FOSFAT VE SİLİKAT KAPLANMIŞ ÇİNKONUN KOROZYONUNA ANİLİN VE Ce+3’ÜN ETKİSİ
Yıl 2017,
Cilt: 12 Sayı: 3, 158 - 167, 07.07.2017
DERYA Altuğ
TURAN Yanardağ
,
ALİ ABBAS Aksüt
Öz
Bu çalışmada, fosfat (disodyum fosfat, SP) ve silikat (disodyum silikat, SS) iyonları ile ön işlem yapılmış saf çinkonun klorür
ortamındaki korozyonuna anilin ve Ce3+’ün etkisi araştırılmıştır.
Fosfat ve silikat kaplanmış çinko, Ce3+ ile etkileştirilip ve
oksalat+anilin çözeltisinde dönüşümlü voltametri alındıktan sonra sodyum klorür
ortamındaki korozyonu potansiyelin zamanla değişimi (OCP), AC-empedans (EIS) ve
akım-potansiyel eğrileri alınarak incelenmiştir. Silikat üzerine yüksek
derişimli seryum kaplama çinkonun korozyon hızının daha düşük
olduğunu ve çinko metalini korozyondan daha fazla koruduğunu (%99) göstermiştir.
Kaynakça
- 1. Tallman, D.E., Spinks, G., Dominis, A., and Wallace, G.G., (2002). Electroactive Conducting Polymers for Corrosion Control. Part 1. General Introduction and A Review of Non-Ferrous Metals, Journal of Solid State Electrochemistry, Volume:6, pp:73-84.
- 2. Karpakam, V., Kamaraj, K., Sathiyanarayanan, S., Venkatachari, G., and Ramu, S., (2011). Electrosynthesis of Polyaniline-Molybdate Coating on Steel and its Corrosion Protection Performance, Electrochimica Acta, Volume:56, pp:2165−2173.
- 3. Gupta, G., Birbilis, N., Cook, A.B., and Khanna, A.S., (2013). Polyaniline-Lignosulfonate/Epoxy Coating for Corrosion Protection of AA2024-T3, Corrosion Science, Volume:67, pp:256−267.
- 4. Hosseini, M.G., Sabouri, M., and Shahrabi, T., (2007). Corosion Protection of Mild Steel by Polypyrole Phosphate Composite Coating, Progress in Organic Coatings, Volume:60, pp:178−185.
- 5. Kamaraj, K., Karpakam, V., Sathiyanarayanan, S., Syed Azim, S., and Venkatachari, G., (2011). Synthesis of Tungstate Doped Polyaniline and its Usefulness in Corrosion Protective Coatings, Electrochimica Acta, Volume:56, pp:9262−9268.
- 6. Tan, Y. and Ghandi, K., (2013). Kinetics and Mechanism of Pyrrole Chemical Polymerization, Synthetic Metals, Volume:175, pp:183–191.
- 7. Ateh, D.D., Navsaria, H.A., and Vadgama, P., (2006). Polypyrrole-Based Conducting Polymers and Interactions with Biological Tissues, Journal of The Royal Society Interface, Volume:3(11), pp:741–752.
- 8. Maksymiuk, K., (2006). Chemical Reactivity of Polypyrrole and its Relevance to Polypyrrole Based Electrochemical Sensors, Electroanalysis, Volume:18, pp:1537–1551.
- 9. Ansari, R., (2006). Polypyrrole Conducting Electroactive Polymers: Synthesis and Stability Studies, European Journal of Chemistry, Volume:3, pp:186–201.
- 10. Vernitskaya, T.V. and Efimov, O.N., (1997). Polypyrrole: A Conducting Polymer; its Synthesis, Properties and Applications, Russian Chemical Reviews, Volume:66(5), pp:443–454.
- 11. Troch-Nagels, G., Winand, R., Weymeersch, A., and Renard, L., (1992). Electron Conducting Organic Coating of Mild Steel by Electropolymerization, Journal Applied Electrochemistry, Volume:22(8), pp:756-764.
- 12. Wessling, B., (1994). Passivation of Metals by Coating with Polyaniline: Corrosion Potential Shift and Morphological Changes, Advanced Materials, Volume:6, pp:226-228.
- 13. Lu, W.K., Elsenbaumer, R.L., and Wessling, B., (1995). Corrosion Protection of Mild Steel by Coatings Containing Polyaniline, Synthetic Metals, Volume:71(1-13), pp:2163.
- 14. Camalet, J.L., Lacroix, J.C., Aeiyach, S., Chaneching, K., and Lacaze, P.C., (1996). Electrodeposition of Protective PolyanilineFilms on Mild-Steel, Journal of Electroanalytical Chemisty, Volume:416, pp:179-182.
- 15. Camalet, J.L., Lacroix, J.C., Aeiyach, S., Chaneching, K., and Lacaze, P.C., (1998). Electrosynthesis of Adherent Polyaniline Films on Iron and Mild-Steel Aqueous Oxalic-Acid Medium, Synthetic Metals, Volume:93(2), pp:133-142.
- 16. Camalet, J.L., Lacroix, J.C., Aeiyach, S., and Lacaze, P.C., (1998). Characterization of Polyaniline Films Electrodeposited on Mild-Steel in Aqueous P-Toluenesulfonic Acid-Solution, Journal of Electroanalytical Chemistry, Volume:445, pp:117-124.
- 17. Cachia, J.N., Deschanels, X., Den Auwer, Pinet, O., Phalippou, J., Hennig, C., and Scheinost, A., (2006). Enhancing Cerium and Plutonium Solubility by Reduction in Borosilicate Glass, Journal of Nuclear Materials, Volume:352(1-3), pp:182–189.
- 18. Bolat, E., Yanardağ, T., Küyükoğlu, M., and Aksüt, A.A., (2012). Corrosion of Magnesium Modified with Different Compounds in Cloride Solution, Protection of Metals and Physical Chemistry of Surfaces, Volume:48(2), pp:259-264.
- 19. Yanardağ, T. and Aksüt, A.A., (2012). Effect of Conversion Coatings and Oxalate ion on Corrosion of Pure Zinc in 1M NaCl Solution, Asian Journal of Chemistry, Volume:24(1), pp:345-349.
- 20. Topaktaş, M., Yanardağ, T., and Aksüt, A.A., (2008). Inhibiton Effects of Co+2, Ni+2,La+3 and Ce+3 ions on The corrosion of Aluminium and aluminium Alloys in the NaCl Solution, Communuciation Faculty Science University Ankara Series B, Volume:54(1), pp:1-13.
- 21. Zaid, B., Aeiyach, S., Lacaze, P.C., and Takenouti, H., (1998). A Two-Step Electropolymerisation of Pyrrole on Zn in Aqueous Media, Electrochimica Acta, Volume:43(16-17), pp:2331-2339.
- 22. Paliwoda-Porebsaka, G., Stratmann, M., Rohwerder, M., Rammelt, U., Minh Duc, L., and Pleith, W., (2006). Release Mechanism of Electrodeposited Polypyrrole Doped with Corrosion Inhibitor Anions, Journal of Solid State Electrochemistry, Volume:10(9), pp:730-736.
23. Mouanga, M., Berçot, P., and Rauch, J.Y., (2010). Comparison of Corrosion Behaviour of Zinc in NaCl and in NaOH Solutions. Part I: Corrosion Layer Characterization, Corrosion Science, Volume:52, 3984-3992.
- 24. D’Alkaline, C.V. and Boucherit, M.N., (1997). Potentiostatic Growth of ZnO on Zn: Application of an Ohmic Model, Journal of Electrochemical Society, Volume:144(10), pp:3331-3336.
- 25. Peulon, S. and Lincot, D., (1998). Mechanistic Study of Cathodic Elecfrodeposition of Zinc Oxide and Zinc Hydroxychioride Films from Oxygenated Aqueous Zinc Chloride Solutions, Journal of Electrochemical Society, Volume:145(3), pp:864-874.
- 26. Kazanskii, L.P., Sokolova, E.M., and Pronin, Y.E., (2013). Adsorption of 1,2,3-Benzotriazole on Zinc Surface from Phosphate Solution, Protection of Metals and Physical Chemistry of Surfaces, Volume:49(7), pp:844–853.
Yıl 2017,
Cilt: 12 Sayı: 3, 158 - 167, 07.07.2017
DERYA Altuğ
TURAN Yanardağ
,
ALİ ABBAS Aksüt
Kaynakça
- 1. Tallman, D.E., Spinks, G., Dominis, A., and Wallace, G.G., (2002). Electroactive Conducting Polymers for Corrosion Control. Part 1. General Introduction and A Review of Non-Ferrous Metals, Journal of Solid State Electrochemistry, Volume:6, pp:73-84.
- 2. Karpakam, V., Kamaraj, K., Sathiyanarayanan, S., Venkatachari, G., and Ramu, S., (2011). Electrosynthesis of Polyaniline-Molybdate Coating on Steel and its Corrosion Protection Performance, Electrochimica Acta, Volume:56, pp:2165−2173.
- 3. Gupta, G., Birbilis, N., Cook, A.B., and Khanna, A.S., (2013). Polyaniline-Lignosulfonate/Epoxy Coating for Corrosion Protection of AA2024-T3, Corrosion Science, Volume:67, pp:256−267.
- 4. Hosseini, M.G., Sabouri, M., and Shahrabi, T., (2007). Corosion Protection of Mild Steel by Polypyrole Phosphate Composite Coating, Progress in Organic Coatings, Volume:60, pp:178−185.
- 5. Kamaraj, K., Karpakam, V., Sathiyanarayanan, S., Syed Azim, S., and Venkatachari, G., (2011). Synthesis of Tungstate Doped Polyaniline and its Usefulness in Corrosion Protective Coatings, Electrochimica Acta, Volume:56, pp:9262−9268.
- 6. Tan, Y. and Ghandi, K., (2013). Kinetics and Mechanism of Pyrrole Chemical Polymerization, Synthetic Metals, Volume:175, pp:183–191.
- 7. Ateh, D.D., Navsaria, H.A., and Vadgama, P., (2006). Polypyrrole-Based Conducting Polymers and Interactions with Biological Tissues, Journal of The Royal Society Interface, Volume:3(11), pp:741–752.
- 8. Maksymiuk, K., (2006). Chemical Reactivity of Polypyrrole and its Relevance to Polypyrrole Based Electrochemical Sensors, Electroanalysis, Volume:18, pp:1537–1551.
- 9. Ansari, R., (2006). Polypyrrole Conducting Electroactive Polymers: Synthesis and Stability Studies, European Journal of Chemistry, Volume:3, pp:186–201.
- 10. Vernitskaya, T.V. and Efimov, O.N., (1997). Polypyrrole: A Conducting Polymer; its Synthesis, Properties and Applications, Russian Chemical Reviews, Volume:66(5), pp:443–454.
- 11. Troch-Nagels, G., Winand, R., Weymeersch, A., and Renard, L., (1992). Electron Conducting Organic Coating of Mild Steel by Electropolymerization, Journal Applied Electrochemistry, Volume:22(8), pp:756-764.
- 12. Wessling, B., (1994). Passivation of Metals by Coating with Polyaniline: Corrosion Potential Shift and Morphological Changes, Advanced Materials, Volume:6, pp:226-228.
- 13. Lu, W.K., Elsenbaumer, R.L., and Wessling, B., (1995). Corrosion Protection of Mild Steel by Coatings Containing Polyaniline, Synthetic Metals, Volume:71(1-13), pp:2163.
- 14. Camalet, J.L., Lacroix, J.C., Aeiyach, S., Chaneching, K., and Lacaze, P.C., (1996). Electrodeposition of Protective PolyanilineFilms on Mild-Steel, Journal of Electroanalytical Chemisty, Volume:416, pp:179-182.
- 15. Camalet, J.L., Lacroix, J.C., Aeiyach, S., Chaneching, K., and Lacaze, P.C., (1998). Electrosynthesis of Adherent Polyaniline Films on Iron and Mild-Steel Aqueous Oxalic-Acid Medium, Synthetic Metals, Volume:93(2), pp:133-142.
- 16. Camalet, J.L., Lacroix, J.C., Aeiyach, S., and Lacaze, P.C., (1998). Characterization of Polyaniline Films Electrodeposited on Mild-Steel in Aqueous P-Toluenesulfonic Acid-Solution, Journal of Electroanalytical Chemistry, Volume:445, pp:117-124.
- 17. Cachia, J.N., Deschanels, X., Den Auwer, Pinet, O., Phalippou, J., Hennig, C., and Scheinost, A., (2006). Enhancing Cerium and Plutonium Solubility by Reduction in Borosilicate Glass, Journal of Nuclear Materials, Volume:352(1-3), pp:182–189.
- 18. Bolat, E., Yanardağ, T., Küyükoğlu, M., and Aksüt, A.A., (2012). Corrosion of Magnesium Modified with Different Compounds in Cloride Solution, Protection of Metals and Physical Chemistry of Surfaces, Volume:48(2), pp:259-264.
- 19. Yanardağ, T. and Aksüt, A.A., (2012). Effect of Conversion Coatings and Oxalate ion on Corrosion of Pure Zinc in 1M NaCl Solution, Asian Journal of Chemistry, Volume:24(1), pp:345-349.
- 20. Topaktaş, M., Yanardağ, T., and Aksüt, A.A., (2008). Inhibiton Effects of Co+2, Ni+2,La+3 and Ce+3 ions on The corrosion of Aluminium and aluminium Alloys in the NaCl Solution, Communuciation Faculty Science University Ankara Series B, Volume:54(1), pp:1-13.
- 21. Zaid, B., Aeiyach, S., Lacaze, P.C., and Takenouti, H., (1998). A Two-Step Electropolymerisation of Pyrrole on Zn in Aqueous Media, Electrochimica Acta, Volume:43(16-17), pp:2331-2339.
- 22. Paliwoda-Porebsaka, G., Stratmann, M., Rohwerder, M., Rammelt, U., Minh Duc, L., and Pleith, W., (2006). Release Mechanism of Electrodeposited Polypyrrole Doped with Corrosion Inhibitor Anions, Journal of Solid State Electrochemistry, Volume:10(9), pp:730-736.
23. Mouanga, M., Berçot, P., and Rauch, J.Y., (2010). Comparison of Corrosion Behaviour of Zinc in NaCl and in NaOH Solutions. Part I: Corrosion Layer Characterization, Corrosion Science, Volume:52, 3984-3992.
- 24. D’Alkaline, C.V. and Boucherit, M.N., (1997). Potentiostatic Growth of ZnO on Zn: Application of an Ohmic Model, Journal of Electrochemical Society, Volume:144(10), pp:3331-3336.
- 25. Peulon, S. and Lincot, D., (1998). Mechanistic Study of Cathodic Elecfrodeposition of Zinc Oxide and Zinc Hydroxychioride Films from Oxygenated Aqueous Zinc Chloride Solutions, Journal of Electrochemical Society, Volume:145(3), pp:864-874.
- 26. Kazanskii, L.P., Sokolova, E.M., and Pronin, Y.E., (2013). Adsorption of 1,2,3-Benzotriazole on Zinc Surface from Phosphate Solution, Protection of Metals and Physical Chemistry of Surfaces, Volume:49(7), pp:844–853.