Nigerian Jatropha Curcas Oil Seeds: Prospect for Biodiesel Production in Nigeria

Yıl 2012, Cilt: 2 Sayı: 2, 317 - 325, 01.06.2012

Elizabeth Funmilayo Aransiola Michael Olawale Daramola Tunde Victor Ojumu Mujidat Omolara Aremu Stephen kolawole Layokun Bamidele Ogbe Solomon

Öz

ABSTRACTThis study investigated production of biodiesel from oil seeds of Jatropha curcas, obtained in Nigeria, with a view to encouraging the cultivation of Jatropha plant in Nigeria and to providing a motivation for the development of biodiesel production from this feedstock.  Also effect of oil-to-alcohol molar ratio on the biodiesel production from Nigerian Jatropha curcas seeds oil was investigated with a view to confirming established base case. A maximum yield of fatty acid methyl esters (FAME) of 87% was obtained at 333 Kelvin, oil-to-alcohol molar ratio of 1:6 and at 1wt% NaOH catalyst concentration. The physical properties of the BD obtained from Nigerian Jatropha oil met the ASTM standard of D-6751. Consequently, this study reveals that Jatropha curcas, an economically invaluable plant in Nigeria, could be a good feedstock for biodiesel production in Nigeria.

Anahtar Kelimeler

Renewable energy; Biodiesel; Transesterification; Nigerian Jatropha curcas oil; Biofuel

Kaynakça

• M. Devanesan, T. Viruthagiri, and N. Sugumar, “Transesterification of Jatropha oil using immobilized Pseudomonas biotechnology, vol. 6, (no. 21), 2010. African Journal of
• A.K. Khan, “Research into biodiesel kinetics and catalyst development,” Department of Chemical Engineering, vol. 17, 2002. University of Queensland,
• M. Horn, “OPEC's optimal crude oil price,” Energy Policy, vol. 32, (no. 2), pp. 269-280, 2004.
• A. Demirbas, “Biodiesel production from vegetable oils via catalytic and non-catalytic supercritical methanol transesterification methods,” Progress in Energy and Combustion Science, vol. 31, (no. 5-6), pp. 466-487, S. Amin, “Review on biofuel oil and gas production processes from microalgae,” Energy Conversion and Management, vol. 50, (no. 7), pp. 1834-1840, 2009.
• A. Demirbas “Production of biodiesel from algae oils,” Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, vol. 31, (no. 2), pp. 163-168, G. Huang, F. Chen, D. Wei, X. Zhang, and G. Chen, “Biodiesel production by microalgal biotechnology,” Applied Energy, vol. 87, (no. 1), pp. 38-46, 2010.
• E.G. Shay, “Diesel fuel from vegetable oils: status and opportunities,” Biomass and Bioenergy, vol. 4, (no. 4), pp. 227-242, 1993.
• A. Demirbas, “Biodiesel fuels from vegetable oils via catalytic transesterifications and other methods: a survey,” Energy Conversion and Management, vol. 44, (no. 13), pp. 2093- , 2003. supercritical alcohol
• M. Gui, K. Lee, and S. Bhatia, “Feasibility of edible oil vs. non-edible oil vs. waste edible oil as biodiesel feedstock,” Energy, vol. 33, (no. 11), pp. 1646-1653,
• C. Baroi, E.K. Yanful, and M.A. Bergougnou, “Biodiesel Production from Jatropha curcas Oil Using Potassium Carbonate as an Unsupported Catalyst,” International Journal of Chemical Reactor Engineering, vol. 7, (no. 7), pp. 72, 2009.
• J. Martinez-Herrera, P. Siddhuraju, G. Francis, G. Davila-Ortiz, and K. Becker, “Chemical composition, toxic/antimetabolic constituents, and effects of different treatments on their levels, in four provenances of Jatropha curcas L. from Mexico,” Food Chemistry, vol. , (no. 1), pp. 80-89, 2006.
• W. Achten, L. Verchot, Y.J. Franken, E. Mathijs, V.P. Singh, R. Aerts, and B. Muys, “Jatropha bio-diesel production and use,” Biomass and Bioenergy, vol. 32, (no. 12), pp. 1063-1084, 2008.
• G. Augustus, M. Jayabalan, and G. Seiler, “Evaluation and bioinduction of energy components of Jatropha curcas,” Biomass and Bioenergy, vol. 23, (no. ), pp. 161-164, 2002.
• J.C. Juan, D.A. Kartika, T.Y. Wu, and T.Y.Y. Hin, “Biodiesel production from jatropha oil by catalytic and non-catalytic approaches: An overview,” Bioresource Technology, vol. 102, (no. 2), pp. 452-460, 2011.
• A. Aderibigbe, C. Johnson, H. Makkar, K. Becker, and N. Foidl, “Chemical composition and effect of heat on organic matter-and nitrogen-degradability and some antinutritional components of Jatropha meal,” Animal feed science and technology, vol. 67, (no. 2), pp. 223- , 1997.
• S. Jain and M. Sharma, “Prospects of biodiesel from Jatropha in India: A review,” Renewable and Sustainable Energy Reviews, vol. 14, (no. 2), pp. 763-771, 2010. E. Akintayo, “Characteristics and composition of Parkiabiglobbossa and Jatropha curcas oils and cakes,” Bioresource Technology, vol. 92, (no. 3), pp. 307-310, 2004.
• C. Martín, A. Moure, G. Martín, E. Carrillo, H. Domínguez, and J.C. Parajó, “Fractional characterisation of jatropha, neem, moringa, trisperma, castor and candlenut seeds as potential feedstocks for biodiesel production in Cuba,” Biomass and Bioenergy, vol. 34, (no. 4), pp. 533-538, 2010.
• H. Lu, Y. Liu, H. Zhou, Y. Yang, M. Chen, and B. Liang, “Production of biodiesel from Jatropha curcas L. oil,” Computers & Chemical Engineering, vol. 33, (no. ), pp. 1091-1096, 2009.
• R. Wang, M.A. Hanna, W.-W. Zhou, P.S. Bhadury, Q. Chen, B.-A. Song, and S. Yang, “Production and selected fuel properties of biodiesel from promising non- edible oils: Euphorbia lathyris L., Sapiumsebiferum L. and Jatropha curcas L,” Bioresource Technology, vol. , (no. 2), pp. 1194-1199, 2011.
• F. Ma and M.A. Hanna, “Biodiesel production: a review1,” Bioresource Technology, vol. 70, (no. 1), pp. 15, 1999.
• M. Balat, “Biodiesel fuel production from vegetable oils via supercritical ethanol transesterification,” Energy Sources, Environmental Effects, vol. 30, (no. 5), pp. 429-440, Recovery, Utilization, and E. Aransiola, E. Betiku, S. Layokun, and B. Solomon, “Production of biodiesel by transesterification of refined soybean oil,” International Journal of Biological and Chemical Sciences, vol. 4, (no. 2), pp. 391 399, 2010. H.J. Berchmans and production from crude Jatrophacurcas L. seed oil with a high content of free fatty acids,” Bioresource
• Technology, vol. 99, (no. 6), pp. 1716-1721, 2008.
• S. Jain and M. Sharma, “Kinetics of acid base of catalyzedtransesterification Bioresource Technology, vol. 101, (no. 20), pp. 7701- , 2010. Jatrophacurcas oil,” A.K. Endalew, Y. Kiros, and R. Zanzi,
• “Heterogeneous catalysis for biodiesel production from Jatrophacurcas oil (JCO),” Energy, 2011.
• S. Hawash, G. El Diwani, and E.A. Kader, “Optimization of Biodiesel Production from Jatropha Oil By Heterogeneous Base Catalysed Transesterification,” International Journal of Engineering Science, vol. 3, W. Xie, H. Peng, and L. Chen, “Transesterification of soybean oil catalyzed by potassium loaded on alumina as a solid-base catalyst,” Applied Catalysis A: General, vol. 300, (no. 1), pp. 67-74, 2006.
• W. Xue, Y.C. Zhou, B.A. Song, X. Shi, J. Wang, S.T. Yin, D.Y. Hu, L.H. Jin, and S. Yang, “Synthesis of biodiesel from Jatropha curcas L. seed oil using artificial zeolites loaded with CH3COOK as a heterogeneous catalyst,” Natural Science, vol. 1, pp. 55-62, 2009.
• A. Demirbas, “Biodiesel from vegetable oils via transesterification in supercritical methanol,” Energy Conversion and Management, vol. 43, (no. 17), pp. 2349- , 2002.
• O. Alamu, M. Waheed, and S. Jekayinfa, “Alkali- catalysed laboratory production and testing of biodiesel fuel from Nigerian palm kernel oil,” Agricultural Engineering International: The CIGR EJournal., 2007.
• M. Belewu, F.A. Adekola, G.B. Adebayo, O.M. Ameen, N.O. Muhammed, A.M. Olaniyan, O.F. Adekola, and A.K. Musa, “Physico-chemical characteristics of oil and biodiesel from Nigerian and Indian Jatropha curcas seeds,” International Journal of Biological and Chemical Sciences, vol. 4, (no. 2), pp. 524-529, 2010.
• E. Aluyor, P. Aluyor, and C. Ozigagu, “Effect of refining on the quality and composition of groundnut oil,” African Journal of Food Science, vol. 3, (no. 8), pp. 205, 2009.
• E. Akbar, Z. Yaakob, S.K. Kamarudin, M. Ismail, and J. Salimon, “Characteristic and composition of Jatrophacurcas oil seed from Malaysia and its potential as biodiesel feedstock feedstock,” European Journal of Scientific Research, vol. 29, (no. 3), pp. 396-403, 2009.
• M. Mittelbach, “Diesel fuel derived from vegetable oils, VI: Specifications and quality control of biodiesel,” Bioresource Technology, vol. 56, (no. 1), pp. 7-11, 1996.
• A O A C, “"Official Method of Analysis”. Association of official Analytical Chemists ” in Book "Official Method of Analysis”. Association of official Analytical Chemists Series "Official Method of Analysis”. Association of official Analytical Chemists Editor ed.^eds., City, 2000.
• M.A. Dubé, S. Zheng, D.D. McLean, and M. Kates, “A comparison of attenuated total reflectance-FTIR spectroscopy and GPC for monitoring biodiesel production,” Journal of the American Oil Chemists' Society, vol. 81, (no. 6), pp. 599-603, 2004.
• D. Darnoko and M. Cheryan, “Kinetics of palm oil transesterification in a batch reactor,” Journal of the American Oil Chemists' Society, vol. 77, (no. 12), pp. 1267, 2000.
• R.D. Knutson, J. Penn, and W.T. Boehm, Agricultural and food policy [USA]: Prentice-Hall, 1983.