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Synthesis of the 4-N,N-Dimethylaminobenzoic Acid Complexes of Mn II , Co II , Ni II , and Cu II . Spectroscopic and Thermal Characterization

Yıl 2008, Cilt: 36 Sayı: 1, 31 - 39, 01.01.2008

Özgür Aybirdi Dursun Ali Kose Hacali Necefoglu

Öz

4-N,N-dimethylaminobenzoic acid complexes of Mn II , Co II , Ni II and Cu II were synthesised and their structuralproperties were investigated by employing elemental analysis, magnetic susceptibilitiy, solid state UV-vis, directinjection probe mass, FTIR and thermoanalytic TG-DTG methods.According to the microanalytical results, formulaof complexes are CMn, C H NO H NOCo, CNi and CH NO H NOCu. The complexes of Mn II and Ni II contain four moles of coordination waters, but Co II and Cu II complexes have two moles of coordinatedwater ligands. All of the complexes include two moles 4-N,N-dimethylaminobenzoate ligands, but it was coordinatedto metal atom as monodentate in Mn II and Ni II and bidentate in Co II and Cu II complexes.It was found that ratioof metal:ligand is 1:2 and the decomposition of each complex starts with dehydration and follows by decompositionof organic part, respectively. The thermal dehydration of the complexes takes place in steps from one to two. Thedecomposition mechanism and thermal stability of the investigated complexes are interpreted in terms of theirstructures. The final decomposition products are found to be the respective metal oxides

Anahtar Kelimeler

4-N N-dimethylaminobenzoate Thermal decomposition metal complexes transition metal compounds

Kaynakça

  • 1. W. Ferenc, B. Cristovao, B. Mazurek and J. Sarzynski, Journal of the Serbian Chemical Society 71(8-9) (2006) 929.
  • 2. D. Baiiley, D. Tirrell, O. Vogl., J. Macromol. Sci., Chem., A12(5) (1978) 661.
  • 3. J.B. Randal, L.L. Melvin, W.K. James, (Stepan Co.) Eur. Pat. Appl. EP 220,934 (Cl. C07F5/06), 06 May 1987, US Appl. 790,486, 23 Oct 1985 p.49.
  • 4. Kanebo Ltd, Jpn. Kokai Tokyo Koho Jp 60,130,654 [85,130,654] (Cl. C09C3/08), 12 Jul 1985, Appl. 83/240,031, 19 Dec 1983; 9.
  • 5 Kanebo Ltd. Jpn. Kokai Tokyo Koho JP 60,94,949[85,94,949] (Cl.C07C101/60), 28 May 1985, Appl. 83/203,539, 29 Oct 1983, 6
  • 6 Mori, Makoto (Otsuka Pharmaceutical Co., Ltd.; Mori, Masamoto; Nagamine, Takeaki; Kuboki, Makoto, Japan) PCT Int. Appl. WO 96 41,643 (Cl.A61K38/21), 27 Dec 1996, JP Appl. 96/51,784, 8 Mar 1996; 25.
  • 7. Kysel O., Z. Phys. Chem., 89(1-4) (1974) p.62.
  • 8. K.Y. Hee, C.D. Won, Y. Minjoong, K. Dongho., J. Photosci., 3(3) (1996) 153.
  • 9. Y.B. Jiang, X.J. Wang M.G.Jin, L.R. Lin, J.Photochem. Photobio., A126(1-3), (1999) 125.
  • 10. Y.B. Jiang, Chinese. Sci. Bull., 39(14) (1994) 1179.
  • 11. Y.H. Kim, D.W. Cho, M. Yoon D. Kim, J. Phys. Chem., 100(39) (1996) 15670.
  • 12. M. Yoon, D.P.S Negi., Proc. Indian Acad. Sci.- Chem. Sci., 114(6) (2002) 593.
  • 13. T. Gunnlaugsson, A.J. Harte; J.P. Leonard, M. Nieuwenhuyzen, Supramol. Chem., 15(7-8) (2003) 505.
  • 14. J. Rawlings; C.A.L. Mahaffy, Spectrosc. Lett., 21(7) (1988) 597.
  • 15. J.M. Salvatore, G.Sugerman (Kenrich Petrochemicals, Inc.) Ger. Offen. 2,703,829 (Cl. C08K5/56), 04 Aug 1977, US Appl. 653,773, 30 Jan 1976, 3
  • 16. T. Hökelek and H. Necefoglu, Acta Cryst., E63 (2007) 821.
  • 17. D.A. Kose, MSc. Thesis, Univ. Kafkas (2001).
  • 18. Ö. Aybirdi, MSc. Thesis, Univ. Kafkas (2001).
  • 19. D.A. Köse, Russ. J. Inorg. Chem., 52(9) (2007) 1384.
  • 20. H. Icbudak, H. Olmez, O.Z. Yesilel, F. Arslan, P. Naumov, G. Jovanovski, A.R. Ibrahim, A. Usman, H.K. Fun, S. Chantrapromma and S.W. Ng, J. Mol. Struct., 6572 (2003) 55.
  • 21. D.A. Köse, B. Zümreoglu-Karan, O. ahin and O. Büyükgüngör, J. Mol. Struct., 789(1-3) (2006) 147.
  • 22. D.A. Köse, B. Zümreoglu-Karan, C. Unaleroğlu, O. ahin and O. Büyükgüngör, J. Coord. Chem., 18 (2006) 2125.
  • 23. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, Wiley and Sons, New York, (1978) 197.
  • 24. J. Zsakó, G. Pokol, Cs. Novák, Cs. Várhelyi, A. Dobó and G. Liptay, J. Therm. Anal. Cal., 64, (2001) 843.
  • 25. H. Icbudak, Z. Heren, D.A. Kose and H. Necefoglu, J. Therm. Anal.Cal., 76 (2004) 837.
  • 26. W. Ferenc and A.W. Dziewulska, J. Therm. Analys. Cal., 71 (2000) 923.
  • 27. W. Ferenc, B. Cristovao, and J. Sarzynski, J. Therm. Analys. Cal., 86(3) (2006) 783.
  • 28. D.A. Köse, E.F. Öztürkkan, H. Necefoğlu, İ. Uzun, Assian J. Chem., 19(6) (2007) 4880.
  • 29. D.A. Köse, A. Kaya, H. Necefoğlu, Russ. J. Coord. Chem., 33(6) (2007) 422.
  • 30. D.A.Köse, H. İçbudak and H. Necefoğlu, Hacettepe J. Biol. & Chem., 35(2) (2007) 123.
  • 31. D.A. Köse, B. Zümreoglu-Karan, B. Koşar and O. Büyükgüngör, J. Chem. Cryst. (Online published 4 December 2007).

Yıl 2008, Cilt: 36 Sayı: 1, 31 - 39, 01.01.2008

Özgür Aybirdi Dursun Ali Kose Hacali Necefoglu

Öz

Kaynakça

  • 1. W. Ferenc, B. Cristovao, B. Mazurek and J. Sarzynski, Journal of the Serbian Chemical Society 71(8-9) (2006) 929.
  • 2. D. Baiiley, D. Tirrell, O. Vogl., J. Macromol. Sci., Chem., A12(5) (1978) 661.
  • 3. J.B. Randal, L.L. Melvin, W.K. James, (Stepan Co.) Eur. Pat. Appl. EP 220,934 (Cl. C07F5/06), 06 May 1987, US Appl. 790,486, 23 Oct 1985 p.49.
  • 4. Kanebo Ltd, Jpn. Kokai Tokyo Koho Jp 60,130,654 [85,130,654] (Cl. C09C3/08), 12 Jul 1985, Appl. 83/240,031, 19 Dec 1983; 9.
  • 5 Kanebo Ltd. Jpn. Kokai Tokyo Koho JP 60,94,949[85,94,949] (Cl.C07C101/60), 28 May 1985, Appl. 83/203,539, 29 Oct 1983, 6
  • 6 Mori, Makoto (Otsuka Pharmaceutical Co., Ltd.; Mori, Masamoto; Nagamine, Takeaki; Kuboki, Makoto, Japan) PCT Int. Appl. WO 96 41,643 (Cl.A61K38/21), 27 Dec 1996, JP Appl. 96/51,784, 8 Mar 1996; 25.
  • 7. Kysel O., Z. Phys. Chem., 89(1-4) (1974) p.62.
  • 8. K.Y. Hee, C.D. Won, Y. Minjoong, K. Dongho., J. Photosci., 3(3) (1996) 153.
  • 9. Y.B. Jiang, X.J. Wang M.G.Jin, L.R. Lin, J.Photochem. Photobio., A126(1-3), (1999) 125.
  • 10. Y.B. Jiang, Chinese. Sci. Bull., 39(14) (1994) 1179.
  • 11. Y.H. Kim, D.W. Cho, M. Yoon D. Kim, J. Phys. Chem., 100(39) (1996) 15670.
  • 12. M. Yoon, D.P.S Negi., Proc. Indian Acad. Sci.- Chem. Sci., 114(6) (2002) 593.
  • 13. T. Gunnlaugsson, A.J. Harte; J.P. Leonard, M. Nieuwenhuyzen, Supramol. Chem., 15(7-8) (2003) 505.
  • 14. J. Rawlings; C.A.L. Mahaffy, Spectrosc. Lett., 21(7) (1988) 597.
  • 15. J.M. Salvatore, G.Sugerman (Kenrich Petrochemicals, Inc.) Ger. Offen. 2,703,829 (Cl. C08K5/56), 04 Aug 1977, US Appl. 653,773, 30 Jan 1976, 3
  • 16. T. Hökelek and H. Necefoglu, Acta Cryst., E63 (2007) 821.
  • 17. D.A. Kose, MSc. Thesis, Univ. Kafkas (2001).
  • 18. Ö. Aybirdi, MSc. Thesis, Univ. Kafkas (2001).
  • 19. D.A. Köse, Russ. J. Inorg. Chem., 52(9) (2007) 1384.
  • 20. H. Icbudak, H. Olmez, O.Z. Yesilel, F. Arslan, P. Naumov, G. Jovanovski, A.R. Ibrahim, A. Usman, H.K. Fun, S. Chantrapromma and S.W. Ng, J. Mol. Struct., 6572 (2003) 55.
  • 21. D.A. Köse, B. Zümreoglu-Karan, O. ahin and O. Büyükgüngör, J. Mol. Struct., 789(1-3) (2006) 147.
  • 22. D.A. Köse, B. Zümreoglu-Karan, C. Unaleroğlu, O. ahin and O. Büyükgüngör, J. Coord. Chem., 18 (2006) 2125.
  • 23. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, Wiley and Sons, New York, (1978) 197.
  • 24. J. Zsakó, G. Pokol, Cs. Novák, Cs. Várhelyi, A. Dobó and G. Liptay, J. Therm. Anal. Cal., 64, (2001) 843.
  • 25. H. Icbudak, Z. Heren, D.A. Kose and H. Necefoglu, J. Therm. Anal.Cal., 76 (2004) 837.
  • 26. W. Ferenc and A.W. Dziewulska, J. Therm. Analys. Cal., 71 (2000) 923.
  • 27. W. Ferenc, B. Cristovao, and J. Sarzynski, J. Therm. Analys. Cal., 86(3) (2006) 783.
  • 28. D.A. Köse, E.F. Öztürkkan, H. Necefoğlu, İ. Uzun, Assian J. Chem., 19(6) (2007) 4880.
  • 29. D.A. Köse, A. Kaya, H. Necefoğlu, Russ. J. Coord. Chem., 33(6) (2007) 422.
  • 30. D.A.Köse, H. İçbudak and H. Necefoğlu, Hacettepe J. Biol. & Chem., 35(2) (2007) 123.
  • 31. D.A. Köse, B. Zümreoglu-Karan, B. Koşar and O. Büyükgüngör, J. Chem. Cryst. (Online published 4 December 2007).
Toplam 31 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Bölüm Research Article
Yazarlar

Özgür Aybirdi Bu kişi benim

Dursun Ali Kose Bu kişi benim

Hacali Necefoglu Bu kişi benim

Yayımlanma Tarihi 1 Ocak 2008
Yayımlandığı Sayı Yıl 2008 Cilt: 36 Sayı: 1

Kaynak Göster

APA Aybirdi, Ö., Kose, D. A., & Necefoglu, H. (2008). Synthesis of the 4-N,N-Dimethylaminobenzoic Acid Complexes of Mn II , Co II , Ni II , and Cu II . Spectroscopic and Thermal Characterization. Hacettepe Journal of Biology and Chemistry, 36(1), 31-39.
AMA Aybirdi Ö, Kose DA, Necefoglu H. Synthesis of the 4-N,N-Dimethylaminobenzoic Acid Complexes of Mn II , Co II , Ni II , and Cu II . Spectroscopic and Thermal Characterization. HJBC. Ocak 2008;36(1):31-39.
Chicago Aybirdi, Özgür, Dursun Ali Kose, ve Hacali Necefoglu. “Synthesis of the 4-N,N-Dimethylaminobenzoic Acid Complexes of Mn II , Co II , Ni II , and Cu II . Spectroscopic and Thermal Characterization”. Hacettepe Journal of Biology and Chemistry 36, sy. 1 (Ocak 2008): 31-39.
EndNote Aybirdi Ö, Kose DA, Necefoglu H (01 Ocak 2008) Synthesis of the 4-N,N-Dimethylaminobenzoic Acid Complexes of Mn II , Co II , Ni II , and Cu II . Spectroscopic and Thermal Characterization. Hacettepe Journal of Biology and Chemistry 36 1 31–39.
IEEE Ö. Aybirdi, D. A. Kose, ve H. Necefoglu, “Synthesis of the 4-N,N-Dimethylaminobenzoic Acid Complexes of Mn II , Co II , Ni II , and Cu II . Spectroscopic and Thermal Characterization”, HJBC, c. 36, sy. 1, ss. 31–39, 2008.
ISNAD Aybirdi, Özgür vd. “Synthesis of the 4-N,N-Dimethylaminobenzoic Acid Complexes of Mn II , Co II , Ni II , and Cu II . Spectroscopic and Thermal Characterization”. Hacettepe Journal of Biology and Chemistry 36/1 (Ocak 2008), 31-39.
JAMA Aybirdi Ö, Kose DA, Necefoglu H. Synthesis of the 4-N,N-Dimethylaminobenzoic Acid Complexes of Mn II , Co II , Ni II , and Cu II . Spectroscopic and Thermal Characterization. HJBC. 2008;36:31–39.
MLA Aybirdi, Özgür vd. “Synthesis of the 4-N,N-Dimethylaminobenzoic Acid Complexes of Mn II , Co II , Ni II , and Cu II . Spectroscopic and Thermal Characterization”. Hacettepe Journal of Biology and Chemistry, c. 36, sy. 1, 2008, ss. 31-39.
Vancouver Aybirdi Ö, Kose DA, Necefoglu H. Synthesis of the 4-N,N-Dimethylaminobenzoic Acid Complexes of Mn II , Co II , Ni II , and Cu II . Spectroscopic and Thermal Characterization. HJBC. 2008;36(1):31-9.

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