zhang, “Microstructure and varistor properties of Pr–Coco-doped ZnO ceramics obtained by sol–gel method,” Journal of MaterialsScience: Materials in Electronics, c. 28, ss.10166–10172, 2017.
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Toplam 74 adet kaynakça vardır.

Ayrıntılar

Birincil Dil	Türkçe
Konular	Mühendislik
Bölüm	Makaleler
Yazarlar	Sevim Demirözü Şenol 0000-0002-5322-963X Melike İmamoğlu Bu kişi benim 0000-0001-8489-976X
Yayımlanma Tarihi	29 Mayıs 2021
Yayımlandığı Sayı	Yıl 2021

Kaynak Göster

APA	Demirözü Şenol, S., & İmamoğlu, M. (2021). Pr3+ Katkılı ZnO Nanoparçacıkların Hidrotermal Yöntemle Sentezi ve Karakterizasyonu. Duzce University Journal of Science and Technology, 9(3), 393-405. https://doi.org/10.29130/dubited.816181
AMA	Demirözü Şenol S, İmamoğlu M. Pr3+ Katkılı ZnO Nanoparçacıkların Hidrotermal Yöntemle Sentezi ve Karakterizasyonu. DÜBİTED. Mayıs 2021;9(3):393-405. doi:10.29130/dubited.816181
Chicago	Demirözü Şenol, Sevim, ve Melike İmamoğlu. “Pr3+ Katkılı ZnO Nanoparçacıkların Hidrotermal Yöntemle Sentezi Ve Karakterizasyonu”. Duzce University Journal of Science and Technology 9, sy. 3 (Mayıs 2021): 393-405. https://doi.org/10.29130/dubited.816181.
EndNote	Demirözü Şenol S, İmamoğlu M (01 Mayıs 2021) Pr3+ Katkılı ZnO Nanoparçacıkların Hidrotermal Yöntemle Sentezi ve Karakterizasyonu. Duzce University Journal of Science and Technology 9 3 393–405.
IEEE	S. Demirözü Şenol ve M. İmamoğlu, “Pr3+ Katkılı ZnO Nanoparçacıkların Hidrotermal Yöntemle Sentezi ve Karakterizasyonu”, DÜBİTED, c. 9, sy. 3, ss. 393–405, 2021, doi: 10.29130/dubited.816181.
ISNAD	Demirözü Şenol, Sevim - İmamoğlu, Melike. “Pr3+ Katkılı ZnO Nanoparçacıkların Hidrotermal Yöntemle Sentezi Ve Karakterizasyonu”. Duzce University Journal of Science and Technology 9/3 (Mayıs 2021), 393-405. https://doi.org/10.29130/dubited.816181.
JAMA	Demirözü Şenol S, İmamoğlu M. Pr3+ Katkılı ZnO Nanoparçacıkların Hidrotermal Yöntemle Sentezi ve Karakterizasyonu. DÜBİTED. 2021;9:393–405.
MLA	Demirözü Şenol, Sevim ve Melike İmamoğlu. “Pr3+ Katkılı ZnO Nanoparçacıkların Hidrotermal Yöntemle Sentezi Ve Karakterizasyonu”. Duzce University Journal of Science and Technology, c. 9, sy. 3, 2021, ss. 393-05, doi:10.29130/dubited.816181.
Vancouver	Demirözü Şenol S, İmamoğlu M. Pr3+ Katkılı ZnO Nanoparçacıkların Hidrotermal Yöntemle Sentezi ve Karakterizasyonu. DÜBİTED. 2021;9(3):393-405.

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