Determination of Titanium in Zinc ash by FAAS After Digested using Ultrasound-Assisted Extraction
Yıl 2021,
, 147 - 154, 30.06.2021
Fatma Kurşun
,
Buse Dağcı
Cemile Özcan
Öz
In this study, it is aimed to determine the amount of Ti (titanium) in waste ash samples taken from galvanizing factories by using flame atomic absorption (FAAS). Various time periods and different solvent mixtures were examined by using ultrasound-assisted extraction for digestion of zinch ash which taken from various processes of galvanizing metal sheet or pipe. The best solvent mixtures for Ti metal in galvanized waste was found HCl:HNO3:H2O2 (1:3:2) > HCl > HNO3:HCl (1:3) > HNO3 > HNO3:H2SO4 (3:1) > HNO3:H2SO4 (1:1) > HNO3:H2SO4 (3:2) > HNO3:H2SO4 (2:1), respectively.
Kaynakça
- [1] Dvorak, P., Jandova, J., Hydrometallurgical recovery of zinc from hot dip galvanizing ash. Hydrometallurgy, C 77, S 29-33, 2005.
- [2] Ahmer, C., Maaß, P., Peißker, P., Handbook of Hot-dip Galvanization. WILLEY-VCH Verlag GmbH & Co, KGaA, Weinheim, 2011.
- [3] Delvasto, P., Casal-Ramos, J. A., González-Jordán, O., Durán-Rodríguez, N. C., Domínguez-Vargas, J. R., Moncada, P., Caracterización de residuos sólidos procedentes de dos procesos distintos de galvanizado en caliente por inmersión, Revista De Metalurgia, C 48(1), S 33-44, 2012.
- [4] Trpcevska, J., Holkova, B., Briancin, J., Koralova, K., Piroskova J., The pyrometallurgical recovery of zinc from the coarse-grained fraction of zinc ash by centrifugal force, Int. J. Miner. Process., C 143, S 25-33, 2015.
- [5]Url4<https://webdosya.csb.gov.tr/db/cygm/editordosya/Galvaniz_Kaplama_Kilavuzu.pdf>, erişim tarihi 13.06.2020.
- [6] Ogden, H. R., Clifford, A. H., Rare Metals. Handbook, Reinhold Publishing Corporation, Chapman&Hall Ltd., London, UK,, S 559-579, 1961.
- [7] Url-1<https://www.britannica.com/technology/titanium-processing/The-metal-and-its-alloys>, erişim tarihi 31.03.2020.
- [8] Burke, R. A., Hazardous Materials Chemistry for Emergency Responders, CRC Press, S 51-516, 2013.
- [9] Petry, C. F., Capeletti, L. B., Stedile, F. C., dos Santos, J. H. Z., Pozebon, D., Determination of Titanium and Vanadium in Ziegler-Natta Catalysts by Inductively Coupled Plasma Atomic Emissin Spectrometry, Analytical, Sciences, The Japan Society for Analytical Chemistry, C 22, S 855-859, 2006.
- [10] Mirzaei, M. Naeini A. K., Determination of Trace Amounts of Titanium by Flame Atomic Absorption Spectrometry after Cloud Point Extraction, Journal of Analytical Chemistry, C 68(7), S 595-599, 2013.
- [11] Harris, D. C., Quantitative Chemical Analysis (8th edition) Translation Editor: Türker, A.R., Ankara, 2015.
DETERMINATION OF TITANIUM IN ZINC ASH BY FAAS AFTER DIGESTED USING ULTRASOUND-ASSISTED EXTRACTION
Yıl 2021,
, 147 - 154, 30.06.2021
Fatma Kurşun
,
Buse Dağcı
Cemile Özcan
Öz
Bu çalışmada, alevli atomik absorpsiyon (FAAS) kullanılarak galvaniz fabrikalarından alınan atık kül örneklerindeki Ti (titanyum) miktarının belirlenmesi amaçlanmıştır. Çeşitli galvanizleme sac veya boru proseslerinden elde edilen çinko külünün çözünürleştirilmesi için ses destekli ekstraksiyon kullanılarak çeşitli zaman periyotları ve farklı çözücü karışımları incelenmiştir. Galvanizli atıkta Ti metali için en iyi çözücü karışımları sırasıyla, HCl:HNO3:H2O2 (1:3:2) > HCl > HNO3:HCl (1:3) > HNO3 > HNO3:H2SO4 (3:1) > HNO3:H2SO4 (1:1) > HNO3:H2SO4 (3:2) > HNO3:H2SO4 (2:1) olarak bulunmuştur.
Kaynakça
- [1] Dvorak, P., Jandova, J., Hydrometallurgical recovery of zinc from hot dip galvanizing ash. Hydrometallurgy, C 77, S 29-33, 2005.
- [2] Ahmer, C., Maaß, P., Peißker, P., Handbook of Hot-dip Galvanization. WILLEY-VCH Verlag GmbH & Co, KGaA, Weinheim, 2011.
- [3] Delvasto, P., Casal-Ramos, J. A., González-Jordán, O., Durán-Rodríguez, N. C., Domínguez-Vargas, J. R., Moncada, P., Caracterización de residuos sólidos procedentes de dos procesos distintos de galvanizado en caliente por inmersión, Revista De Metalurgia, C 48(1), S 33-44, 2012.
- [4] Trpcevska, J., Holkova, B., Briancin, J., Koralova, K., Piroskova J., The pyrometallurgical recovery of zinc from the coarse-grained fraction of zinc ash by centrifugal force, Int. J. Miner. Process., C 143, S 25-33, 2015.
- [5]Url4<https://webdosya.csb.gov.tr/db/cygm/editordosya/Galvaniz_Kaplama_Kilavuzu.pdf>, erişim tarihi 13.06.2020.
- [6] Ogden, H. R., Clifford, A. H., Rare Metals. Handbook, Reinhold Publishing Corporation, Chapman&Hall Ltd., London, UK,, S 559-579, 1961.
- [7] Url-1<https://www.britannica.com/technology/titanium-processing/The-metal-and-its-alloys>, erişim tarihi 31.03.2020.
- [8] Burke, R. A., Hazardous Materials Chemistry for Emergency Responders, CRC Press, S 51-516, 2013.
- [9] Petry, C. F., Capeletti, L. B., Stedile, F. C., dos Santos, J. H. Z., Pozebon, D., Determination of Titanium and Vanadium in Ziegler-Natta Catalysts by Inductively Coupled Plasma Atomic Emissin Spectrometry, Analytical, Sciences, The Japan Society for Analytical Chemistry, C 22, S 855-859, 2006.
- [10] Mirzaei, M. Naeini A. K., Determination of Trace Amounts of Titanium by Flame Atomic Absorption Spectrometry after Cloud Point Extraction, Journal of Analytical Chemistry, C 68(7), S 595-599, 2013.
- [11] Harris, D. C., Quantitative Chemical Analysis (8th edition) Translation Editor: Türker, A.R., Ankara, 2015.