DYESTUFF REMOVAL FROM SYNTHETIC TEXTILE WASTEWATER USING OLIVE LEAF AS ADSORBENT MATERIAL

Öz

The textile industry is one of the sectors where water use is high. Textile wastewater contains a high percentage of dyestuffs. Dyestuffs prevent photosynthetic activities in water and disrupt the ecological balance in water. Treatment of dyestuffs is very important for the prevention of water pollution and for the health of living things. There are several methods for the treatment of wastewater containing dyestuffs. In this study, it was aimed to remove dyestuff from synthetic textile wastewater by using olive leaf by adsorption method. The effects of initial pH, amount of adsorbent, contact time and temperature on adsorption were investigated. According to the data obtained, optimum conditions were determined as pH 2, 0.25 g of adsorbent, 2 hours of contact time, and a temperature of 25 °C. When the experimental data were applied to the kinetic models, it was observed that they conformed to the pseudo-second-order rate equation. The data obtained at the end of the experiments were applied to the Langmuir and Freundlich isotherm models. It was observed that the data obtained with olive leaf conformed to the Freundlich isotherm. The reaction for the olive leaf is an exothermic and occurs spontaneously, according to thermodynamic analysis. Negative entropy indicates a decrease in disorder in adsorption.

Anahtar Kelimeler

• textile wastewater
• dyestuff
• adsorption
• olive leaf

Kaynakça

1. 1. Aboelfetoh, E.F., Gemeay, A.H., El-Sharkawy, R.G. (2020). Effective disposal of methylene blue using green immobilized silver nanoparticles on graphene oxide and reduced graphene oxide sheets through one-pot synthesis. Environ. Monit. Assess. 192, 355.
2. 2. Akın, M., & Akın, G. (2007). Importance of water, water potential in Turkey, water basins and water pollution. The Journal of the Faculty of Languages and History-Geography, 47(2), 105-118.
3. 3. Asadullah, M., Asaduzzaman, M., Kabir, M.S., Mostofo, M.G., Miyazawa, T. (2010). Chemical and structural evaluation of activated carbon prepared from jute sticks for Brilliant Green dye removal from aqueous solution. J. Hazard. Mater. 1-3, 437-443.
4. 4. Bharathiraja B., Jayamuthunagai J., Praveenkumar R., Iyyappan J. (2018). Phytoremediation techniques for the removal of dye in wastewater. Bioremediation: applications for environmental protection and management, 243-252.
5. 5. Bhatnagar, A., Sillanpaa, M. (2010). Utilization of agro-industrial and municipial waste materials as potential adsorbents for water treatment- a review. Chem. Eng. J. 157, 277-296.
6. 6. Blazquez, G., Martin-Lara, M.A., Tenorio, G. (2011). Batch biosorption of lead(II) from aqueous solutions by olive tree pruning waste: Equilibrium, kinetics and thermodynamic study. Chem. Eng. J., 198, 170-177.
7. 7. Crini G.& Badot P.M. (2008). Application of chitosan, a natural aminopolysaccaride, for dye removal from aqueous solutions by adsorption processes using batch studies: a review of recent literature. Prog. Polym. Sci. 33(4), 33-447.
8. 8. Dutta, S., Gupta, B., Srivastava, S.K., Gupta, A.K. (2021). Recent advances on the removal of dyes from wastewater using various adsorbent: a critical review, Mater. Adv. 2, 4497.

9. 9. Ganaie R.J., Rafiq S., Sharma A. (2023). Recent Advances in Physico-chemical Methods for Removal of Dye from Wastewater. IOP Conf. Series: Earth and Environmental Science, 1110, 012040.
10. 10. Geylan, F. M. (2016). Production of nanoactive carbon from olive leaf and determination of some physical properties, Master's Thesis, Balıkesir University, Balıkesir, Türkiye.
11. 11. Hannachi, H., Breton, C., Msallem, M., Hadj, S.B.E., Gazzah, M.E., Berville, A. (2010). Genetic relationships between cultivated and wild olive trees (Olea Europaea L. Var. Europaea and Var. Sylvestris) based on nuclear and chloroplast SSR markers. Nat. Resour., 01,95.
12. 12. Haque, E., Lee, J.E., Jang, I.T., Hwang, Y.K., Chang, J., Jegal, J., Jhung, S.H. (2010). Adsorptive removal of methyl orange from aqueous solution with metal-organic frameworls, porous chromium-benzenedicarboxylates. J. Hazar. Mater. 1-3, 535-542.
13. 13. Ho, Y.S. (2004). Citation review of Lagergren kinetic rate equation on adsorption reaction. Scientometrics, 59(1), 171-177.
14. 14. Ho, Y.S. (2003). Removal of metal ions from sodium arsenate solution using tree fern. Transactions of IChemE, Part B 81, 352-356.
15. 15. Liu, C.H.& Wu C.T. (2010). Optimization of nanostructured lipid carriers for lutein delivery. Colloids and Surfaces A: Physicochem. Eng. Aspects 353 149–156.
16. 16. Moosavi, S., Lai, C.W., Gan, S., Zamiri, G., Pivehzhani, O.A., Johan, M.R. (2020). Application of Efficient Magnetic Particles and Activated Carbon for Dye Removal from Wastewater. ACS Omega, 5, 20684-20697.
17. 17. Namal, O.Ö. (2017). Investigation of Processes Used in the Treatment of Textile Industry Wastewater. Nevşehir Journal of Science and Technology, ICOCEE Special issue, 388-396. DOI: 10.17100/nevbiltek.322169
18. 18. Ojedokun, A.T., Bello, O.S. (2017). Kinetic modeling of liquid-phase adsorption of Congo red dye using guava leaf-based activated carbon. Appl. Water Sci. 7, 1965-1977.
19. 19. Öztürk, N., Bektaş T.E. (2004). Nitrate removal from aqueous solution by adsorption onto various materials. Journal of Hazardous Materials, 112 (1-2) 155-162.
20. 20. Soleimanifard, M., Mahoonak A.S., Sepahvand A., Heydari R., Farhadi S. (2019). Spanish olive leaf extract‐loaded nanostructured lipid carriers:Production and physicochemical characterization by Zetasizer, FT‐IR, DTA/TGA, FE‐SEM and XRD. J Food Process Preserv. 43:e13994.
21. 21. Srivastava, V., Choubey A.K. (2021). Investigation of adsorption of organic dyes present in wastewater using chitosan beads immobilized with biofabricated CuO nanoparticles. J. Mol. Struct., 1242, 130749.
22. 22. Şeker, A. F. (2007). Investigation of the removal of various dyestuffs used in the textile industry with activated carbon. Master's Thesis, Gebze Technical University, İzmit, Türkiye.
23. 23. URL-1 (2022). Artemis Arıtım, ‘’ What are BOD and COD parameters?’’ www.artemisaritim.com 24. URL-2 (2022). Wikipedia, ‘Wastewater treatment’’, https://tr.wikipedia.org
24. 25. URL-3 (2012). https://cevre.erciyes.edu.tr/upload/XYN1LR12-koI.pdf, Chemical Oxygen Demand, (2012). Kayseri: Erciyes University, Department of Environmental Engineering, Environmental Chemistry Laboratory Course.
25. 26. URL-4 (2022). https://tibuad.istanbul.edu.tr/tr/content/blog/olea-europaea-l.-folium-(zeytin-yapragi)
26. 27. Wang, H., Wei, Y. (2017). Magnetic graphene oxide modified by chloride imidazole ionic liquid for the high-efficiency adsorption of anionic dyes. RSC Adv., 7, 9079.
27. 28. Weber, W.J. (1972). Physicochemical Processes for water Quality Control, Wiley, New York, 640.
28. 29. Yagub, M.T., Sen, T.K., Afroze, S., Ang, H.M. (2014). Dye and its removal from aqueous solution by adsorption: a review. Adv. Colloid Interface Sci. 209, 172-184.
29. 30. Yao, Y., Bing, H., Feifei, X., Xiaofeng, C. (2011). Equilibrium and kinetic studies of methyl orange adsorption on multiwalled carbon nanotubes. Chem. Eng. J. 170(1), 82-89.
30. 31. Yusoff, N.H.M., Chong C.H., Wong V.L., Cheah K.H., Wan Y.K. (2023). The influence of structural topology od additively manufactured PEGDA monolith on adsorption performance for textile wastewater treatment. Asia-Pac. J. Chem. e2952.
31. 32. Xue, A., Zhou, S., Zhao, Y., Lu, X., Han, P. (2010). Adsorption of reactive dyes from aqueous solution by silylated palygorskite. App. Clay Sci. 48(4), 638-640.