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Preparation and Investigation of Thermal Properties of Polypyrrole and Polyacrylonitrile / Clay Composites

Yıl 2013, Cilt: 25 Sayı: 3, 134 - 139, 27.12.2013

Öz

The aim of this study was to improve thermal properties of polypyrrole and polyacrylonitrile. For this purpose, polypyrrole and polyacrylonitrile / clay composites were prepared by different methods. The thermal properties of the prepared composites were examined by thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC) techniques. The results obtained showed that thermal properties of the composites were a significantly increased with the increase in clay content in the formulation of composite.

Kaynakça

  • Goh, S.H., Chan, H.S.O. ve Ong, C.H. (1998). Miscible blends of conductive polyaniline with tertiary amide polymers. J. Appl. Polym. Sci., 68, 1839-1844.
  • Chen, K.H. ve Yang, S.M. (2003). Polyaniline-montmorillonite composite synthesized by electrochemical method. Synth. Met., 135, 151-152.
  • Omastova, M. ve Micusık, M. (2012). Polypyrrole coating of inorganic and organic materials by chemical oxidative polymerisation. Chem. Pap., 66, 392-414.
  • Chang, L.T. ve Yen, C.C. (1995). Studies on the preparation and properties of conductive polymers. VIII. Use of heat treatment to prepare metallized films from silver chelate of PVA and PAN. J. Appl. Polym. Sci., 55, 371-374.
  • Madakbaş, S., Çakmakçı, E., Kahraman, M.V. ve Esmer, K. (2013). Preparation, characterisation, and dielectric properties of polypyrrole-clay composites. Chem. Pap., 67, 1048-1053.
  • Shirakawa, H., Louis, E.J., MacDiarmid, A.G., Chiang, C.K. ve Heeger, A.J. (1977). Synthesis of electrically conducting organic polymers: halogen derivatives of polyacetylene, (CH) x . J. Chem. Soc. Chem. Com., 16, 578-580.
  • Pant, H.C., Patra, M.K., Negi, S.C., Bhatia, A., Vadera, S.R. ve Kumar, N. (2006). Studies on conductivity and dielectric properties of polyaniline-zinc sulphide composites. Bull. Mater. Sci. 29, 379-384.
  • Madakbaş¸ S., Çakmakçı, E., Kahraman, M.V. (2013). Preparation and thermal properties of polyacrylonitrile/hexagonal boron nitride composites. Thermochim. Acta, 552, 1-4. Şen, F. Ve Kahraman, M.V. (2013). Preparation and Properties of Nano Diamond / 6FBisphenol A Based Cyanate Ester Composites. Polym. Composite., 34, 1977-1985.

Polipirol ve Poliakrilonitril / Kil Kompozitlerin Hazırlanması ve Termal Özelliklerinin İncelenmesi

Yıl 2013, Cilt: 25 Sayı: 3, 134 - 139, 27.12.2013

Öz

Bu çalışmada polipirol ve poliakrilonitrilin termal özelliklerinin geliştirilmesi amaçlandı. Bu amaç için polipirol ve poliakrilonitril / kil kompozitler farklı metotlar ile hazırlandı. Hazırlanan kompozitlerin termal özellikleri termal gravimetrik analiz (TGA) ve diferansiyel taramalı kalorimetri (DSC) teknikleri ile incelendi. Elde edilen sonuçlar kompozit formülasyonlarında kil içeriğinin artması ile kompozitlerin termal özelliklerinde önemli bir artış olduğunu gösterdi.

Kaynakça

  • Goh, S.H., Chan, H.S.O. ve Ong, C.H. (1998). Miscible blends of conductive polyaniline with tertiary amide polymers. J. Appl. Polym. Sci., 68, 1839-1844.
  • Chen, K.H. ve Yang, S.M. (2003). Polyaniline-montmorillonite composite synthesized by electrochemical method. Synth. Met., 135, 151-152.
  • Omastova, M. ve Micusık, M. (2012). Polypyrrole coating of inorganic and organic materials by chemical oxidative polymerisation. Chem. Pap., 66, 392-414.
  • Chang, L.T. ve Yen, C.C. (1995). Studies on the preparation and properties of conductive polymers. VIII. Use of heat treatment to prepare metallized films from silver chelate of PVA and PAN. J. Appl. Polym. Sci., 55, 371-374.
  • Madakbaş, S., Çakmakçı, E., Kahraman, M.V. ve Esmer, K. (2013). Preparation, characterisation, and dielectric properties of polypyrrole-clay composites. Chem. Pap., 67, 1048-1053.
  • Shirakawa, H., Louis, E.J., MacDiarmid, A.G., Chiang, C.K. ve Heeger, A.J. (1977). Synthesis of electrically conducting organic polymers: halogen derivatives of polyacetylene, (CH) x . J. Chem. Soc. Chem. Com., 16, 578-580.
  • Pant, H.C., Patra, M.K., Negi, S.C., Bhatia, A., Vadera, S.R. ve Kumar, N. (2006). Studies on conductivity and dielectric properties of polyaniline-zinc sulphide composites. Bull. Mater. Sci. 29, 379-384.
  • Madakbaş¸ S., Çakmakçı, E., Kahraman, M.V. (2013). Preparation and thermal properties of polyacrylonitrile/hexagonal boron nitride composites. Thermochim. Acta, 552, 1-4. Şen, F. Ve Kahraman, M.V. (2013). Preparation and Properties of Nano Diamond / 6FBisphenol A Based Cyanate Ester Composites. Polym. Composite., 34, 1977-1985.

Ayrıntılar

Birincil Dil İngilizce
Bölüm Araştırma Makaleleri
Yazarlar

Seyfullah MADAKBAŞ


Memet Vezir KAHRAMAN


Ferhat ŞEN


Kadir ESMER

Yayımlanma Tarihi 27 Aralık 2013
Yayınlandığı Sayı Yıl 2013 Cilt: 25 Sayı: 3

Kaynak Göster

Bibtex @ { marufbd187455, journal = {Marmara Fen Bilimleri Dergisi}, eissn = {2146-5150}, address = {}, publisher = {Marmara Üniversitesi}, year = {2013}, volume = {25}, number = {3}, pages = {134 - 139}, doi = {10.7240/201332503}, title = {Preparation and Investigation of Thermal Properties of Polypyrrole and Polyacrylonitrile / Clay Composites}, key = {cite}, author = {Madakbaş, Seyfullah and Kahraman, Memet Vezir and Şen, Ferhat and Esmer, Kadir} }
APA Madakbaş, S. , Kahraman, M. V. , Şen, F. & Esmer, K. (2013). Preparation and Investigation of Thermal Properties of Polypyrrole and Polyacrylonitrile / Clay Composites . Marmara Fen Bilimleri Dergisi , 25 (3) , 134-139 . Retrieved from https://dergipark.org.tr/tr/pub/marufbd/issue/17881/187455
MLA Madakbaş, S. , Kahraman, M. V. , Şen, F. , Esmer, K. "Preparation and Investigation of Thermal Properties of Polypyrrole and Polyacrylonitrile / Clay Composites" . Marmara Fen Bilimleri Dergisi 25 (2013 ): 134-139 <https://dergipark.org.tr/tr/pub/marufbd/issue/17881/187455>
Chicago Madakbaş, S. , Kahraman, M. V. , Şen, F. , Esmer, K. "Preparation and Investigation of Thermal Properties of Polypyrrole and Polyacrylonitrile / Clay Composites". Marmara Fen Bilimleri Dergisi 25 (2013 ): 134-139
RIS TY - JOUR T1 - Polipirol ve Poliakrilonitril / Kil Kompozitlerin Hazırlanması ve Termal Özelliklerinin İncelenmesi AU - SeyfullahMadakbaş, Memet VezirKahraman, FerhatŞen, KadirEsmer Y1 - 2013 PY - 2013 N1 - DO - T2 - Marmara Fen Bilimleri Dergisi JF - Journal JO - JOR SP - 134 EP - 139 VL - 25 IS - 3 SN - -2146-5150 M3 - UR - Y2 - 2023 ER -
EndNote %0 Marmara Fen Bilimleri Dergisi Preparation and Investigation of Thermal Properties of Polypyrrole and Polyacrylonitrile / Clay Composites %A Seyfullah Madakbaş , Memet Vezir Kahraman , Ferhat Şen , Kadir Esmer %T Preparation and Investigation of Thermal Properties of Polypyrrole and Polyacrylonitrile / Clay Composites %D 2013 %J Marmara Fen Bilimleri Dergisi %P -2146-5150 %V 25 %N 3 %R %U
ISNAD Madakbaş, Seyfullah , Kahraman, Memet Vezir , Şen, Ferhat , Esmer, Kadir . "Preparation and Investigation of Thermal Properties of Polypyrrole and Polyacrylonitrile / Clay Composites". Marmara Fen Bilimleri Dergisi 25 / 3 (Aralık 2013): 134-139 .
AMA Madakbaş S. , Kahraman M. V. , Şen F. , Esmer K. Preparation and Investigation of Thermal Properties of Polypyrrole and Polyacrylonitrile / Clay Composites. MFBD. 2013; 25(3): 134-139.
Vancouver Madakbaş S. , Kahraman M. V. , Şen F. , Esmer K. Preparation and Investigation of Thermal Properties of Polypyrrole and Polyacrylonitrile / Clay Composites. Marmara Fen Bilimleri Dergisi. 2013; 25(3): 134-139.
IEEE S. Madakbaş , M. V. Kahraman , F. Şen ve K. Esmer , "Preparation and Investigation of Thermal Properties of Polypyrrole and Polyacrylonitrile / Clay Composites", Marmara Fen Bilimleri Dergisi, c. 25, sayı. 3, ss. 134-139, Ara. 2013, doi:10.7240/201332503

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