ADSORPTION OF REMAZOL BRILLANT BLUE R FROM AQUATIC SOLUTION USING NATURAL ADSORBENT (Pistachio Hull)
Yıl 2018,
Cilt: 13 Sayı: 2, 103 - 113, 21.04.2018
Serpil Savcı
,
Mutlu Yalvaç
,
Zeynep Karaman
Öz
This study examines
that adsorption of Remazol Brillant Blue R (RBBR) from aquatic solution was
studied using pistachio hull (PH) as an adsorbent. The removal efficiency of
pistachio hull was studied as a function of, pH, initial dye concentration,
adsorbent dose and time via batch method at room temperature. Langmuir and
Freundlich Isotherms applied to obtained data from experiments. The correlation
coefficient values shown that the data fit the Langmuir Isotherm (R2=0.9989)
compare to Freundlich Isotherm (R2=0.7825). Maximum adsorption
capacity was observed as 16.739mg/g. Thermodynamic parameters also studied. The
value of Gibbs Free Energy, (ΔG=2.696kJ/mol) is positive. This value is
indicated that the adsorption was not a spontaneous one. According to the
experimental data, pistachio hull can be used as an appropriate, no cost and
easy obtainable adsorbent for the removal of Remazol Brillant Blue R dye.
Kaynakça
- [1] Mittal, J., Mittal, A., Malviya, V.K., and Gupta, V.K., (2009). Adsorptive Removal of Hazardous Anionic Dye Congo Red from Wastewater Using Waste Materials and Recovery by Desorption. J. Colloid Interface Sci. Volume:340, Number:1, pp:16-26.
- [2] Liu, C.H., Wu, J.S., Chiu, H.C., Suen, S.Y., and Chu, K.H., (2007). Removal of Anionic Reactive Dyes from Water Using Anion Exchange Membranes as Adsorbers. Water Res. Volume:41, Number:1, pp:1491-1500.
- [3] Osugi, M.E., Rajeshwar, K., Ferraz, E.R.A., de Oliveira, D.P., Araújo, A.R., and Zanoni, M.V.B., (2009). Comparison of Oxidation Efficiency of Disperse Dyes by Chemical and Photoelectrocatalytic Chlorination and Removal of Mutagenic Activity. Electrochim. Acta. Volume: 54, pp: 2086-2093.
- [4] Wang, Q., Gao, D., Gao, C., Wei, Q., Cai, Y., Xu, J., Liu, X. and Xu, Y., (2012). Removal of a Cationic Dye by Adsorption/Photodegradation Using Electrospun PAN/O-MMT Composite Nanofibrous membranes coated with TiO2. Int. J. Photoenergy. Volume:2012, pp:680419-680426.
- [5] Deveci, T., Unyayar, A., and Mazmanci, M.A., (2004). Production of Remazol Brilliant Blue R Decolourising Oxygenase from the Culture Filtrate of Funalia trogii ATCC 200800. Journal of Molecular Catalysis B: Enzymatic. Volume:30, pp:25-32.
- [6] Amin, N.K., (2008). Removal of Reactive Dye from Aqueous Solutions by Adsorption onto Activated carbons Prepared from Sugarcane Bagasse Pith. Desalination. Volume:223, pp:152-161.
- [7] Sathishkumara, P., Arulkumarb, M., and Palvannanb, T., (2012). Utilization of Agro-Industrial Waste Jatropha curcas Pods as an Activated Carbon for the Adsorption of Reactive Dye Remazol Brilliant Blue R (RBBR). Journal of Cleaner Production. Volume:22, pp:67-75.
[8] Ergene, A., Ada, K., Tan, S., and Katırcıoğlu, H., (2009). Removal of Remazol Brilliant Blue R Dye from Aqueous Solutions by Adsorption onto Immobilized Scenedesmus quadricauda: Equilibrium and Kinetic Modeling Studies. Desalination. Volume:249, pp:1308-1314.
- [9] Sathishkumar, P., Arulkumar, M., and Palvannan, T., (2012). Utilization of Agro-Industrial Waste Jatropha curcas Pods as an Activated Carbon for the Adsorption of Reactive Dye Remazol Brilliant Blue R (RBBR). Journal of Cleaner Production. Volume:22, Number:1, pp:67-75.
- [10] Saha, T.K., Bhoumik, N.C., Karmaker, S., Ahmed, M.G., Ichikawa, H., and Fukumori, Y., (2010). Adsorption of Methyl Orange onto Chitosan from Aqueous Solution. J. Water Resource and Protection. Volume:2, pp:898-906.
- [11] Jayakumar, R., Prabaharan, M., Reis, R.L., and Mano, J.F., (2005). Graft Copolymerized Chitosan-Present Status and Applications, Carbohydr. Polym., Volume:62, pp:142-158.
- [12] Wen, Y.Z., Liu, W.Q., Fang, Z.H., and Liu, W.P., (2005). Effects of Adsorption Interferents on Removal of Reactive Red 195 Dye in Waste Water by Chitosan. J. Environ. Sci. China, Volume:17, pp:766-769.
- [13] Ho, Y.S., (2006). Isotherms for the Sorption of Lead onto Peat: Comparison of linear and non-linear methods. Polish Journal of Environmental Study, Volume:15, pp:81.
- [14] Silva, T.L., Ronix, A., Pezoti, O., Souza, L.S., Leandro, P.K.T., Bedin, K.C., Beltrame, K.K., Cazetta, A.L., and Almeida, V.C., (2016). Mesoporous Activated Carbon from Industrial Laundry Sewage Sludge: Adsorption studies of reactive dye Remazol Brilliant Blue R. Chemical Engineering Journal, Volume:303, pp:467-476.
- [15] Nair, V. and Vinu, R., (2016). Peroxide-assisted Microwave Activation of Pyrolysis Char for Adsorption of Dyes from Wastewater. Bioresource Technology, Volume:216, pp:511-519.
- [16] Moussavi, G. and Khosravi, R., (2011). The Removal of Cationic Dyes from Aqueous Solutions by Adsorption onto Pistachio Hull Waste. Chemical engineering research and design, Volume:89, pp:2182-2189.
- [17] Foo, K.Y. and Hameed, B.H., (2011). Preparation and Characterization of Activated Carbon from Pistachio Nut Shells via Microwave-Induced Chemical Activation. Biomass and bioenergy, Volume:35, pp:3257-3261.
- [18] Zhong, Z., Yanga, Q., Li, X.M., Luoa, K., Liua, Y., and Zeng, G.M., (2012). Preparation of Peanut Hull-Based Activated Carbon by Microwave-Induced Phosphoric Acid Activation and Its Application in Remazol Brilliant Blue R Adsorption, Industrial Crops and Products, Volume:37, pp:178-185.
- [19] Azhar Ahmad, M., Gazali Herawan, S., and Anas Yusof, A., (2014). Equilibrium, Kinetics, and Thermodynamics of Remazol Brilliant Blue R Dye Adsorption onto Activated Carbon Prepared from Pinang Frond", Mechanical Engineering, Volume:2014, pp:7.
- [20] Abramian, L. and El-Rassy, H., (2009). Adsorption Kinetics and Thermodynamics of Azo-Dye Orange II onto Highly Porous Titania Aerogel. Chemical Engineering Journal, Volume:150, pp:403-410.
- [21] Alkan, M., Demirbaş, O., and Doğan, M., (2007). Adsorption Kinetics and Thermodynamics of an Anionic Dye onto Sepiolite. Microporous and Mesoporous Materials, Volume:101, pp:388-396.
- [22] Namasivayam, C. and Kavitha, D., (2002). Removal of Congo Red from Water by Adsorption onto Activated Carbon Prepared from Coir Pith, an Agricultural Solid Waste. Dyes and Pigments, Volume:54, pp:47-58.
- [23] Azmier Ahmad, M., Ahmad, N., and Solomon Bello, O., (2015). Adsorption Kinetic Studies for the Removal of Synthetic Dye Using Durian Seed Activated Carbon. Journal of Dispersion Science and Technology, Volume:36, pp:670-684.
- [24] Javed, S.H., Zahir, H., Khan, A., Afzal, S., and Mansha M., (2018). Adsorption of Mordant Red 73 Dye on Acid Activated Bentonite: Kinetics and Thermodynamic Study. Journal of Molecular Liquids Volume:254, pp:398–405.
- [25] Konicki, W., Aleksandrzak, M., and Mijowska, E., (2017). Equilibrium, Kinetic and Thermodynamic Studies on Adsorption of Cationic Dyes from Aqueous Solutions Using Graphene Oxide. Chemical Engineering Research and design Volume:1, Number:23, pp:35–49.
- [26] Luo, H., Huang, X., Luo, Y., Li, Z., Li, L., Gao, C., Xiong, J., and Li, W., (2018). Adsorption Behavior and Mechanism of Acidic Blue 25 Dye onto Cucurbit [8] uril: A spectral and DFT Study. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy Volume:193 pp:125–132.
- [27] Belbachir, I. and Makhoukhi, B., (2017). Adsorption of Bezathren Dyes onto Sodic Bentonite from Aqueous Solutions. Journal of the Taiwan Institute of Chemical Engineers Volume:75, pp:105–111.
ADSORPTION OF REMAZOL BRILLANT BLUE R FROM AQUATIC SOLUTION USING NATURAL ADSORBENT (Pistachio Hull)
Yıl 2018,
Cilt: 13 Sayı: 2, 103 - 113, 21.04.2018
Serpil Savcı
,
Mutlu Yalvaç
,
Zeynep Karaman
Öz
This study examines that adsorption of Remazol Brillant Blue R (RBBR) from aquatic solution was studied using pistachio hull (PH) as an adsorbent. The removal efficiency of pistachio hull was studied as a function of, pH, initial dye concentration, adsorbent dose and time via batch method at room temperature. Langmuir and Freundlich Isotherms applied to obtained data from experiments. The correlation coefficient values shown that the data fit the Langmuir Isotherm (R2=0.9989) compare to Freundlich Isotherm (R2=0.7825). Maximum adsorption capacity was observed as 16.739mg/g. Thermodynamic parameters also studied. The value of Gibbs Free Energy, (ΔG=2.696kJ/mol) is positive. This value is indicated that the adsorption was not a spontaneous one. According to the experimental data, pistachio hull can be used as an appropriate, no cost and easy obtainable adsorbent for the removal of Remazol Brillant Blue R dye.
Kaynakça
- [1] Mittal, J., Mittal, A., Malviya, V.K., and Gupta, V.K., (2009). Adsorptive Removal of Hazardous Anionic Dye Congo Red from Wastewater Using Waste Materials and Recovery by Desorption. J. Colloid Interface Sci. Volume:340, Number:1, pp:16-26.
- [2] Liu, C.H., Wu, J.S., Chiu, H.C., Suen, S.Y., and Chu, K.H., (2007). Removal of Anionic Reactive Dyes from Water Using Anion Exchange Membranes as Adsorbers. Water Res. Volume:41, Number:1, pp:1491-1500.
- [3] Osugi, M.E., Rajeshwar, K., Ferraz, E.R.A., de Oliveira, D.P., Araújo, A.R., and Zanoni, M.V.B., (2009). Comparison of Oxidation Efficiency of Disperse Dyes by Chemical and Photoelectrocatalytic Chlorination and Removal of Mutagenic Activity. Electrochim. Acta. Volume: 54, pp: 2086-2093.
- [4] Wang, Q., Gao, D., Gao, C., Wei, Q., Cai, Y., Xu, J., Liu, X. and Xu, Y., (2012). Removal of a Cationic Dye by Adsorption/Photodegradation Using Electrospun PAN/O-MMT Composite Nanofibrous membranes coated with TiO2. Int. J. Photoenergy. Volume:2012, pp:680419-680426.
- [5] Deveci, T., Unyayar, A., and Mazmanci, M.A., (2004). Production of Remazol Brilliant Blue R Decolourising Oxygenase from the Culture Filtrate of Funalia trogii ATCC 200800. Journal of Molecular Catalysis B: Enzymatic. Volume:30, pp:25-32.
- [6] Amin, N.K., (2008). Removal of Reactive Dye from Aqueous Solutions by Adsorption onto Activated carbons Prepared from Sugarcane Bagasse Pith. Desalination. Volume:223, pp:152-161.
- [7] Sathishkumara, P., Arulkumarb, M., and Palvannanb, T., (2012). Utilization of Agro-Industrial Waste Jatropha curcas Pods as an Activated Carbon for the Adsorption of Reactive Dye Remazol Brilliant Blue R (RBBR). Journal of Cleaner Production. Volume:22, pp:67-75.
[8] Ergene, A., Ada, K., Tan, S., and Katırcıoğlu, H., (2009). Removal of Remazol Brilliant Blue R Dye from Aqueous Solutions by Adsorption onto Immobilized Scenedesmus quadricauda: Equilibrium and Kinetic Modeling Studies. Desalination. Volume:249, pp:1308-1314.
- [9] Sathishkumar, P., Arulkumar, M., and Palvannan, T., (2012). Utilization of Agro-Industrial Waste Jatropha curcas Pods as an Activated Carbon for the Adsorption of Reactive Dye Remazol Brilliant Blue R (RBBR). Journal of Cleaner Production. Volume:22, Number:1, pp:67-75.
- [10] Saha, T.K., Bhoumik, N.C., Karmaker, S., Ahmed, M.G., Ichikawa, H., and Fukumori, Y., (2010). Adsorption of Methyl Orange onto Chitosan from Aqueous Solution. J. Water Resource and Protection. Volume:2, pp:898-906.
- [11] Jayakumar, R., Prabaharan, M., Reis, R.L., and Mano, J.F., (2005). Graft Copolymerized Chitosan-Present Status and Applications, Carbohydr. Polym., Volume:62, pp:142-158.
- [12] Wen, Y.Z., Liu, W.Q., Fang, Z.H., and Liu, W.P., (2005). Effects of Adsorption Interferents on Removal of Reactive Red 195 Dye in Waste Water by Chitosan. J. Environ. Sci. China, Volume:17, pp:766-769.
- [13] Ho, Y.S., (2006). Isotherms for the Sorption of Lead onto Peat: Comparison of linear and non-linear methods. Polish Journal of Environmental Study, Volume:15, pp:81.
- [14] Silva, T.L., Ronix, A., Pezoti, O., Souza, L.S., Leandro, P.K.T., Bedin, K.C., Beltrame, K.K., Cazetta, A.L., and Almeida, V.C., (2016). Mesoporous Activated Carbon from Industrial Laundry Sewage Sludge: Adsorption studies of reactive dye Remazol Brilliant Blue R. Chemical Engineering Journal, Volume:303, pp:467-476.
- [15] Nair, V. and Vinu, R., (2016). Peroxide-assisted Microwave Activation of Pyrolysis Char for Adsorption of Dyes from Wastewater. Bioresource Technology, Volume:216, pp:511-519.
- [16] Moussavi, G. and Khosravi, R., (2011). The Removal of Cationic Dyes from Aqueous Solutions by Adsorption onto Pistachio Hull Waste. Chemical engineering research and design, Volume:89, pp:2182-2189.
- [17] Foo, K.Y. and Hameed, B.H., (2011). Preparation and Characterization of Activated Carbon from Pistachio Nut Shells via Microwave-Induced Chemical Activation. Biomass and bioenergy, Volume:35, pp:3257-3261.
- [18] Zhong, Z., Yanga, Q., Li, X.M., Luoa, K., Liua, Y., and Zeng, G.M., (2012). Preparation of Peanut Hull-Based Activated Carbon by Microwave-Induced Phosphoric Acid Activation and Its Application in Remazol Brilliant Blue R Adsorption, Industrial Crops and Products, Volume:37, pp:178-185.
- [19] Azhar Ahmad, M., Gazali Herawan, S., and Anas Yusof, A., (2014). Equilibrium, Kinetics, and Thermodynamics of Remazol Brilliant Blue R Dye Adsorption onto Activated Carbon Prepared from Pinang Frond", Mechanical Engineering, Volume:2014, pp:7.
- [20] Abramian, L. and El-Rassy, H., (2009). Adsorption Kinetics and Thermodynamics of Azo-Dye Orange II onto Highly Porous Titania Aerogel. Chemical Engineering Journal, Volume:150, pp:403-410.
- [21] Alkan, M., Demirbaş, O., and Doğan, M., (2007). Adsorption Kinetics and Thermodynamics of an Anionic Dye onto Sepiolite. Microporous and Mesoporous Materials, Volume:101, pp:388-396.
- [22] Namasivayam, C. and Kavitha, D., (2002). Removal of Congo Red from Water by Adsorption onto Activated Carbon Prepared from Coir Pith, an Agricultural Solid Waste. Dyes and Pigments, Volume:54, pp:47-58.
- [23] Azmier Ahmad, M., Ahmad, N., and Solomon Bello, O., (2015). Adsorption Kinetic Studies for the Removal of Synthetic Dye Using Durian Seed Activated Carbon. Journal of Dispersion Science and Technology, Volume:36, pp:670-684.
- [24] Javed, S.H., Zahir, H., Khan, A., Afzal, S., and Mansha M., (2018). Adsorption of Mordant Red 73 Dye on Acid Activated Bentonite: Kinetics and Thermodynamic Study. Journal of Molecular Liquids Volume:254, pp:398–405.
- [25] Konicki, W., Aleksandrzak, M., and Mijowska, E., (2017). Equilibrium, Kinetic and Thermodynamic Studies on Adsorption of Cationic Dyes from Aqueous Solutions Using Graphene Oxide. Chemical Engineering Research and design Volume:1, Number:23, pp:35–49.
- [26] Luo, H., Huang, X., Luo, Y., Li, Z., Li, L., Gao, C., Xiong, J., and Li, W., (2018). Adsorption Behavior and Mechanism of Acidic Blue 25 Dye onto Cucurbit [8] uril: A spectral and DFT Study. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy Volume:193 pp:125–132.
- [27] Belbachir, I. and Makhoukhi, B., (2017). Adsorption of Bezathren Dyes onto Sodic Bentonite from Aqueous Solutions. Journal of the Taiwan Institute of Chemical Engineers Volume:75, pp:105–111.