Removal of Remazol Brilliant Blue R (RBBR) dyes with a low cost adsorbent, cigarette ash

Yıl 2018, , 174 - 180, 01.04.2018

Rabia Köklü , Çiğdem Özer

https://doi.org/10.16984/saufenbilder.329234

Cited By: 1

Öz

The treatment of wastewaters contaminated with dye from the widespread use of dyestuff is an important environmental issue.  Smoking is also a harmful habit that many people have nowadays. This study aimed to investigate the Remazol Brillant Blue R (RBBR) adsorb ability of the cigarette ash to gain a use area for waste ash generated during smoking and to introduce a new, alternative and low cost adsorbent in the removal of dyestuff by adsorption method.  For this purpose, the conditions of RBBR adsorption on the cigarette ash, which is a costless adsorbent, were investigated according to pH, initial dyestuff concentration, contact time and adsorbent dose and maximum adsorption capacity was determined as 178,57 mg/g. In addition, the suitability of experimental data with isotherm and kinetic models was analyzed and the parameters of these models were calculated. Adsorption of RBBR dye with cigarette ash has been shown to be better expressed by Langmuir isotherm.

Anahtar Kelimeler

RBBR, adsorption, cigarette ash, isotherm and kinetic

Remazol Brillant Blue R (RBBR) boyarmaddesinin düşük maliyetli bir adsorban olan sigara külü ile giderimi

Öz

Boyarmaddelerin geniş kullanımı sebebiyle ortaya çıkan boyalı atıksuların arıtılması önemli bir çevre sorunudur. Sigara kullanımı da günümüzde birçok kişinin sahip olduğu zararlı bir alışkanlıktır. Sigara kullanımı sırasında ortaya çıkan atık küllere bir kullanım alanı yaratmak ve boyarmaddelerin adsorpsiyon yöntemi ile gideriminde yeni, alternatif ve düşük maliyetli bir adsorban ortaya koymak amacıyla yola çıkılan bu çalışmada, sigara külünün Remazol Brillant Blue R (RBBR) boyarmaddesini adsorplama yeteneği araştırılmıştır.  Bu amaçla, RBBR boyarmaddesinin maliyetsiz bir adsorban olan sigara külü üzerine adsorbsiyon şartları pH, başlangıç boyarmadde konsantrasyonu, karıştırma süresi ve adsorbent dozuna bağlı olarak incelenmiş ve maksimum adsorbsiyon kapasitesi 178,57 mg/g olarak belirlenmiştir. Bunun yanında deneysel verilerin izoterm ve kinetik modellere uygunluğu araştırılmış ve bu modellere ait parametreler hesaplanmıştır. RBBR boyarmaddesinin sigara külü ile adsorpsiyonunun Langmiur izotermi ile daha iyi ifade edildiği görülmüştür. 

Anahtar Kelimeler

RBBR, adsorpsiyon, sigara külü, izoterm ve kinetik

Kaynakça

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