Sol-gel Preparation of Silan based Zirconia Hybrid Thin Film

Öz

The sol-gel process is an innovative advanced method, initially developed to synthesize glass and ceramics at low temperature. Sol-gel process can be used to synthesis materials with a variety of shapes, such as porous membranes, thin fibers, nano-size powders and thin films. In this study, epoxy and methacrylate based silane coupling agents are used together with zirconium oxide to form a hybrid coating system on glass surface. In the experimental study, an organic–inorganic molecular hybrid compound was prepared by sol-gel method. First glasses were cleaned by traditional piranha solution (3:1 H2SO4 : H2O2) to remove contaminants. Silanization was applied to increase the adhesion of hybrid coatings on glass substrates. Glass substrate was coated with this solution by a homemade dip-coater. In this study, (3-Glycidoxypropyltrimethoxysilane, GLYMO and 3-(trimethoxysilyl)propylmethacrylate, TMSPM) were chosen as a silane. Zirconia is inorganic component of hybrid materails. Coated samples were characterized by Fouirer Transform Infrared Spectrophotometer (FTIR), Scanning Electron Microscope with Energy Dispersive X-ray Spectroscopy (SEM-EDX) and Contact Angle Goniometer.

Anahtar Kelimeler

• silane,coating,sol-gel,zirconia

Kaynakça

1. [1] Garcia J. C., Scolfaro L. M. R., Lino A. T., Freire V. N., Farias G. A., Silva C. C., Leite Alves H. W., Rodrigues S. C. P. and da Silva Jr E. F.. “Structural, electronic, and optical properties of ZrO2 from ab initio calculations” Journal of Applied Physics 100, 104103 (2006) Doi:10.1063/1.2386967 [2] Ciuparu D., Ensuque A., Shafeev G., Bozon-Verduraz F. “Synthesis and apparent bandgap of nanophase zirconia” Journal Of Materials Science Letters 19 (2000) 931– 933. Doi:10.1023/A:1006799701474 [3] Patel U.S., Patel K.H., Chauhan K.V., Chawla A.K., Rawal S.K. “Investigation of various properties for zirconium oxide films synthesized by sputtering” Procedia Technology 23 ( 2016 ) 336 – 343. Doi:10.1016/j.protcy.2016.03.035 [4] Adnan M. M., Dalod A. R. M., Balci M.H., Glaum J. and Einarsrud M.A. “In Situ Synthesis of Hybrid Inorganic–Polymer Nanocomposites” Polymers 10 (2018) 1129. Doi:10.3390/polym10101129 [5] Yedikardeş F.B. “Preparation And Characterization Of Anti Bacterial, Anti Scratch And Easy To Clean Multifunctional Coatings By Sol Gel Method”, M.Sc. Thesis, ITU, June 2016 [6] Bezir N. Çiçek, Evcin A., Kayali R., Özen M.K., Balyaci G. “Comparison of Pure and Doped TiO2 Thin Films Prepared by Sol-Gel Spin-Coating Method” ACTA PHYSICA POLONICA A, 132 (2017) page 620-624 Doi:10.12693/APhysPolA.132.620 [7] Adamczyk A., “The influence of ZrO2 precursor type on the structure of ZrO2-TiO2-SiO2 gels and selected thin films”, Journal of Molecular Structure 1171 (2018) 706-716 Doi:10.1016/j.molstruc.2018.06.068 [8] Halbus A.F., Horozov T.S. and Paunov V.N. “Self-grafting copper oxide nanoparticles show a strong enhancement of their anti-algal and anti-yeast action” Nanoscale Advances 1 (2019) 2323-2336 Doi:10.1039/c9na00099b [9] Vengadaesvaran B., Arun N., Chanthiriga R., Bushroa A. R., Ramis Rau S., Ramesh K., Vikneswaran R., Alshabeeb G. H. E., Ramesh S. and Arof A. K., “Scratch resistance enhancement of 3-glycidyloxypropyltrimethoxysilane coating incorporated with silver nanoparticles” Surface Engineering 30 (2014) 177-182 Doi:10.1179/1743294413Y.0000000238 [10] Lee M.H., Min B.K., Son J.S. and Kwon T.Y. “Influence of Different Post-Plasma Treatment Storage Conditions on the Shear Bond Strength of Veneering Porcelain to Zirconia” Materials 9:43 (2016) 2-12. Doi:10.3390/ma9010043 [11] Bezir N. Çiçek, Evcin A., Kayali R., Kaşikçi Özen M., Esen K., Cambaz E.B. “Characteristic Properties of Dy-Eu-Ce Co-Doped ZrO2 Nanofibers Fabricated via Electrospinning”, Acta Physica Polonica A, 130, 1 (2016) 300-303 Doi:10.12693/APhysPolA.130.300 [12] Hassanien A.S., Akl A.A. “Effect of Se addition on optical and electrical properties of chalcogenide CdSSe thin films” Superlattices and Microstructures 89 (2016) 153-169 Doi:10.1016/j.spmi.2015.10.044