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ESKİŞEHİR'DE MUTTALİP KİLİ İÇİN UYGULAMALI ARAŞTIRMA

Yıl 2022, Cilt: 10 Sayı: 1, 27 - 34, 25.02.2022
https://doi.org/10.20290/estubtdb.1020747

Öz

Tuğla-kiremit sektörü, Türkiye'nin önemli sanayi kuruluşlarından biri olmasına rağmen, ihtiyacı karşılayabilecek hammadde arayışı önemli sorunlardan biridir. 9. Devlet Kalkınma Planına göre rezervleri yetersiz olan ve aranması gereken kil grubuna dâhildir. Ülkemizde killerin analizi konusunda yeterli çalışma bulunmamaktadır. Bu nedenle Eskişehir ili Muttalip yöresinde kiremit sektöründe kilin uygunluğu araştırılmıştır. X-Işınları Difraksiyonu (XRD), X-Işınları Floresan Spektrometresi (XRF), Taramalı Elektron Mikroskobu (FESEM), partikül analizi sonucunda, kiremit için uygun bulunan kil çamur haline getirildi ve Vakum Presine yerleştirildi. Nem tayin cihazı ile nem analizi sonucunda Vakum Press cihazından tablet kiremitler elde edilmiştir. Elde edilen tablet kiremitler kurutma aşamasında 80°C'de fırınlanmış ve yüzeyde çatlaklar oluşmuştur. Kurutma aşamasındaki bu çatlaklar, doğal kurutma yöntemi veya daha düşük sıcaklıklarda kurutma ile giderilebilmekte ve Muttalip kilinden mukavemeti yüksek bir endüstriyel ürün olan kiremit elde edilebilmektedir.

Destekleyen Kurum

Hatipoğlu Güneş Kiremit ve Tuğla Sanayi A.Ş. fabrikası

Teşekkür

Hatipoğlu Güneş Kiremit ve Tuğla Sanayi A.Ş. fabrikası Ar-Ge laboratuvar tesisleri için ve orada çalışan Maden Yüksek Mühendisi Atakan MUTLU'ya bu çalışmada desteklerinden dolayı teşekkür ederim.

Kaynakça

  • [1] Presidency of the Republic of Turkey, Strategy and Budget Department, Ninth Development Plan report 2007-2013. Turkey, 2006.
  • [2] Nayak PS, Singh BK. Instrumental characterization of clay by XRF, XRD and FTIR. Bulletin of Materials Science 2007; 30(3): 235-238.
  • [3] Grim RE. Clay mineralogy. New York: McGraw-Hill,1968.
  • [4] Chang LLY. Industrial mineralogy: Materials, processes, and uses. Upper Saddle River, New Jersey: Prentice Hall, 2002.
  • [5] Grim R. Some applications of clay mineralogy. Am Mineral 1960; 45: 259-269.
  • [6] Celik H. Technological characterization and industrial application of two Turkish clays for the ceramic industry. Applied Clay Science 2010; 50(2): 245-254.
  • [7] Kamseu E, Leonelli C, Boccaccini DN, Veronesi P, Miselli P, Pellacani G, Melo UC. Characterisation of porcelain compositions using two China clays from Cameroon. Ceramics International 2007; 33(5): 851-857.
  • [8] Zhang MY, Sun H, Song C, Li Y, Hou M. Pores Evolution of Soft Clay under Loading/Unloading Process. Applied Sciences-Basel 2020; 10(23) 8468.
  • [9] Kreimeyer R. Some notes on the firing color of clay bricks. Appl. Clay Sci. 1987; 2: 175-183.
  • [10] Fisher P. Some comments on the color of fired clays. Ziegelindustrie Int. 1984; 37: 475-483.
  • [11] Wijeyesekera DC, Ho MH, Bai X, Bakar IBH. Strength and Stiffness Development in Soft Soils: A FESEM aided Soil Microstructure Viewpoint IOP Conf. Series: Materials Science and Engineering 2016; 136: 012041.
  • [12] Staudigel PT, Swart PK. Isotopic behavior during the aragonite-calcite transition: Implications for sample preparation and proxy interpretation. Chemical Geology 2016; 442: 130-138.
  • [13] Ulian G, Moro D, Valdre G. Infrared and Raman spectroscopic features of clinochlore Mg6Si4O10(OH)(8): A density functional theory contribution. Applied Clay Science 2020; 197.
  • [14] Cloutier J, Piercey SJ, Huntington J. Mineralogy, Mineral Chemistry and SWIR Spectral Reflectance of Chlorite and White Mica. Minerals 2021; 11(5). [15] Kwon S, Kim Y, Roh, Y. Cesium removal using acid- and base-activated biotite and illite. Journal of Hazardous Materials 2021; 401.
  • [16] Wang YB, Wang Y, Wen K, Dang W, Xun J. Strengthening the inhibition effect of sodium silicate on muscovite by electrochemical modification. Minerals Engineering 2021; 161.
  • [17] Monteiro SN, Vieira CMF. Influence of firing temperature on the ceramic properties of clays from Campos dos Goytacazes, Brazil. Applied Clay Science 2004; 27(3-4): 229-234.
  • [18] Clausell JV, Bastida J, Serrano FJ, Pardo P, Huertas FJ. A new FESEM procedure for assessment of XRD microstructural data of kaolinites. Applied Clay Science 2007; 37(1-2): 127-132.
  • [19] Sun H, Hou MX, Chen C, Ge X. Microstructure investigation of soft clay subjected to triaxial loading. Engineering Geology 2020; 274.
  • [20] Guo M, Liang Y, Cai M, Nie J, Ju M, Liu M, Jiang G. Improved slag resistance of taphole clay due to in situ formation of TiCN from ferrotitanium slag. Ceramics International 2021; 47(16): 23630-23636.
  • [21] Muleja AA, Mubiayi MP, Hassard F, Mamba BB. Titania containing natural clay doped with carbon nanotubes for enhanced natural photocatalytic discoloration of wastewater. Journal of Nanoparticle Research 2021; 23(4).
  • [22] Celik H. Technological Characterization and Comparison of two Ceramic Clays Used for Manufacturing of Traditional Ceramic Products in Turkey. Scientific Mining Journal 2017; 56: 137-147.
  • [23] Aungatichart P, Wada S. Correlation between Bigot and Ratzenberger drying sensitivity indices of red clay from Ratchaburi province (Thailand). Applied Clay Science 2009; 43(2): 182-185.
  • [24] Baccour H, Medhioub M, Jamoussi F, Mhiri T. Densification Behaviour of a Red Firing Tunisian Triassic Clay. American Journal of Applied Sciences 2008; 5: 263-269.
  • [25] Mahmoudi S, Zargouni F. Simultaneous Optimisation of Drying Parameters of Ceramic Bodies. Current Research in Geoscience 2014; 4(1): 1-7.
  • [26] Schneider HE, Hanke W. Determination of the Drying Crack Sensitivity of Structural Ceramics and Heavy Clay Raw Materials. Ziegelindustrie International 1996; 7(8):168-480.

APPLIED RESEARCH INTO MUTTALIP CLAY IN ESKISEHIR

Yıl 2022, Cilt: 10 Sayı: 1, 27 - 34, 25.02.2022
https://doi.org/10.20290/estubtdb.1020747

Öz

Although the brick-tile industry is one of the important industrial establishments in Turkey, the search for raw materials that can meet the needs is one of the important problems. According to the 9th State Development Plan, it is included in the clay group, which has insufficient reserves and must be sought. There are not enough studies on the analysis of clays in our country. For this reason, the suitability of clay in the tile sector in the Muttalip region of Eskisehir province was investigated. As a result of X-Ray Diffraction (XRD), X-Ray Fluorescence Spectrometer (XRF), Scanning Electron Microscopy (FESEM), particle analysis, the clay, which was found to be suitable for tiles, was slurred and inserted into Vacuum Press devices as a result of moisture analysis, and tablet tiles were obtained. The tiles obtained were baked at 80°C during the drying phase and cracks were formed on the surface. These cracks in the drying stage can be resolved by natural drying method or drying at lower temperatures, and tile, which is an industrial product with high strength, can be obtained from Muttalip clay.

Kaynakça

  • [1] Presidency of the Republic of Turkey, Strategy and Budget Department, Ninth Development Plan report 2007-2013. Turkey, 2006.
  • [2] Nayak PS, Singh BK. Instrumental characterization of clay by XRF, XRD and FTIR. Bulletin of Materials Science 2007; 30(3): 235-238.
  • [3] Grim RE. Clay mineralogy. New York: McGraw-Hill,1968.
  • [4] Chang LLY. Industrial mineralogy: Materials, processes, and uses. Upper Saddle River, New Jersey: Prentice Hall, 2002.
  • [5] Grim R. Some applications of clay mineralogy. Am Mineral 1960; 45: 259-269.
  • [6] Celik H. Technological characterization and industrial application of two Turkish clays for the ceramic industry. Applied Clay Science 2010; 50(2): 245-254.
  • [7] Kamseu E, Leonelli C, Boccaccini DN, Veronesi P, Miselli P, Pellacani G, Melo UC. Characterisation of porcelain compositions using two China clays from Cameroon. Ceramics International 2007; 33(5): 851-857.
  • [8] Zhang MY, Sun H, Song C, Li Y, Hou M. Pores Evolution of Soft Clay under Loading/Unloading Process. Applied Sciences-Basel 2020; 10(23) 8468.
  • [9] Kreimeyer R. Some notes on the firing color of clay bricks. Appl. Clay Sci. 1987; 2: 175-183.
  • [10] Fisher P. Some comments on the color of fired clays. Ziegelindustrie Int. 1984; 37: 475-483.
  • [11] Wijeyesekera DC, Ho MH, Bai X, Bakar IBH. Strength and Stiffness Development in Soft Soils: A FESEM aided Soil Microstructure Viewpoint IOP Conf. Series: Materials Science and Engineering 2016; 136: 012041.
  • [12] Staudigel PT, Swart PK. Isotopic behavior during the aragonite-calcite transition: Implications for sample preparation and proxy interpretation. Chemical Geology 2016; 442: 130-138.
  • [13] Ulian G, Moro D, Valdre G. Infrared and Raman spectroscopic features of clinochlore Mg6Si4O10(OH)(8): A density functional theory contribution. Applied Clay Science 2020; 197.
  • [14] Cloutier J, Piercey SJ, Huntington J. Mineralogy, Mineral Chemistry and SWIR Spectral Reflectance of Chlorite and White Mica. Minerals 2021; 11(5). [15] Kwon S, Kim Y, Roh, Y. Cesium removal using acid- and base-activated biotite and illite. Journal of Hazardous Materials 2021; 401.
  • [16] Wang YB, Wang Y, Wen K, Dang W, Xun J. Strengthening the inhibition effect of sodium silicate on muscovite by electrochemical modification. Minerals Engineering 2021; 161.
  • [17] Monteiro SN, Vieira CMF. Influence of firing temperature on the ceramic properties of clays from Campos dos Goytacazes, Brazil. Applied Clay Science 2004; 27(3-4): 229-234.
  • [18] Clausell JV, Bastida J, Serrano FJ, Pardo P, Huertas FJ. A new FESEM procedure for assessment of XRD microstructural data of kaolinites. Applied Clay Science 2007; 37(1-2): 127-132.
  • [19] Sun H, Hou MX, Chen C, Ge X. Microstructure investigation of soft clay subjected to triaxial loading. Engineering Geology 2020; 274.
  • [20] Guo M, Liang Y, Cai M, Nie J, Ju M, Liu M, Jiang G. Improved slag resistance of taphole clay due to in situ formation of TiCN from ferrotitanium slag. Ceramics International 2021; 47(16): 23630-23636.
  • [21] Muleja AA, Mubiayi MP, Hassard F, Mamba BB. Titania containing natural clay doped with carbon nanotubes for enhanced natural photocatalytic discoloration of wastewater. Journal of Nanoparticle Research 2021; 23(4).
  • [22] Celik H. Technological Characterization and Comparison of two Ceramic Clays Used for Manufacturing of Traditional Ceramic Products in Turkey. Scientific Mining Journal 2017; 56: 137-147.
  • [23] Aungatichart P, Wada S. Correlation between Bigot and Ratzenberger drying sensitivity indices of red clay from Ratchaburi province (Thailand). Applied Clay Science 2009; 43(2): 182-185.
  • [24] Baccour H, Medhioub M, Jamoussi F, Mhiri T. Densification Behaviour of a Red Firing Tunisian Triassic Clay. American Journal of Applied Sciences 2008; 5: 263-269.
  • [25] Mahmoudi S, Zargouni F. Simultaneous Optimisation of Drying Parameters of Ceramic Bodies. Current Research in Geoscience 2014; 4(1): 1-7.
  • [26] Schneider HE, Hanke W. Determination of the Drying Crack Sensitivity of Structural Ceramics and Heavy Clay Raw Materials. Ziegelindustrie International 1996; 7(8):168-480.
Toplam 25 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Makaleler
Yazarlar

Hülya Kuru Mutlu 0000-0002-6955-5851

Yayımlanma Tarihi 25 Şubat 2022
Yayımlandığı Sayı Yıl 2022 Cilt: 10 Sayı: 1

Kaynak Göster

APA Kuru Mutlu, H. (2022). APPLIED RESEARCH INTO MUTTALIP CLAY IN ESKISEHIR. Eskişehir Teknik Üniversitesi Bilim Ve Teknoloji Dergisi B - Teorik Bilimler, 10(1), 27-34. https://doi.org/10.20290/estubtdb.1020747
AMA Kuru Mutlu H. APPLIED RESEARCH INTO MUTTALIP CLAY IN ESKISEHIR. Estuscience - Theory. Şubat 2022;10(1):27-34. doi:10.20290/estubtdb.1020747
Chicago Kuru Mutlu, Hülya. “APPLIED RESEARCH INTO MUTTALIP CLAY IN ESKISEHIR”. Eskişehir Teknik Üniversitesi Bilim Ve Teknoloji Dergisi B - Teorik Bilimler 10, sy. 1 (Şubat 2022): 27-34. https://doi.org/10.20290/estubtdb.1020747.
EndNote Kuru Mutlu H (01 Şubat 2022) APPLIED RESEARCH INTO MUTTALIP CLAY IN ESKISEHIR. Eskişehir Teknik Üniversitesi Bilim ve Teknoloji Dergisi B - Teorik Bilimler 10 1 27–34.
IEEE H. Kuru Mutlu, “APPLIED RESEARCH INTO MUTTALIP CLAY IN ESKISEHIR”, Estuscience - Theory, c. 10, sy. 1, ss. 27–34, 2022, doi: 10.20290/estubtdb.1020747.
ISNAD Kuru Mutlu, Hülya. “APPLIED RESEARCH INTO MUTTALIP CLAY IN ESKISEHIR”. Eskişehir Teknik Üniversitesi Bilim ve Teknoloji Dergisi B - Teorik Bilimler 10/1 (Şubat 2022), 27-34. https://doi.org/10.20290/estubtdb.1020747.
JAMA Kuru Mutlu H. APPLIED RESEARCH INTO MUTTALIP CLAY IN ESKISEHIR. Estuscience - Theory. 2022;10:27–34.
MLA Kuru Mutlu, Hülya. “APPLIED RESEARCH INTO MUTTALIP CLAY IN ESKISEHIR”. Eskişehir Teknik Üniversitesi Bilim Ve Teknoloji Dergisi B - Teorik Bilimler, c. 10, sy. 1, 2022, ss. 27-34, doi:10.20290/estubtdb.1020747.
Vancouver Kuru Mutlu H. APPLIED RESEARCH INTO MUTTALIP CLAY IN ESKISEHIR. Estuscience - Theory. 2022;10(1):27-34.