Product Gas Distribution and Composition From Catalyzed Gasification of Mimosa

Abstract

The aim of this study is to analyze the potential of giant sensitive plant or Mimosa for gaseous fuel production by means of gasification process. An experimental study was carried out in a bench scale, fixed bed gasifier with air at atmospheric pressure. Parametric investigation was performed to determine the effect of temperature (600-900oC), collection time (10-110 min) and catalyst to biomass ratio (0.5-2) on product gas yields and composition. Experimental results showed that high temperature favors hydrogen, carbon monoxide and carbon dioxide yield (11, 18 and 24 mol %), while methane was found to follow opposite trend. Production rates of hydrogen and carbon monoxide appeared to increase during volatile releasing step, but decrease during carbonization. With catalyst to biomass ratio of 1, high hydrogen and carbon monoxide concentrations in the product gas (27 and 29 mol%, respectively) were achieved.

Keywords

• - Biomass; Dolomite; Fixed Bed; Giant Sensitive Plant; Thermo-chemical Conversion; Renewable Energy:

Kaynakça

1. R. C. Saxena, D. K. Adhikari, and H. B. Goyal, "Biomass-based energy fuel through biochemical routes: A review," Renewable and Sustainable Energy Reviews, vol. 13, pp. 167-178, 2009.
2. I. De Bari, D. Barisano, M. Cardinale, D. Matera, F. Nanna, and D. Viggiano, "Air Gasification of Biomass in a Downdraft Fixed Bed:  A Comparative Study of the Inorganic and Organic Products Distribution," Energy & Fuels, vol. 14, pp. 889-898, July 2000.
3. R. J. B. Smith, M. Loganathan, and S. Shantha Murthy, "A Review of the Water Gas Shift Reaction Kinetics," in International Journal of Chemical Reactor Engineering vol. 8, ed, 2010, p. 1.
4. G. Chen, J. Andries, Z. Luo, and H. Spliethoff, "Biomass pyrolysis/gasification for product gas production: the overall investigation of parametric effects," Energy Conversion and Management, vol. 44, pp. 1875-1884,
5. I. Narváez, A. Orío, M. P. Aznar, and J. Corella, "Biomass Gasification with Air in an Atmospheric Bubbling Fluidized Bed. Effect of Six Operational Variables on the Quality of the Produced Raw Gas," Industrial & Engineering Chemistry Research, vol. 35, pp. 2110-2120, January 1996.
6. P. Plis and R. K. Wilk, "Theoretical and experimental investigation of biomass gasification process in a fixed bed gasifier," Energy, vol. 36, pp. 3838-3845, 2011.
7. J. F. González, S. Román, D. Bragado, and M. Calderón, "Investigation on the reactions influencing biomass air and air/steam gasification for hydrogen production," Fuel Processing Technology, vol. 89, pp. 764-772, 2008.
8. S. Thiha, N. Tippayawong, T. Wongsiriamnuay, and C. Chaichana, "Catalytic destruction of biomass tar by dolomite in a dual packed bed reactor," International conference on green and sustainable innovation 2009

9. (ICGSI), Chiang Rai, Thailand, pp., 2009.
10. J. Gil, J. Corella, M. a. P. Aznar, and M. A. Caballero, "Biomass gasification in atmospheric and bubbling fluidized bed: Effect of the type of gasifying agent on the product distribution," Biomass and Bioenergy, vol. 17, pp. 389-403, 1999.
11. J. Firn and Y. M. Buckley, "Impacts of Invasive Plants on Australian Rangelands," Rangelands, vol. 32, pp. 48-51, February 2010.
12. W.-M. Chen, E. K. James, J.-H. Chou, S.-Y. Sheu, S.-Z. Yang, and J. I. Sprent, "β-Rhizobia from Mimosa pigra, a newly discovered invasive plant in Taiwan," New Phytologist, vol. 168, pp. 661-675, 2005.
13. W. M. Lonsdale, "Rates of Spread of an Invading Species--Mimosa Pigra in Northern Australia," Journal of Ecology, vol. 81, pp. 513-521, 1993.
14. T. Wongsiriamnuay and N. Tippayawong, "Non- isothermal pyrolysis characteristics of giant sensitive plants using thermogravimetric analysis," Bioresource Technology, vol. 101, pp. 5638-5644, 2010. T. Wongsiriamnuay and N. Tippayawong,
15. "Thermogravimetric analysis of giant sensitive plants under air atmosphere," Bioresource Technology, vol. 101, pp. 9314-9320, 2010.
16. T. Wongsiriamnuay, T. Phengpom, P. Panthong, and N. Tippayawong, "Renewable Energy from Thermal Gasification of a Giant Sensitive Plant (Mimosa pigra L.) ", 5th International Conference on Combustion, Incineration/Pyrolysis and Emission Control, Chiang Mai, Thailand pp., 16-19 December 2008. T. Wongsiriamnuay and N. Tippayawong,
17. "Gasification of Giant Sensitive Plants in a Fixed Bed Reactor," 23rd International Conference on Efficiency, Cost, Optimization, Simulation and Environmental Impact of Energy Systems, Lausanne, Switzerland, pp., 17 June 2010.
18. K. Presnell, "The potential use of mimosa as fuel for power generation.," 3rd International Symposium on the Management of Mimosa pigra, Darwin, Australia, pp. 68- 22-25 September 2002.
19. L. Wang, C. L. Weller, D. D. Jones, and M. A. Hanna, "Contemporary issues in thermal gasification of biomass and its application to electricity and fuel production," Biomass and Bioenergy, vol. 32, pp. 573- , 2008.
20. K. Raveendran, A. Ganesh, and K. C. Khilar, "Pyrolysis characteristics of biomass and biomass components," Fuel, vol. 75, pp. 987-998, 1996.
21. M. Lapuerta, J. J. Hernández, A. Pazo, and J. López, "Gasification and co-gasification of biomass wastes: Effect of the biomass origin and the gasifier operating conditions," Fuel Processing Technology, vol. 89, pp. 837, 2008.
22. M. Pohořelý, M. Vosecký, P. Hejdová, M. Punčochář, S. Skoblja, M. Staf, J. Vošta, B. Koutský, and K. Svoboda, "Gasification of coal and PET in fluidized bed reactor," Fuel, vol. 85, pp. 2458-2468, 2006.
23. T. Hanaoka, S. Inoue, S. Uno, T. Ogi, and T. Minowa, "Effect of woody biomass components on air- steam gasification," Biomass and Bioenergy, vol. 28, pp. 76, 2005.
24. J. M. Encinar, F. J. Beltrán, A. Ramiro, and J. F. González, "Pyrolysis/gasification of agricultural residues by carbon dioxide in the presence of different additives: influence of variables," Fuel Processing Technology, vol. , pp. 219-233, 1998.
25. I. Ahmed and A. K. Gupta, "Evolution of syngas from cardboard gasification," Applied Energy, vol. 86, pp. 1732-1740, 2009.
26. K. Mitsuoka, S. Hayashi, H. Amano, K. Kayahara, E. Sasaoaka, and M. A. Uddin, "Gasification of woody biomass char with CO2: The catalytic effects of K and Ca species on char gasification reactivity," Fuel Processing Technology, vol. 92, pp. 26-31, 2011.
27. A. Olivares, M. P. Aznar, M. A. Caballero, J. Gil, E. Francés, and J. Corella, "Biomass Gasification:  Produced Gas Upgrading by In-Bed Use of Dolomite," Industrial & Engineering Chemistry Research, vol. 36, pp. 5220-5226, December 1997.
28. J. Gil, M. A. Caballero, J. A. Martín, M.-P. Aznar, and J. Corella, "Biomass Gasification with Air in a Fluidized Bed:  Effect of the In-Bed Use of Dolomite under Different Operation Conditions," Industrial & Engineering Chemistry Research, vol. 38, pp. 4226-4235, November 1999.
29. M. Asadullah, S.-i. Ito, K. Kunimori, M. Yamada, and K. Tomishige, "Biomass Gasification to Hydrogen and Syngas at Low Temperature: Novel Catalytic System Using Fluidized-Bed Reactor," Journal of Catalysis, vol. , pp. 255-259, 2002.
30. J. S. Dennis and A. N. Hayhurst, "the effect of CO2 on the kinetics and extent of calcination of limestone and dolomite particles in Engineering Science, vol. 42, pp. 2361-2372, 1987. fluidised beds," Chemical