Tungsten(VI) Oxide Supported Rhodium(0) Nanoparticles Used as Catalyst in Hydrogenation of Benzene at Room Temperature

Serap Albayrak

EN

Tungsten(VI) Oxide Supported Rhodium(0) Nanoparticles Used as Catalyst in Hydrogenation of Benzene at Room Temperature

Abstract

Rhodium(III) ions were first impregnated on the surface of tungsten(VI) oxide (WO3 ) in aqueous solution and reduced with aqueous NaBH4 to form rhodium(0) nanoparticles (Rh NPs) on the surface of WO3. After the isolation of the Rh NPs/WO3 catalyst by centrifugation, it was characterized by advanced analytical techniques. The results reveal the successful formation of Rh NPs on the surface of WO3. Rh NPs/WO3 catalyst with a turnover frequency value of 131 h-1 was found to be very active in hydrogenation of neat benzene at 25.0±0.1ºC.

Keywords

Tungsten(VI) oxide,rhodium nanoparticles,benzene,hydrogenation

References

. . .

Details

Primary Language

English

Subjects

Engineering

Journal Section

Research Article

Authors

Serap Albayrak
Türkiye

Publication Date

November 1, 2018

Submission Date

April 25, 2018

Acceptance Date

July 6, 2018

Published in Issue

Year 2018 Volume: 46 Number: 4

IZ

https://izlik.org/JA69SZ36HZ

Cite

RIS / Bibtex

APA

Albayrak, S. (2018). Tungsten(VI) Oxide Supported Rhodium(0) Nanoparticles Used as Catalyst in Hydrogenation of Benzene at Room Temperature. Hacettepe Journal of Biology and Chemistry, 46(4), 465-472. https://izlik.org/JA69SZ36HZ

AMA

1.Albayrak S. Tungsten(VI) Oxide Supported Rhodium(0) Nanoparticles Used as Catalyst in Hydrogenation of Benzene at Room Temperature. HJBC. 2018;46(4):465-472. https://izlik.org/JA69SZ36HZ

Chicago

Albayrak, Serap. 2018. “Tungsten(VI) Oxide Supported Rhodium(0) Nanoparticles Used As Catalyst in Hydrogenation of Benzene at Room Temperature”. Hacettepe Journal of Biology and Chemistry 46 (4): 465-72. https://izlik.org/JA69SZ36HZ.

EndNote

Albayrak S (November 1, 2018) Tungsten(VI) Oxide Supported Rhodium(0) Nanoparticles Used as Catalyst in Hydrogenation of Benzene at Room Temperature. Hacettepe Journal of Biology and Chemistry 46 4 465–472.

IEEE

[1]S. Albayrak, “Tungsten(VI) Oxide Supported Rhodium(0) Nanoparticles Used as Catalyst in Hydrogenation of Benzene at Room Temperature”, HJBC, vol. 46, no. 4, pp. 465–472, Nov. 2018, [Online]. Available: https://izlik.org/JA69SZ36HZ

ISNAD

Albayrak, Serap. “Tungsten(VI) Oxide Supported Rhodium(0) Nanoparticles Used As Catalyst in Hydrogenation of Benzene at Room Temperature”. Hacettepe Journal of Biology and Chemistry 46/4 (November 1, 2018): 465-472. https://izlik.org/JA69SZ36HZ.

JAMA

1.Albayrak S. Tungsten(VI) Oxide Supported Rhodium(0) Nanoparticles Used as Catalyst in Hydrogenation of Benzene at Room Temperature. HJBC. 2018;46:465–472.

MLA

Albayrak, Serap. “Tungsten(VI) Oxide Supported Rhodium(0) Nanoparticles Used As Catalyst in Hydrogenation of Benzene at Room Temperature”. Hacettepe Journal of Biology and Chemistry, vol. 46, no. 4, Nov. 2018, pp. 465-72, https://izlik.org/JA69SZ36HZ.

Vancouver

1.Serap Albayrak. Tungsten(VI) Oxide Supported Rhodium(0) Nanoparticles Used as Catalyst in Hydrogenation of Benzene at Room Temperature. HJBC [Internet]. 2018 Nov. 1;46(4):465-72. Available from: https://izlik.org/JA69SZ36HZ