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Sol-gel Preparation of Silan based Titania Hybrid Composite Thin Film

Yıl 2021, Cilt 7, Sayı 1, 25 - 28, 31.03.2021

Öz

In this study, epoxy and methacrylate based silane coupling agents are used together with titanium oxide to form a hybrid coating system on glass surface. In the experimental study, an organic–inorganic molecular hybrid compound was prepared by sol-gel method. First glasses were cleaned by traditional piranha solution (3:1 H2SO4 : H2O2) to remove contaminants. In order to improve the adhesion of hybrid coatings on glass substrates silanization treatment was applied. Silanization solution was prepared by dissolving 1 g 3-aminopropyl-Triethoxysilane (3-APTES) in 100 mL 2-propanol. Glass substrates were coated with this solution using a dip-coater. Silanes (3-Glycidoxypropyltrimethoxysilane, GLYMO and 3-(trimethoxysilyl)propylmethacrylate, TMSPM or MEMO) were mixed deionized water and 2-propanol. Titanium oxide was added and mixed the silane solutions for 1 hour. After modified solution was coated on a glass sheet by dip coater with heater. After evaporation of solvents, coated samples were characterized by Fouirer Transform Infrared Spektrofotometre (FTIR), Scanning Electron Microscope with Energy Dispersive X-ray Spectroscopy (SEM-EDX) and Contact Angle Goniometer.

Kaynakça

  • [1] Sanchez Clément, Julian-Lopez Beatriz, Belleville Philippe, Popall Michael.. “Application of Hybrid Organic–Inorganic Nanocomposites” Journal of Materials Chemistry. 15 (2005) 3559-3592 Doi:10.1039/B509097K. [2] İskender Şenay, İşmar Serkan and Evcin Atilla, “Scratch Resistance Hybrid Coating on PMMA”, International Natural Science, Engineering and Material Technologies Conference, İstanbul / TURKEY 2019. [3] Minelli M., De Angelis M.G., Doghieri F., Marini M., Toselli M., Pilati F., “Oxygen permeability of novel organic–inorganic coatings: I. Effects of organic–inorganic ratio and molecular weight of the organic component”, European Polymer Journal, 44, 8 (2008) pp 2581-2588, Doi:10.1016/j.eurpolymj.2008.06.006. [4] BİÇER Eyüp Can, EVCİN Atilla, GÜRAKSIN Gür Emre, “Characterization of Hydroxyapatite Coating on Ti6Al4V by Sol-gel Method”, International Journal of Computational and Experimental Science and Engineering (IJCESEN) 4, 3 (2018) pp. 15-19 [5] Kahraman Memet, Kuğu Murat, Menceloglu Yusuf, Kayaman-Apohan Nilhan, Güngör Atilla “The novel use of organo alkoxy silane for the synthesis of organic–inorganic hybrid coatings” Journal of Non-Crystalline Solids. 352 (2006) 2143-2151. Doi:10.1016/j.jnoncrysol.2006.02.029. [6] Bezir N. Çiçek, Evcin A., Kayali R., Özen M.K., Balyaci G. “Comparison of Pure and Doped TiO2 Thin Films Prepared by Sol-Gel Spin-Coating Method” ACTA PHYSICA POLONICA A, 132 (2017) page 620-624 Doi:10.12693/APhysPolA.132.620 [7] Gharagozlou Mehrnaz, Naghibi Sanaz, Materials Science in Semiconductor Processing 35, (2015) 166–173. [8] Halbus A.F., Horozov T.S. and Paunov V.N. “Self-grafting copper oxide nanoparticles show a strong enhancement of their anti-algal and anti-yeast action” Nanoscale Advances 1 (2019) 2323-2336 Doi:10.1039/c9na00099b [9] Vengadaesvaran B., Arun N., Chanthiriga R., Bushroa A. R., Ramis Rau S., Ramesh K., Vikneswaran R., G. Alshabeeb H. E., Ramesh S. and Arof A. K. “Scratch resistance enhancement of 3-glycidyloxypropyltrimethoxysilane coating incorporated with silver nanoparticles” Surface Engineering 30 (2014) 177-182 Doi:10.1179/1743294413Y.0000000238 [10] Adamczyk A., “The influence of ZrO2 precursor type on the structure of ZrO2-TiO2-SiO2 gels and selected thin films”, Journal of Molecular Structure 1171 (2018) 706-716 Doi:10.1016/j.molstruc.2018.06.068 [11] Patel U.S., Patel K.H., Chauhan K.V., Chawla A.K., Rawal S.K. “Investigation of various properties for zirconium oxide films synthesized by sputtering” Procedia Technology 23 ( 2016 ) 336 – 343. Doi:10.1016/j.protcy.2016.03.035 [12] Lee M.H., Min B.K., Son J.S. and Kwon T.Y. “Influence of Different Post-Plasma Treatment Storage Conditions on the Shear Bond Strength of Veneering Porcelain to Zirconia” Materials 9:43 (2016) 2-12. Doi:10.3390/ma9010043 [13] Bezir N. Çiçek, Evcin A., Kayali R., Özen M.K., Esen K. N. Çiçek Bezir, A. Evcin, R. Kayali, M.K. Özen, K. Esen, Comparison of Five-Layered ZrO2 and Single-Layered Ce, Eu, and Dy-Doped ZrO2 Thin Films Prepared by Sol-Gel Spin Coating Method, ACTA PHYSICA POLONICA A, Vol 132 (2017) 612 Doi: 10.12693/APhysPolA.132.612 [14] Hassanien A.S., Akl A.A. “Effect of Se addition on optical and electrical properties of chalcogenide CdSSe thin films” Superlattices and Microstructures 89 (2016) 153-169 Doi:10.1016/j.spmi.2015.10.044 [15] Oh H, KrantzJ, Litzov I, Stubhan T, Pinna L, Brabec C J “Comparison of various sol–gel derived metal oxide layers for inverted organic solar cells” Solar Energy Materials & Solar Cells 95,8 (2011) 2194-2199 Doi: 10.1016/j.solmat.2011.03.023

Yıl 2021, Cilt 7, Sayı 1, 25 - 28, 31.03.2021

Öz

Kaynakça

  • [1] Sanchez Clément, Julian-Lopez Beatriz, Belleville Philippe, Popall Michael.. “Application of Hybrid Organic–Inorganic Nanocomposites” Journal of Materials Chemistry. 15 (2005) 3559-3592 Doi:10.1039/B509097K. [2] İskender Şenay, İşmar Serkan and Evcin Atilla, “Scratch Resistance Hybrid Coating on PMMA”, International Natural Science, Engineering and Material Technologies Conference, İstanbul / TURKEY 2019. [3] Minelli M., De Angelis M.G., Doghieri F., Marini M., Toselli M., Pilati F., “Oxygen permeability of novel organic–inorganic coatings: I. Effects of organic–inorganic ratio and molecular weight of the organic component”, European Polymer Journal, 44, 8 (2008) pp 2581-2588, Doi:10.1016/j.eurpolymj.2008.06.006. [4] BİÇER Eyüp Can, EVCİN Atilla, GÜRAKSIN Gür Emre, “Characterization of Hydroxyapatite Coating on Ti6Al4V by Sol-gel Method”, International Journal of Computational and Experimental Science and Engineering (IJCESEN) 4, 3 (2018) pp. 15-19 [5] Kahraman Memet, Kuğu Murat, Menceloglu Yusuf, Kayaman-Apohan Nilhan, Güngör Atilla “The novel use of organo alkoxy silane for the synthesis of organic–inorganic hybrid coatings” Journal of Non-Crystalline Solids. 352 (2006) 2143-2151. Doi:10.1016/j.jnoncrysol.2006.02.029. [6] Bezir N. Çiçek, Evcin A., Kayali R., Özen M.K., Balyaci G. “Comparison of Pure and Doped TiO2 Thin Films Prepared by Sol-Gel Spin-Coating Method” ACTA PHYSICA POLONICA A, 132 (2017) page 620-624 Doi:10.12693/APhysPolA.132.620 [7] Gharagozlou Mehrnaz, Naghibi Sanaz, Materials Science in Semiconductor Processing 35, (2015) 166–173. [8] Halbus A.F., Horozov T.S. and Paunov V.N. “Self-grafting copper oxide nanoparticles show a strong enhancement of their anti-algal and anti-yeast action” Nanoscale Advances 1 (2019) 2323-2336 Doi:10.1039/c9na00099b [9] Vengadaesvaran B., Arun N., Chanthiriga R., Bushroa A. R., Ramis Rau S., Ramesh K., Vikneswaran R., G. Alshabeeb H. E., Ramesh S. and Arof A. K. “Scratch resistance enhancement of 3-glycidyloxypropyltrimethoxysilane coating incorporated with silver nanoparticles” Surface Engineering 30 (2014) 177-182 Doi:10.1179/1743294413Y.0000000238 [10] Adamczyk A., “The influence of ZrO2 precursor type on the structure of ZrO2-TiO2-SiO2 gels and selected thin films”, Journal of Molecular Structure 1171 (2018) 706-716 Doi:10.1016/j.molstruc.2018.06.068 [11] Patel U.S., Patel K.H., Chauhan K.V., Chawla A.K., Rawal S.K. “Investigation of various properties for zirconium oxide films synthesized by sputtering” Procedia Technology 23 ( 2016 ) 336 – 343. Doi:10.1016/j.protcy.2016.03.035 [12] Lee M.H., Min B.K., Son J.S. and Kwon T.Y. “Influence of Different Post-Plasma Treatment Storage Conditions on the Shear Bond Strength of Veneering Porcelain to Zirconia” Materials 9:43 (2016) 2-12. Doi:10.3390/ma9010043 [13] Bezir N. Çiçek, Evcin A., Kayali R., Özen M.K., Esen K. N. Çiçek Bezir, A. Evcin, R. Kayali, M.K. Özen, K. Esen, Comparison of Five-Layered ZrO2 and Single-Layered Ce, Eu, and Dy-Doped ZrO2 Thin Films Prepared by Sol-Gel Spin Coating Method, ACTA PHYSICA POLONICA A, Vol 132 (2017) 612 Doi: 10.12693/APhysPolA.132.612 [14] Hassanien A.S., Akl A.A. “Effect of Se addition on optical and electrical properties of chalcogenide CdSSe thin films” Superlattices and Microstructures 89 (2016) 153-169 Doi:10.1016/j.spmi.2015.10.044 [15] Oh H, KrantzJ, Litzov I, Stubhan T, Pinna L, Brabec C J “Comparison of various sol–gel derived metal oxide layers for inverted organic solar cells” Solar Energy Materials & Solar Cells 95,8 (2011) 2194-2199 Doi: 10.1016/j.solmat.2011.03.023

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Research Articles
Yazarlar

Atilla EVCİN (Sorumlu Yazar)
AFYON KOCATEPE ÜNİVERSİTESİ, MÜHENDİSLİK FAKÜLTESİ, MALZEME BİLİMİ VE MÜHENDİSLİĞİ BÖLÜMÜ
0000-0002-0163-5097
Türkiye


Harun GÜNEY
AGRI IBRAHIM CECEN UNIVERSITY
0000-0001-9877-2591
Türkiye


Nalan BEZİR
SÜLEYMAN DEMİREL ÜNİVERSİTESİ, FEN-EDEBİYAT FAKÜLTESİ, FİZİK BÖLÜMÜ
0000-0002-5708-1521
Türkiye

Yayımlanma Tarihi 31 Mart 2021
Başvuru Tarihi 26 Nisan 2020
Kabul Tarihi 11 Mart 2021
Yayınlandığı Sayı Yıl 2021, Cilt 7, Sayı 1

Kaynak Göster

Bibtex @araştırma makalesi { ijcesen727277, journal = {International Journal of Computational and Experimental Science and Engineering}, issn = {}, eissn = {2149-9144}, address = {}, publisher = {İskender AKKURT}, year = {2021}, volume = {7}, pages = {25 - 28}, doi = {}, title = {Sol-gel Preparation of Silan based Titania Hybrid Composite Thin Film}, key = {cite}, author = {Evcin, Atilla and Güney, Harun and Bezir, Nalan} }
APA Evcin, A. , Güney, H. & Bezir, N. (2021). Sol-gel Preparation of Silan based Titania Hybrid Composite Thin Film . International Journal of Computational and Experimental Science and Engineering , 7 (1) , 25-28 . Retrieved from https://dergipark.org.tr/tr/pub/ijcesen/issue/57886/727277
MLA Evcin, A. , Güney, H. , Bezir, N. "Sol-gel Preparation of Silan based Titania Hybrid Composite Thin Film" . International Journal of Computational and Experimental Science and Engineering 7 (2021 ): 25-28 <https://dergipark.org.tr/tr/pub/ijcesen/issue/57886/727277>
Chicago Evcin, A. , Güney, H. , Bezir, N. "Sol-gel Preparation of Silan based Titania Hybrid Composite Thin Film". International Journal of Computational and Experimental Science and Engineering 7 (2021 ): 25-28
RIS TY - JOUR T1 - Sol-gel Preparation of Silan based Titania Hybrid Composite Thin Film AU - Atilla Evcin , Harun Güney , Nalan Bezir Y1 - 2021 PY - 2021 N1 - DO - T2 - International Journal of Computational and Experimental Science and Engineering JF - Journal JO - JOR SP - 25 EP - 28 VL - 7 IS - 1 SN - -2149-9144 M3 - UR - Y2 - 2021 ER -
EndNote %0 International Journal of Computational and Experimental Science and Engineering Sol-gel Preparation of Silan based Titania Hybrid Composite Thin Film %A Atilla Evcin , Harun Güney , Nalan Bezir %T Sol-gel Preparation of Silan based Titania Hybrid Composite Thin Film %D 2021 %J International Journal of Computational and Experimental Science and Engineering %P -2149-9144 %V 7 %N 1 %R %U
ISNAD Evcin, Atilla , Güney, Harun , Bezir, Nalan . "Sol-gel Preparation of Silan based Titania Hybrid Composite Thin Film". International Journal of Computational and Experimental Science and Engineering 7 / 1 (Mart 2021): 25-28 .
AMA Evcin A. , Güney H. , Bezir N. Sol-gel Preparation of Silan based Titania Hybrid Composite Thin Film. IJCESEN. 2021; 7(1): 25-28.
Vancouver Evcin A. , Güney H. , Bezir N. Sol-gel Preparation of Silan based Titania Hybrid Composite Thin Film. International Journal of Computational and Experimental Science and Engineering. 2021; 7(1): 25-28.
IEEE A. Evcin , H. Güney ve N. Bezir , "Sol-gel Preparation of Silan based Titania Hybrid Composite Thin Film", International Journal of Computational and Experimental Science and Engineering, c. 7, sayı. 1, ss. 25-28, Mar. 2021

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