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Advancing Ambient-Air Perovskite Solar Cells: Comparative Insights into Spin-Coating and Inkjet Printing for Performance, Stability, and Large-Area Scalability

Cilt: 6 Sayı: 1 31 Aralık 2025
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Advancing Ambient-Air Perovskite Solar Cells: Comparative Insights into Spin-Coating and Inkjet Printing for Performance, Stability, and Large-Area Scalability

Öz

Perovskite solar cells (PSCs) have emerged as a highly promising photovoltaic technology due to their high power conversion efficiencies, solution processability, and scalability potential. Among solution-based deposition methods, spin coating has traditionally dominated laboratory-scale fabrication, offering rapid crystallization and uniform films under controlled conditions; however, it suffers from high material waste and limited reproducibility for large-area devices. Inkjet printing, by contrast, provides a digital, additive, and scalable approach, enabling precise control over film thickness, patterning, and material usage, even under ambient air. This review provides a comparative analysis of spin-coated and inkjet-printed PSCs fabricated in air, focusing on film formation mechanisms, morphological and structural properties, optoelectronic performance, operational stability, and scalability. Recent studies (2018–2025) show that ambient-air-processed PSCs can achieve power conversion efficiencies of up to 17.7% (spin coating) and 12.4% (inkjet printing), with long-term stability exceeding 85%. Challenges such as droplet coalescence, coffee-ring effects, and humidity-induced degradation are addressed via ink formulation, substrate engineering, and hybrid fabrication strategies. These insights offer guidance for bridging the gap between laboratory research and industrial-scale production of air-processed PSCs.

Anahtar Kelimeler

Perovskite solar cells (PSCs), Spin coating deposition, Inkjet printing fabrication, Ambient-air processing, Large-area scalability, Thin-film morphology, Operational stability

Etik Beyan

This study is based solely on computational and theoretical methods and does not involve human participants, animals, or biological samples; therefore, ethical approval is not required.

Teşekkür

The author gratefully acknowledges the valuable data and insights obtained from previously published works on inkjet-printed perovskite solar cells fabricated under ambient air conditions.

Kaynakça

  1. X. Yang, et al., “High-efficiency perovskite solar cells processed under ambient air conditions,” Light: Science & Applications, vol. 13, pp. 1–11, 2024.
  2. R. Rahighi, e t al., “Sequential spin-coating engineering for uniform perovskite films fabricated in air,” Materials for Renewable and Sustainable Energy, vol. 13, pp. 55–70, 2024.
  3. S. L ee, et al., “Air-stable CsPbI₃ perovskite solar cells via controlled humidity processing,” Nature Communications Materials, vol. 9, pp. 1–12, 2025.
  4. R. Pesch, A. Dier cks, J. Petry, A. Welle, R. Pappenberger, F. Schackmar, H. Eggers, J. Sutter, U. Lemmer, and U. W. Paetzold, “Hybrid two-step inkjet-printed perovskite solar cells,” Solar RRL, vol. 18, no. 2, 202400165, 2024. [Online]. Available: https:/ /doi.org/10.1002/solr.202400165.
  5. P . W.-K. Fong, H. Hu, Z. Ren, K. Liu, L. Cui, T. Bi, Q. Liang, Z. Wu, J. Hao, and G. Li, “Printing high-efficiency pe - rovskite solar cells in high-humidity ambient environment—An in situ guided investigation,” Advanced Science, vol. 8, no. 8, 202003359, 2021. [Online]. Available: https:/ /doi.org/10.1002/advs.202003359.
  6. J. Boucl é, et al., “Influence of humidity and ink wettability on perovskite layer formation,” Solar RRL, vol. 3, 1900170, 2019.
  7. R. Rahighi, e t al., “Sequential spin coating improves film compactness under ambient air,” Materials for Renewable and Sustainable Energy, vol. 13, pp. 55–70, 2024.
  8. S. L ee, et al., “Humidity-driven δ-phase transition in CsPbI₃ perovskite thin films,” Nature Communications Materials, vol. 9, 2025.
  9. X. Yang, et al., “Dimethylammonium-assisted crystallization control of perovskite films processed in air,” Light: Science & Applications, vol. 13, 2024.
  10. A. Gheno , et al., “Effect of halide additives on ink wettability and morphology of inkjet-printed perovskite films,” Solar RRL, vol. 2, 2018.

Kaynak Göster

APA
Bashir, R., & İnanc, İ. (2025). Advancing Ambient-Air Perovskite Solar Cells: Comparative Insights into Spin-Coating and Inkjet Printing for Performance, Stability, and Large-Area Scalability. OMÜ Mühendislik Bilimleri ve Teknolojisi Dergisi, 6(1), 1-20. https://izlik.org/JA95BL48DA
AMA
1.Bashir R, İnanc İ. Advancing Ambient-Air Perovskite Solar Cells: Comparative Insights into Spin-Coating and Inkjet Printing for Performance, Stability, and Large-Area Scalability. OMUJEST. 2025;6(1):1-20. https://izlik.org/JA95BL48DA
Chicago
Bashir, Rakan, ve İbrahim İnanc. 2025. “Advancing Ambient-Air Perovskite Solar Cells: Comparative Insights into Spin-Coating and Inkjet Printing for Performance, Stability, and Large-Area Scalability”. OMÜ Mühendislik Bilimleri ve Teknolojisi Dergisi 6 (1): 1-20. https://izlik.org/JA95BL48DA.
EndNote
Bashir R, İnanc İ (01 Aralık 2025) Advancing Ambient-Air Perovskite Solar Cells: Comparative Insights into Spin-Coating and Inkjet Printing for Performance, Stability, and Large-Area Scalability. OMÜ Mühendislik Bilimleri ve Teknolojisi Dergisi 6 1 1–20.
IEEE
[1]R. Bashir ve İ. İnanc, “Advancing Ambient-Air Perovskite Solar Cells: Comparative Insights into Spin-Coating and Inkjet Printing for Performance, Stability, and Large-Area Scalability”, OMUJEST, c. 6, sy 1, ss. 1–20, Ara. 2025, [çevrimiçi]. Erişim adresi: https://izlik.org/JA95BL48DA
ISNAD
Bashir, Rakan - İnanc, İbrahim. “Advancing Ambient-Air Perovskite Solar Cells: Comparative Insights into Spin-Coating and Inkjet Printing for Performance, Stability, and Large-Area Scalability”. OMÜ Mühendislik Bilimleri ve Teknolojisi Dergisi 6/1 (01 Aralık 2025): 1-20. https://izlik.org/JA95BL48DA.
JAMA
1.Bashir R, İnanc İ. Advancing Ambient-Air Perovskite Solar Cells: Comparative Insights into Spin-Coating and Inkjet Printing for Performance, Stability, and Large-Area Scalability. OMUJEST. 2025;6:1–20.
MLA
Bashir, Rakan, ve İbrahim İnanc. “Advancing Ambient-Air Perovskite Solar Cells: Comparative Insights into Spin-Coating and Inkjet Printing for Performance, Stability, and Large-Area Scalability”. OMÜ Mühendislik Bilimleri ve Teknolojisi Dergisi, c. 6, sy 1, Aralık 2025, ss. 1-20, https://izlik.org/JA95BL48DA.
Vancouver
1.Rakan Bashir, İbrahim İnanc. Advancing Ambient-Air Perovskite Solar Cells: Comparative Insights into Spin-Coating and Inkjet Printing for Performance, Stability, and Large-Area Scalability. OMUJEST [Internet]. 01 Aralık 2025;6(1):1-20. Erişim adresi: https://izlik.org/JA95BL48DA