The Mathematical and Graphical Interpretation of Solubility Profile-Viscosity Behavior of Poly MA-alt-NVP ​

Year 2012, Volume: 40 Issue: 3, 239 - 250, 01.08.2012

Deniz Demircan Bozdoğan Günay Kibarer Ali Güner Zakir M.o. Rzayev

Abstract

Alternating copolymer of maleic anhydride MA with N-vinyl-2-pyrrolidone NVP is synthesized by free radical polymerization reaction. Solubility of the copolymer in certain solvents is investigated by different algorithmic approaches such as Van Krevelen Hoftyzer VKH , Hoy and Askadskii. Spectral characterization of that copolymer is achieved by FTIR, 1H, 13C NMR spectroscopic methods whereas the polymer hydrodynamic behavior of the copolymer is investigated by viscometric method for comparison purpose with that obtained from the solubility profile through algorithmic calculations.

Keywords

Poly MA-alt-NVP, Solubility parameter, Viscometry, FTIR

Poly MA-alt-NVP Kopolimerinin Çözünürlük Profili- Vizkozite Davranışına Grafiksel ve Matematiksel Olarak Açıklık Getirilmesi

Abstract

M aleik anhidritin MA N-vinil-2-pirolidon NVP ile ardışık kopolimeri serbest radikal kopolimerleşme reaksiyonu ile sentezlendi. Kopolimerin çeşitli çözücülerdeki çözünürlüğü, Van Krevelen Hoftyzer VKH , Hoy ve Askadskii gibi değişik algoritmik yaklaşımlarla irdelendi. Kopolimerin spektral karakterizasyonu, FTIR, 1H, 13C NMR gibi spektroskopik yöntemlerle gerçekleştirilirken, polimer hidrodinamik davranışı ise algoritmik hesaplamalar yoluyla elde edilen çözünürlük profili verilerinin vizkometrik metod kullanılarak elde edilen verilerle karşılaştırılmasıyla araştırıldı

Keywords

Poli MA-ard-NVP , Çözünürlük parametresi, Vizkometri, FTIR.

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