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Sol-gel Preparation of Silan based Zirconia Hybrid Thin Film

Yıl 2021, , 9 - 12, 31.03.2021
https://doi.org/10.22399/ijcesen.727304

Öz

The sol-gel process is an innovative advanced method, initially developed to synthesize glass and ceramics at low temperature. Sol-gel process can be used to synthesis materials with a variety of shapes, such as porous membranes, thin fibers, nano-size powders and thin films. In this study, epoxy and methacrylate based silane coupling agents are used together with zirconium oxide to form a hybrid coating system on glass surface. In the experimental study, an organic–inorganic molecular hybrid compound was prepared by sol-gel method. First glasses were cleaned by traditional piranha solution (3:1 H2SO4 : H2O2) to remove contaminants. Silanization was applied to increase the adhesion of hybrid coatings on glass substrates. Glass substrate was coated with this solution by a homemade dip-coater. In this study, (3-Glycidoxypropyltrimethoxysilane, GLYMO and 3-(trimethoxysilyl)propylmethacrylate, TMSPM) were chosen as a silane. Zirconia is inorganic component of hybrid materails. Coated samples were characterized by Fouirer Transform Infrared Spectrophotometer (FTIR), Scanning Electron Microscope with Energy Dispersive X-ray Spectroscopy (SEM-EDX) and Contact Angle Goniometer.

Kaynakça

  • [1] Garcia J. C., Scolfaro L. M. R., Lino A. T., Freire V. N., Farias G. A., Silva C. C., Leite Alves H. W., Rodrigues S. C. P. and da Silva Jr E. F.. “Structural, electronic, and optical properties of ZrO2 from ab initio calculations” Journal of Applied Physics 100, 104103 (2006) Doi:10.1063/1.2386967 [2] Ciuparu D., Ensuque A., Shafeev G., Bozon-Verduraz F. “Synthesis and apparent bandgap of nanophase zirconia” Journal Of Materials Science Letters 19 (2000) 931– 933. Doi:10.1023/A:1006799701474 [3] Patel U.S., Patel K.H., Chauhan K.V., Chawla A.K., Rawal S.K. “Investigation of various properties for zirconium oxide films synthesized by sputtering” Procedia Technology 23 ( 2016 ) 336 – 343. Doi:10.1016/j.protcy.2016.03.035 [4] Adnan M. M., Dalod A. R. M., Balci M.H., Glaum J. and Einarsrud M.A. “In Situ Synthesis of Hybrid Inorganic–Polymer Nanocomposites” Polymers 10 (2018) 1129. Doi:10.3390/polym10101129 [5] Yedikardeş F.B. “Preparation And Characterization Of Anti Bacterial, Anti Scratch And Easy To Clean Multifunctional Coatings By Sol Gel Method”, M.Sc. Thesis, ITU, June 2016 [6] Bezir N. Çiçek, Evcin A., Kayali R., Özen M.K., Balyaci G. “Comparison of Pure and Doped TiO2 Thin Films Prepared by Sol-Gel Spin-Coating Method” ACTA PHYSICA POLONICA A, 132 (2017) page 620-624 Doi:10.12693/APhysPolA.132.620 [7] Adamczyk A., “The influence of ZrO2 precursor type on the structure of ZrO2-TiO2-SiO2 gels and selected thin films”, Journal of Molecular Structure 1171 (2018) 706-716 Doi:10.1016/j.molstruc.2018.06.068 [8] Halbus A.F., Horozov T.S. and Paunov V.N. “Self-grafting copper oxide nanoparticles show a strong enhancement of their anti-algal and anti-yeast action” Nanoscale Advances 1 (2019) 2323-2336 Doi:10.1039/c9na00099b [9] Vengadaesvaran B., Arun N., Chanthiriga R., Bushroa A. R., Ramis Rau S., Ramesh K., Vikneswaran R., Alshabeeb G. H. E., Ramesh S. and Arof A. K., “Scratch resistance enhancement of 3-glycidyloxypropyltrimethoxysilane coating incorporated with silver nanoparticles” Surface Engineering 30 (2014) 177-182 Doi:10.1179/1743294413Y.0000000238 [10] Lee M.H., Min B.K., Son J.S. and Kwon T.Y. “Influence of Different Post-Plasma Treatment Storage Conditions on the Shear Bond Strength of Veneering Porcelain to Zirconia” Materials 9:43 (2016) 2-12. Doi:10.3390/ma9010043 [11] Bezir N. Çiçek, Evcin A., Kayali R., Kaşikçi Özen M., Esen K., Cambaz E.B. “Characteristic Properties of Dy-Eu-Ce Co-Doped ZrO2 Nanofibers Fabricated via Electrospinning”, Acta Physica Polonica A, 130, 1 (2016) 300-303 Doi:10.12693/APhysPolA.130.300 [12] Hassanien A.S., Akl A.A. “Effect of Se addition on optical and electrical properties of chalcogenide CdSSe thin films” Superlattices and Microstructures 89 (2016) 153-169 Doi:10.1016/j.spmi.2015.10.044
Yıl 2021, , 9 - 12, 31.03.2021
https://doi.org/10.22399/ijcesen.727304

Öz

Kaynakça

  • [1] Garcia J. C., Scolfaro L. M. R., Lino A. T., Freire V. N., Farias G. A., Silva C. C., Leite Alves H. W., Rodrigues S. C. P. and da Silva Jr E. F.. “Structural, electronic, and optical properties of ZrO2 from ab initio calculations” Journal of Applied Physics 100, 104103 (2006) Doi:10.1063/1.2386967 [2] Ciuparu D., Ensuque A., Shafeev G., Bozon-Verduraz F. “Synthesis and apparent bandgap of nanophase zirconia” Journal Of Materials Science Letters 19 (2000) 931– 933. Doi:10.1023/A:1006799701474 [3] Patel U.S., Patel K.H., Chauhan K.V., Chawla A.K., Rawal S.K. “Investigation of various properties for zirconium oxide films synthesized by sputtering” Procedia Technology 23 ( 2016 ) 336 – 343. Doi:10.1016/j.protcy.2016.03.035 [4] Adnan M. M., Dalod A. R. M., Balci M.H., Glaum J. and Einarsrud M.A. “In Situ Synthesis of Hybrid Inorganic–Polymer Nanocomposites” Polymers 10 (2018) 1129. Doi:10.3390/polym10101129 [5] Yedikardeş F.B. “Preparation And Characterization Of Anti Bacterial, Anti Scratch And Easy To Clean Multifunctional Coatings By Sol Gel Method”, M.Sc. Thesis, ITU, June 2016 [6] Bezir N. Çiçek, Evcin A., Kayali R., Özen M.K., Balyaci G. “Comparison of Pure and Doped TiO2 Thin Films Prepared by Sol-Gel Spin-Coating Method” ACTA PHYSICA POLONICA A, 132 (2017) page 620-624 Doi:10.12693/APhysPolA.132.620 [7] Adamczyk A., “The influence of ZrO2 precursor type on the structure of ZrO2-TiO2-SiO2 gels and selected thin films”, Journal of Molecular Structure 1171 (2018) 706-716 Doi:10.1016/j.molstruc.2018.06.068 [8] Halbus A.F., Horozov T.S. and Paunov V.N. “Self-grafting copper oxide nanoparticles show a strong enhancement of their anti-algal and anti-yeast action” Nanoscale Advances 1 (2019) 2323-2336 Doi:10.1039/c9na00099b [9] Vengadaesvaran B., Arun N., Chanthiriga R., Bushroa A. R., Ramis Rau S., Ramesh K., Vikneswaran R., Alshabeeb G. H. E., Ramesh S. and Arof A. K., “Scratch resistance enhancement of 3-glycidyloxypropyltrimethoxysilane coating incorporated with silver nanoparticles” Surface Engineering 30 (2014) 177-182 Doi:10.1179/1743294413Y.0000000238 [10] Lee M.H., Min B.K., Son J.S. and Kwon T.Y. “Influence of Different Post-Plasma Treatment Storage Conditions on the Shear Bond Strength of Veneering Porcelain to Zirconia” Materials 9:43 (2016) 2-12. Doi:10.3390/ma9010043 [11] Bezir N. Çiçek, Evcin A., Kayali R., Kaşikçi Özen M., Esen K., Cambaz E.B. “Characteristic Properties of Dy-Eu-Ce Co-Doped ZrO2 Nanofibers Fabricated via Electrospinning”, Acta Physica Polonica A, 130, 1 (2016) 300-303 Doi:10.12693/APhysPolA.130.300 [12] Hassanien A.S., Akl A.A. “Effect of Se addition on optical and electrical properties of chalcogenide CdSSe thin films” Superlattices and Microstructures 89 (2016) 153-169 Doi:10.1016/j.spmi.2015.10.044
Toplam 1 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Research Articles
Yazarlar

Atilla Evcin 0000-0002-0163-5097

Harun Güney 0000-0001-9877-2591

Nalan Bezir 0000-0002-5708-1521

Yayımlanma Tarihi 31 Mart 2021
Gönderilme Tarihi 26 Nisan 2020
Kabul Tarihi 11 Mart 2021
Yayımlandığı Sayı Yıl 2021

Kaynak Göster

APA Evcin, A., Güney, H., & Bezir, N. (2021). Sol-gel Preparation of Silan based Zirconia Hybrid Thin Film. International Journal of Computational and Experimental Science and Engineering, 7(1), 9-12. https://doi.org/10.22399/ijcesen.727304