Synthesis, Crystal Structure and Hydrogen Bond Properties of {[HNC5H4B(OH)(OCH3)- 4]2PdCl2} New Compound

Öz

In this study, the new compound {[HNC5H4B(OH)(OCH3)-4]2PdCl2} was synthesized and its crystal structure was determined. Compound crystallized in the space group P21/n in the monoclinic crystal system at a=3.8749 (8) Å, b=10.177 (2) Å, c=20.403 (4) Å, α= γ = 90°, β =91.78° and Z=2 units cell parameters The Pd ion in the compound is at the inversion center and has a quaternary coordination. Because the N–Pd–N* and Cl–Pd–Cl* angles are 180°, the Pd ion has a square plane geometry. The CH···O, CH···Cl and π···π interactions in the compound form a 3-dimensional structure in the bc plane and along a axis.

Anahtar Kelimeler

• Single crystal structure
• Pd compound
• hydrogen bond interactions

{[HNC5H4B(OH)(OCH3)-4]2PdCl2} Yeni Bileşiğin Sentezi, Kristal Yapısı ve Hidrojen Bağ Özellikleri

Öz

Bu çalışmada, yeni bileşik {[HNC5H4B(OH)(OCH3)-4]2PdCl2} sentezlendi ve kristal yapısı belirlendi. Bileşik, monoklinik kristal sisteminde P21/n uzay grubunda a=3.8749 (8) Å, b=10.177 (2) Å, c=20.403 (4) Å, α= γ = 90°, β =91.78° ve Z=2 birim hücre parametrelerinde kristallendi. Bileşikteki Pd iyonu inversiyon merkezinde ve dörtlü bir koordinasyona sahiptir. N–Pd–N* ve Cl–Pd–Cl* açıları 180° olduğu için, Pd iyonu kare düzlem geometriye sahiptir. Bileşikteki CH···O, CH···Cl ve π···π etkileşimleri, bc düzleminde ve a ekseni boyunca 3 boyutlu bir yapı oluşturmaktadır.

Anahtar Kelimeler

• Tek kristal yapı
• Pd bileşiği
• hidrojen bağ etkileşimleri

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