Biosynthesis of Gold Nanoparticles (AuNPs) with Dimrit Raisin Extract and Their Degradation Activity for Water Contaminants

Diğdem Trak; Yasin Arslan

doi:10.29130/dubited.901949

TR EN

Altın Nanopartiküllerin (AuNP) Dimrit Kuru Üzüm Özütü İle Biyosentezi ve Su Kirleticileri İçin Bozunma Aktiviteleri

Abstract

İstenilen morfoloji, boyut ve şekle sahip AuNP'ler, geleneksel olarak fiziksel ve/veya kimyasal yöntemler kullanılarak sentezlenmektedir. Fakat, bu yöntemlerin toksik kimyasal kullanımı, pahalı olması ve zorlu reaksiyon koşullarını içerdiği de bilinmektedir. Bu çalışmada Dimrit kuru üzüm özütü ile altın nanopartiküllerin sentezlenmesi için ilk defa kolay, uygun maliyetli, daha çevreci ve biyolojik bir yöntem tarif edilmiştir. AuNP'lerin sentez çalışmalarında hem özüt hem de Au çözeltisinin derişimi, sentez süresi ve sentez sıcaklığı gibi bazı deneysel parametrelerin etkileri araştırılmıştır. Sentezlenen AuNP'ler, UV-Vis spektrometresi, Transmisyon elektron mikroskobu (TEM), X-ışını kırınım difraktometresi (XRD) ve Fourier dönüşümü-kızılötesi spektroskopi (FTIR) ile karakterize edilmiştir. TEM sonuçları, 15 nm ortalama boyuta sahip AuNP’lerin üçgen ve altıgen şekiller ile birlikte nanopartiküllerin genellikle küresel şekilde olduğunu göstermiştir. Farklı endüstriyel alanlarda büyük miktarlarda toksik boyalar kullanılmaktadır ve boyalar su kaynakları için tehdit oluşturmaktadır. Bu nedenle, boyaları sudan gidermek için ucuz ve çevre dostu yöntemler geliştirmek zorunlu hale gelmiştir. Son zamanlarda, yeşil sentez ile elde edilmiş nanopartiküller kullanılarak gerçekleştirlen bozunma işlemleri, boyaların su kaynaklarından uzaklaştırılması için etkili bir yöntem haline gelmiştir. Bu çalışmada, ayrıca AuNP'lerin hem metilen mavisi (MB) hem de metil turuncu (MO) boyalarının bozunumu için çalışmalar gerçekleştirilmiştir. AuNP'ler, yüzde uzaklaştırma ve kinetik sonuçları değerlendirildiğinde hem MB hem de MO boyalarının bozunumu için etkili bir katalizör olarak görev almıştır. Ayrıca deney sonuçları, AuNP'lerin atık su arıtma çalışmalarında başarılı bir şekilde kullanılabileceğini göstermiştir.

Keywords

Dimrit kuru üzümü, AuNPs, Optimizasyon etkisi, Boya bozunumu

Project Number

0501-DR-18

Biosynthesis of Gold Nanoparticles (AuNPs) with Dimrit Raisin Extract and Their Degradation Activity for Water Contaminants

Abstract

AuNPs are being conventionally synthesized by traditional methods (physical and/or chemical) with preferred and well-defined morphology, size and shape. On the other hand, it has been reported that these methods involve difficult reaction conditions and/or toxic chemicals. In this study, an easy, cost effective and more environmentally and biological-friendly method was described for the synthesis of gold nanoparticles with Dimrit raisin extract for the first time. The effects of some experimental parameters, such as concentrations of both raisin extracts and Au solutions, synthesis time and synthesis temperature were investigated for the synthesis of AuNPs. The synthesized AuNPs were extensively characterized by UV-Visible spectrometer, Transmission electron microscopy (TEM), X-ray diffraction patterns (XRD) and Fourier transform–infrared spectroscopy (FTIR). TEM results show spherical along with triangular and hexagonal shaped nanoparticles with an average size of 15 nm. Large amounts of toxic dyes are used in the different industrial area and dyes posed a threat for water sources. Therefore, it has become imperative to develop inexpensive and environmentally friendly methods to remove dyes from water. In recent years, degradation using green synthesized nanoparticles has become an efficient method to remove dyes from the water sources. In this study, the catalytic activity of the AuNPs for the degradation of both methylene blue (MB) and methyl orange (MO) dyes were also studied and AuNPs behaved as effective catalysts for both degradations of MB and MO dyes in terms of percentage removal and kinetics. The experiment results showed that AuNPs can be employed as strong candidate in wastewater treatment studies.

Keywords

Dimrit raisin, AuNPs, Optimization effect, Dye degradation

Supporting Institution

Burdur Mehmet Akif Ersoy Üniversitesi Bilimsel Araştırma Projeleri (BAP) Koordinatörlüğü

Project Number

0501-DR-18

Thanks

This research was supported by Burdur Mehmet Akif Ersoy University Scientific Research Projects Coordinator (Project no: 0501-DR-18).

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Details

Primary Language

English

Subjects

Engineering

Journal Section

Research Article

Authors

Diğdem Trak This is me
0000-0001-8979-5505
Türkiye

Yasin Arslan ^*
0000-0002-3743-5679
Türkiye

Publication Date

January 31, 2022

Submission Date

March 24, 2021

Acceptance Date

July 29, 2021

Published in Issue

Year 2022 Volume: 10 Number: 1

DOI

https://doi.org/10.29130/dubited.901949

IZ

https://izlik.org/JA24CU77EN

APA

Trak, D., & Arslan, Y. (2022). Biosynthesis of Gold Nanoparticles (AuNPs) with Dimrit Raisin Extract and Their Degradation Activity for Water Contaminants. Duzce University Journal of Science and Technology, 10(1), 117-127. https://doi.org/10.29130/dubited.901949

AMA

1.Trak D, Arslan Y. Biosynthesis of Gold Nanoparticles (AuNPs) with Dimrit Raisin Extract and Their Degradation Activity for Water Contaminants. DUBİTED. 2022;10(1):117-127. doi:10.29130/dubited.901949

Chicago

Trak, Diğdem, and Yasin Arslan. 2022. “Biosynthesis of Gold Nanoparticles (AuNPs) With Dimrit Raisin Extract and Their Degradation Activity for Water Contaminants”. Duzce University Journal of Science and Technology 10 (1): 117-27. https://doi.org/10.29130/dubited.901949.

EndNote

Trak D, Arslan Y (January 1, 2022) Biosynthesis of Gold Nanoparticles (AuNPs) with Dimrit Raisin Extract and Their Degradation Activity for Water Contaminants. Duzce University Journal of Science and Technology 10 1 117–127.

IEEE

[1]D. Trak and Y. Arslan, “Biosynthesis of Gold Nanoparticles (AuNPs) with Dimrit Raisin Extract and Their Degradation Activity for Water Contaminants”, DUBİTED, vol. 10, no. 1, pp. 117–127, Jan. 2022, doi: 10.29130/dubited.901949.

ISNAD

Trak, Diğdem - Arslan, Yasin. “Biosynthesis of Gold Nanoparticles (AuNPs) With Dimrit Raisin Extract and Their Degradation Activity for Water Contaminants”. Duzce University Journal of Science and Technology 10/1 (January 1, 2022): 117-127. https://doi.org/10.29130/dubited.901949.

JAMA

1.Trak D, Arslan Y. Biosynthesis of Gold Nanoparticles (AuNPs) with Dimrit Raisin Extract and Their Degradation Activity for Water Contaminants. DUBİTED. 2022;10:117–127.

MLA

Trak, Diğdem, and Yasin Arslan. “Biosynthesis of Gold Nanoparticles (AuNPs) With Dimrit Raisin Extract and Their Degradation Activity for Water Contaminants”. Duzce University Journal of Science and Technology, vol. 10, no. 1, Jan. 2022, pp. 117-2, doi:10.29130/dubited.901949.

Vancouver

1.Diğdem Trak, Yasin Arslan. Biosynthesis of Gold Nanoparticles (AuNPs) with Dimrit Raisin Extract and Their Degradation Activity for Water Contaminants. DUBİTED. 2022 Jan. 1;10(1):117-2. doi:10.29130/dubited.901949

Biosynthesis of Gold Nanoparticles (AuNPs) with Dimrit Raisin Extract and Their Degradation Activity for Water Contaminants

Altın Nanopartiküllerin (AuNP) Dimrit Kuru Üzüm Özütü İle Biyosentezi ve Su Kirleticileri İçin Bozunma Aktiviteleri

Abstract

Keywords

Project Number

Biosynthesis of Gold Nanoparticles (AuNPs) with Dimrit Raisin Extract and Their Degradation Activity for Water Contaminants

Abstract

Keywords

Supporting Institution

Project Number

Thanks

References

Details

Primary Language

Subjects

Journal Section

Authors

Publication Date

Submission Date

Acceptance Date

Published in Issue

DOI

IZ

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