The Effects of Hydrogen Peroxide and Sodium Hypochlorite Oxidizing Treatments on the Color Properties of Naturally Colored Green Cotton

Yıl 2019, Cilt: 3 Sayı: 2, 1 - 10, 10.10.2019

Ali Serkan Soydan , Arzu Yavaş , Osman Ozan Avinç , Gizem Karakan Günaydın , M. Niyazi Kıvılcım Mehmet Demirtaş Sema Palamutcu

Öz

Ali Serkan Soydan1, Arzu Yavaş1, Osman Ozan Avinç1, Gizem Karakan Günaydın2, M. Niyazi Kıvılcım3, Mehmet Demirtaş3, Sema Palamutcu*1
1 Pamukkale University, Textiles Engineering Department, Denizli, Turkey
2 Pamukkale University, Buldan Vocational School, Buldan, Denizli, Turkey
3 Cotton Research Institute, Nazilli, Aydın, Turkey
*Corresponding Author email: [e-mail]

The cultivation of naturally
colored cotton has captured the attention lately due to the increasing
environmental concerns and problems. The green color in cotton fibers is owing
to a lipid biopolymer (suberin) sandwiched between the lamellae of cellulose
microfibrils in the secondary wall. Naturally colored green cotton fiber does
not need dyeing or coloration process due to their inherent color characteristics
leading to more ecological and sustainable textile production. Naturally
colored cotton growers and producers have less requirement for the pesticides,
insecticides since these varieties have already insect and disease-resistant
qualities as well as they exhibit property for drought and salt tolerant
leading to more environmental friendly cotton fiber production. The
colorimetric (CIE L*, a*, b*, C*, h^o, K/S etc.) properties of
studied naturally green colored Turkish cotton fiber were explored before and
after scouring (with NaOH), and oxidizing processes with hydrogen peroxide and
sodium hypochlorite (with different sodium hypochlorite concentrations and
different oxidizing treatment periods and at different pH levels, with or
without scouring process as a precursor treatment etc.) in comparison with
their greige (un-treated) counterpart. The application of scouring process with
NaOH to naturally green colored cotton fiber increases the color yield levels
leading to darker appearance. Similarly, hydrogen peroxide and sodium
hypochlorite oxidizing processes resulted in an increase in the color yield
levels of naturally green colored cotton fibers leading to darker appearance.
Even at high sodium hypochlorite concentrations such as 200 ml/l at pH 12 and
room temperature for 48 hours, the naturally green colored cotton fibers
maintain their color.

Anahtar Kelimeler

naturally colored cotton, oxidizing, sodium hypochlorite, hydrogen peroxide

Kaynakça

• [1]. Vreeland, J. and James, M. (1999). The revival of colored cotton. Scientific America, 280 (4), 112-119
• [2]. Lee, J. (1996). A new spin on naturally colored cotton. Agricultural Research 44 (4), 20-21
• [3]. Mohammadioun, M., Gallaway, M. and Apodaca, J. K. (1994). An economic analysis of organic cotton as a niche crop in texas. University of Texas at Austin, Bureau of Business Research, Austin, Texas
• [4]. Burnett, P., 1995, Cotton naturally, Textile Horizons, Vol.15, February, pp 36–38
• [5]. Robbins, J. Destination Discovery 1994, 18–21, Khadi, B. M.; Kulkarni, V. N. Indian Text J 1996, 106(11), 72–76
• [6]. Lee, J. Agric Res 1996, 44, 20–21, Elesini, U. S.; Richards, A. F.; Rowe, T. Proceedings 30th International Symposium on Novelties in Textiles, Ljubljana, 1996, pp 122–125
• [7]. Kohel, R. Crop Sci 1985, 25, 793–797, Fox, S. V. Proceedings: Sixth Annual Engineered Fiber Selection Conference, May 3–5, 186–189
• [8]. Williams, B. L.; Horridge, P. Text Tech Int 1997, 31–36
• [9]. VanZandt, M. J.; Horridge, P.; Dever, J. K. Clothing Text Res J 1997, 15(4), 246–251
• [10]. Chen, H. L., & Yokochi, A. (2000). X‐ray diffractometric study of microcrystallite size of naturally colored cottons. Journal of Applied Polymer Science, 76(9), 1466-1471.
• [11]. Matusiak M, Frydrych I. Investigation of Naturally Coloured Cotton of Different Origin – Analysis of Fibre Properties, FIBRES & TEXTILES in Eastern Europe 2014; 22, 5(107): 34-42
• [12]. Kimmel, L.B. and Day, 2001, M.P., AATCC Rev., 1(10), 32, 2001
• [13]. Ryser, U., Cotton fiber initiation and histodifferentiation, in Cotton Fibers, Developmental Biology, Quality Improvement, and Textile Processing, Basra, A.S., Ed., Haworth Press, Binghamton, New York, 1999, chap. 1, pp. 21–29
• [14]. Ryser, U., Meier, H., & Holloway, P. J. (1983). Identification and localization of suberin in the cell walls of green cotton fibres (Gossypium hirsutum L., var. green lint). Protoplasma, 117(3), 196-205.
• [15]. Elesini, U. S., Cuden, A. P., & Richards, A. F. (2002). Study of the green cotton fibres. Acta Chim. Slov, 49, 815-833.
• [16]. P Singh, V V Singh, V. N Waghmare, Naturally Coloured Cotton, CICR Technical Bulletin NO: 4, http://www.cicr.org.in/pdf/naturally_colored_cotton.pdf
• [17]. Karmakar, S. R. (1999). Chemical technology in the pre-treatment processes of textiles (Vol. 12). Elsevier.
• [18]. Sho Yeung Kang, Helen H. Epps. (2009) Effect of scouring and enzyme treatment on moisture regain percentage of naturally colored cottons. Journal of the Textile Institute 100:7, pages 598-606.
• [19]. Osman Çağırgan, Ayhan Barut, “Nazilli Pamuk Araştırma Enstitüsündeki Genetik-Stok Pamuk Çeşitlerinin Özellikleri”, T.C. Tarım ve Köyişleri Bakanlığı Tarımsal Araştırmalar Genel Müdürlüğü Nazilli Pamuk Araştırma Enstitüsü Müdürlüğü, Yayın No:58, Nazilli, 2000, page 30.
• [20]. Avinc, O., & Yavas, A. (2017). Soybean: For Textile Applications and Its Printing. In Soybean-The Basis of Yield, Biomass and Productivity. InTech.
• [21]. Sho Yeung Kang; Epps, Helen H., Effect of Scouring on the Color of Naturally-colored Cotton and the Mechanism of Color Change, AATCC Review. Jul 2008, Vol. 8 Issue 7, p38-43. 6p