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Use of Nano-Porous Calcium Silicate for Heavy Metal Removal from Aqueous Solutions

Yıl 2018, Cilt: 2 Sayı: 2, 8 - 13, 01.12.2018

Öz

Water is indispensable
for our life and fresh water resources are becoming rich by heavy metals
particularly by industrial wastes. Heavy metals are very harmful to the living
organisms and accumulated in the food chain. Removal of heavy metals are therefore
very important for protection of ecological systems. In this study, nano-porous
calcium silicate produced from Rice Hull Ash in the laboratory, was used for
the adsorption of copper, lead and zinc ions from an aqueous solution. The
three elements – copper, lead and zinc – were adsorbed on the calcium silicate
surface in ratios of 90-96 % in the first 15 minutes. Before and after the adsorption
experiments, FTIR analyses of calcium silicate samples were done to investigate
the adsorption type which can be chemical or physical.

Kaynakça

  • Anupam, K., Dutta, S., Bhattacharjee, C. and Datta, S., 2011. Adsorptive removal of chromium (VI) from aqueous solution over powdered activated carbon: Optimization through response surface methodology. Chem. Eng. J. 173, 135-143.
  • Borrmann, T., Edgar, K., McFarlane, A.J., Spencer, J.N. and Johnston, J.H., 2004. Calcium silicate-carbon nanotube composites. Current Applied Physics, 4, 359-361.
  • Dai, Y., Zhang, K., Li, J., Jiang, Y. and Tanaka, S., 2017. Adsorption of copper and zinc onto carbon material in an aqueous solution oxidized by ammonium peroxydisulphate. Separation and Purification Technology, 186, 255-263.
  • Ito, Y., Kusakawe, T., Ishida, M., Shibata, N. and Takada, K., 2005. Oral solid gentamicin preparation using emulsifier and adsorbent. J. of Controlled Release, 105, 23-31.
  • Johnston, J.H., McFarlane, A.J., Borrmann, T. and Moraes, J., 2004. Nano structured silicas and silicates-new materials and their applications in Paper. Current Applied Physics, 4, 411-414. Johnston, J.H., McFarlane, A.J. and Borrmann, T., 2008. Nano-structured silicate, functionalized from thereof, preparation and uses. United States Patent and Trademark Office, No: 20080305027 dated 12.11.2008.
  • Li, S.M., Jia, N., Zhu, J.F., Maa, M.G. and Sun, R.C., 2010. Synthesis of cellulose nanocomposites in ethanol/water mixed solvents and their characterization. Carbohydrate Polymers, 80, 270-275.
  • Oglakci, A. and Baglar, B., 2010. Heavy Metal Desorption from the Surfaces of Calcium Silicate and Several Adsorbents. Graduation Project, Istanbul Technical University, Chemical Engineering Dept., Istanbul, Turkey.
  • Pourshakiba, M., 2012. Production of Nano-Porous Calcium Silicate from Rice Hull Ash, Characterization and Use of heavy metal Adsorption. Msc. Thesis, İstanbul technical University, Chemical Engineering Dept., Istanbul, Turkey.
  • Sadic, E., Taspinar, O. and Ozcan, O., 2010. Comparison of surface areas and oleic acid adsorption characteristics of various silicates produced from rice hull ash. Fresenius Environmental Bulletin, 19 (12), 2823-2831.
  • Saravanapavan, P. and Hench, L.L., 2003. Mesoporous calcium silicate glasses. I. Synthesis. J. of Non-Crystalline Solids, 318, 1-13.
  • Souza, C., Majuste, D., Dantas, M.S.S. and Ciminelli, V.S.T., 2018. Effect of zinc ion on copper speciation and adsorption on activated carbon. Hydrometallurgy, 176, 78-86.
  • Taspinar, O., Buyukyilmaz, T., Baglar, T., Kol, I. and Ozcan, O., 2011. Comparison of the heavy metal desorption properties of RHA origin calcium silicate and other adsorbents. Proceedings of the 8th Int. IWA Symposium on Waste Management Problems in Agro-Industries, 22-24 June, 2011, Cesme, Izmir, Turkey.
  • Taspinar, O., Buyukyilmaz, T. and Altmisoglu, A., 2013. Effect of Various Compounds on the Nano-Structured Framework of Calcium Silicate, in: TMS2013 Supplemental Proceedings (ed. TMS), John Wiley & Sons, Inc., NJ, Doi: 10.1002/9781118663547.ch11.
  • Teir, S., Eloneva, S. and Zevenhoven, R., 2005. Production of precipitated calcium carbonate from calcium silicate and carbon dioxide. Energy Conversion and Management, 46, 2954-2979.
  • Wang, Q., Zhang, J.P., Smith, T.R., Hurst, W.E. and Sulpizio, T., 2005. Endotoxin removal using a synthetic adsorbent of crystalline calcium silicate hydrate. Bioethanol. Progress, 21. 1220-1225.
Yıl 2018, Cilt: 2 Sayı: 2, 8 - 13, 01.12.2018

Öz

Kaynakça

  • Anupam, K., Dutta, S., Bhattacharjee, C. and Datta, S., 2011. Adsorptive removal of chromium (VI) from aqueous solution over powdered activated carbon: Optimization through response surface methodology. Chem. Eng. J. 173, 135-143.
  • Borrmann, T., Edgar, K., McFarlane, A.J., Spencer, J.N. and Johnston, J.H., 2004. Calcium silicate-carbon nanotube composites. Current Applied Physics, 4, 359-361.
  • Dai, Y., Zhang, K., Li, J., Jiang, Y. and Tanaka, S., 2017. Adsorption of copper and zinc onto carbon material in an aqueous solution oxidized by ammonium peroxydisulphate. Separation and Purification Technology, 186, 255-263.
  • Ito, Y., Kusakawe, T., Ishida, M., Shibata, N. and Takada, K., 2005. Oral solid gentamicin preparation using emulsifier and adsorbent. J. of Controlled Release, 105, 23-31.
  • Johnston, J.H., McFarlane, A.J., Borrmann, T. and Moraes, J., 2004. Nano structured silicas and silicates-new materials and their applications in Paper. Current Applied Physics, 4, 411-414. Johnston, J.H., McFarlane, A.J. and Borrmann, T., 2008. Nano-structured silicate, functionalized from thereof, preparation and uses. United States Patent and Trademark Office, No: 20080305027 dated 12.11.2008.
  • Li, S.M., Jia, N., Zhu, J.F., Maa, M.G. and Sun, R.C., 2010. Synthesis of cellulose nanocomposites in ethanol/water mixed solvents and their characterization. Carbohydrate Polymers, 80, 270-275.
  • Oglakci, A. and Baglar, B., 2010. Heavy Metal Desorption from the Surfaces of Calcium Silicate and Several Adsorbents. Graduation Project, Istanbul Technical University, Chemical Engineering Dept., Istanbul, Turkey.
  • Pourshakiba, M., 2012. Production of Nano-Porous Calcium Silicate from Rice Hull Ash, Characterization and Use of heavy metal Adsorption. Msc. Thesis, İstanbul technical University, Chemical Engineering Dept., Istanbul, Turkey.
  • Sadic, E., Taspinar, O. and Ozcan, O., 2010. Comparison of surface areas and oleic acid adsorption characteristics of various silicates produced from rice hull ash. Fresenius Environmental Bulletin, 19 (12), 2823-2831.
  • Saravanapavan, P. and Hench, L.L., 2003. Mesoporous calcium silicate glasses. I. Synthesis. J. of Non-Crystalline Solids, 318, 1-13.
  • Souza, C., Majuste, D., Dantas, M.S.S. and Ciminelli, V.S.T., 2018. Effect of zinc ion on copper speciation and adsorption on activated carbon. Hydrometallurgy, 176, 78-86.
  • Taspinar, O., Buyukyilmaz, T., Baglar, T., Kol, I. and Ozcan, O., 2011. Comparison of the heavy metal desorption properties of RHA origin calcium silicate and other adsorbents. Proceedings of the 8th Int. IWA Symposium on Waste Management Problems in Agro-Industries, 22-24 June, 2011, Cesme, Izmir, Turkey.
  • Taspinar, O., Buyukyilmaz, T. and Altmisoglu, A., 2013. Effect of Various Compounds on the Nano-Structured Framework of Calcium Silicate, in: TMS2013 Supplemental Proceedings (ed. TMS), John Wiley & Sons, Inc., NJ, Doi: 10.1002/9781118663547.ch11.
  • Teir, S., Eloneva, S. and Zevenhoven, R., 2005. Production of precipitated calcium carbonate from calcium silicate and carbon dioxide. Energy Conversion and Management, 46, 2954-2979.
  • Wang, Q., Zhang, J.P., Smith, T.R., Hurst, W.E. and Sulpizio, T., 2005. Endotoxin removal using a synthetic adsorbent of crystalline calcium silicate hydrate. Bioethanol. Progress, 21. 1220-1225.
Toplam 15 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Bölüm Articles
Yazarlar

Onur Yılmaz Özcan Bu kişi benim

Yayımlanma Tarihi 1 Aralık 2018
Gönderilme Tarihi 12 Haziran 2018
Yayımlandığı Sayı Yıl 2018 Cilt: 2 Sayı: 2

Kaynak Göster

APA Özcan, O. Y. (2018). Use of Nano-Porous Calcium Silicate for Heavy Metal Removal from Aqueous Solutions. Eurasian Journal of Environmental Research, 2(2), 8-13.
AMA Özcan OY. Use of Nano-Porous Calcium Silicate for Heavy Metal Removal from Aqueous Solutions. EJERE. Aralık 2018;2(2):8-13.
Chicago Özcan, Onur Yılmaz. “Use of Nano-Porous Calcium Silicate for Heavy Metal Removal from Aqueous Solutions”. Eurasian Journal of Environmental Research 2, sy. 2 (Aralık 2018): 8-13.
EndNote Özcan OY (01 Aralık 2018) Use of Nano-Porous Calcium Silicate for Heavy Metal Removal from Aqueous Solutions. Eurasian Journal of Environmental Research 2 2 8–13.
IEEE O. Y. Özcan, “Use of Nano-Porous Calcium Silicate for Heavy Metal Removal from Aqueous Solutions”, EJERE, c. 2, sy. 2, ss. 8–13, 2018.
ISNAD Özcan, Onur Yılmaz. “Use of Nano-Porous Calcium Silicate for Heavy Metal Removal from Aqueous Solutions”. Eurasian Journal of Environmental Research 2/2 (Aralık 2018), 8-13.
JAMA Özcan OY. Use of Nano-Porous Calcium Silicate for Heavy Metal Removal from Aqueous Solutions. EJERE. 2018;2:8–13.
MLA Özcan, Onur Yılmaz. “Use of Nano-Porous Calcium Silicate for Heavy Metal Removal from Aqueous Solutions”. Eurasian Journal of Environmental Research, c. 2, sy. 2, 2018, ss. 8-13.
Vancouver Özcan OY. Use of Nano-Porous Calcium Silicate for Heavy Metal Removal from Aqueous Solutions. EJERE. 2018;2(2):8-13.

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