Pyrolytic Degradation Behavior of Biomass Seeds: Cherry And Peach Seed
Yıl 2020,
Cilt: 3 Sayı: 2, 46 - 51, 30.11.2020
Meltem Kızılca Çoruh
,
Hatice Bayrakçeken
Öz
Pyrolytic degradation behavior of peach and cherry seed were investigated by thermal analysis techniques such as thermogravimetric (TG) and derivative thermogravimetric (DTG). Pyrolysis study of peach and cherry seed, which are the sources of plant biomass, are carried out under air flow rate of 10 mL.min-1 and heating rates of 2.5-5-10 and 20 K min-1 in the temperature range of 298-1173 K by means of thermal analysis techniques. The activation energy and pre-exponential factor were determined with different methods as Kissinger–Akahira–Sunose (KAS) and Flyn–Wall–Ozawa (FWO). The average activation energies (Ea) and pre-exponential factor (A) obtained from both models for cherry and peach seed were found as: Ea=125.77 kJ mol-1 and A=13.03 min-1 for KAS; Ea=135.59 kJ mol-1 and A= 27.77 min-1 for FWO and Ea=204.93 kJ mol-1 and A=34.12 min-1 for KAS; Ea=213.47 kJ mol-1 and A= 44.34 min-1 for FWO, respectively.
Kaynakça
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- [14] Polat S., Apaydin-Varol E., Eren Pütün A., 2016. Thermal Decomposition Behavior of Tobacco Stem Part II: Kinetic Analysis. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 38, pp. 3073–3080.
- [15] Liu H., Ahmad M. S., Alhumade H., Elkamel A., Sammak S., Shen B., 2020. A Hybrid Kinetic and Optimization Approach for Biomass Pyrolysis: The Hybrid Scheme of the Isoconversional Methods, DAEM, and a Parallel Reaction Mechanism. Energy Conversion and Management, 208, 112531.
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Yıl 2020,
Cilt: 3 Sayı: 2, 46 - 51, 30.11.2020
Meltem Kızılca Çoruh
,
Hatice Bayrakçeken
Kaynakça
- [1] Özsina G., Eren Pütün A., 2019. TGA/MS/FT-IR Study for Kinetic Evaluation and Evolved Gas Analysis of a Biomass/PVC Co-pyrolysis Process. Energy Conversion and Management, 182, pp.143–153.
- [2] Demirbaş A., 2001. Biomass Resource Facilities and Biomass Conversion Processing for Fuels and Chemicals. Energy Conversion and Management, 182, pp.143–153.
- [3] Zhang L., Xu C., Champagne P., 2010. Overview of Recent Advances in Tthermo-chemical Conversion of Biomass. Energy Conversion and Management, 51, pp. 969–982.
- [4] Samolada M. C., Stoicos T., Vasalos I. A., 1990. An Investigation of the Factors Controlling the Pyrolysis Product Yield of Greek Wood Biomass in a Fluidized Bed. Journal of Analytical and Applied Pyrolysis, 18, pp. 127-141.
- [5] Kızılca M., Copur M., 2016. Investigation of the Thermal Decomposition Kinetics of Chalcopyrite Ore Concentrate Using Thermogravimetric Data. Chemical Engineering Communications, 203, pp. 692-704.
- [6] Özçimen D., Ersoy-Meriçboyu A., 2008. A Study on the Carbonization of Grapeseed and Chestnut Shell. Fuel Process Technol, 89, pp. 1041-1046.
- [7] Özçimen D., Ersoy-Meriçboyu A., 2010. Characterization of Bio Char and Bio-oil Samples Obtained from Carbonization of Various Biomass Materials. Renewable Energy, 35, pp. 1319-1324.
- [8] Luz Bengoechea M., Sancho Begon I., Estrella I., Gomez-Cordoves C., Hernandez M. T., 1997. Phenolic Composition of Industrially Manufactured Pure´es and Concentrates from Peach and Apple Fruits. Journal of Agricultural and Food Chemistry. 45, 4071−4075.
- [9] Özsin G., Eren Pütün A., 2018. Co-pyrolytic Behaviors of Biomass and Polystyrene: Kinetics, Thermodynamics and Evolved Gas Analysis, Korean J. Chem. Eng., 35, pp. 428-437.
- [10] Kantürk Figen A., Sarı Yılmaz M., Pişkin S., 2010. Structural Characterization and Dehydration Kinetics of Kırka Inderite Mineral: Application of Non-isothermal Models. Materials Characterization, 61, pp. 640-647.
- [11] Kızılca M., Copur M., 2017. Thermal Dehydration of Colemanite: Kinetics and Mechanism Determined Using the Master Plots Method. Canadian Metallurgical Quarterly, 56, pp. 259–27.
- [12] Ahmed A., Afolabi E. A., Garba M. U., Musa U., Alhassan A,. Ishaq I., 2019. Effect of Particle Size on Thermal Decomposition and Devolatilization Kinetics of Melon Seed Shell. Chemical Engineering Communications, 206, pp. 1228–1240.
- [13] Isıtan S., Ceylan S., Topcu Y., Hintz C., Tefft J., Chellappa T., Guo J., Goldfarb J. L., 2016. Product Quality Optimization in an Integrated Biorefinery: Conversion of Pistachio Nutshell Biomass to Biofuels and Activated Biochars via Pyrolysis. Energy Conversion and Management, 127, pp. 576–588.
- [14] Polat S., Apaydin-Varol E., Eren Pütün A., 2016. Thermal Decomposition Behavior of Tobacco Stem Part II: Kinetic Analysis. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 38, pp. 3073–3080.
- [15] Liu H., Ahmad M. S., Alhumade H., Elkamel A., Sammak S., Shen B., 2020. A Hybrid Kinetic and Optimization Approach for Biomass Pyrolysis: The Hybrid Scheme of the Isoconversional Methods, DAEM, and a Parallel Reaction Mechanism. Energy Conversion and Management, 208, 112531.
- [16] Setter C., Silva F. T. M., Assis M. R., Ataíde C. H., Trugilho P. F., Oliveira, T. J. P.,, 2020. Slow Pyrolysis of Coffee Husk Briquettes: Characterization of the Solid and Liquid Fractions. Fuel, 261, 116420.