Computer
based simulations for the three-body recombination reaction of nitrogen (II) oxide
with the hydroxyl radical have been used to estimate the error associated with
the pseudo-first orderapproximation
under different simulated conditions. For the absolute rate coefficients
calculated by dividing the pseudo-first
order constant by the concentration of the reactant in excess, the analysis of
the relative error associated with working under pseudo-first order conditions shows that for a reactiants’ ratio
higher than 10, the relative error is less than 5%.
Pseudo-first order conditions absolute rate coefficient computer simulations
Konular | Mühendislik, Kimya Mühendisliği |
---|---|
Bölüm | Makaleler |
Yazarlar | |
Yayımlanma Tarihi | 1 Eylül 2017 |
Gönderilme Tarihi | 10 Ağustos 2017 |
Kabul Tarihi | 25 Ekim 2017 |
Yayımlandığı Sayı | Yıl 2018 Cilt: 5 Sayı: 1 |