Cobalt
(II) phthalocyanines carrying on the four of the peripheral positions
furan and thiophene as chalcones were sythesized. THF is used to investigate the catalytic
oxidation of 2-mercaptoethanol. The
synthesized phthalocyanines show catalytic activity on the oxidation of
2-mercaptoethanol. Cobalt (II) phthalocyanine derived by chalcone with furan
has given catalytic specifications such as turnover number TON as 16.6, initial
reaction rate as 0.293 μmol/sec
and the oxygen consumption as 10.06 μmol/min.
The other cobalt (II) phthalocyanine derived by chalcone with thiophene has
given catalytic specifications such as turnover number TON as 15.9, initial
reaction rate as 0.213 μmol/sec and
the oxygen consumption as 9.88 μmol/min. So chalcone derived phthalocyanines can be used as catalyst is oxidation
of mercaptan by air.
Birincil Dil | İngilizce |
---|---|
Konular | Kimya Mühendisliği |
Bölüm | Araştırma Makalesi |
Yazarlar | |
Yayımlanma Tarihi | 1 Aralık 2018 |
Gönderilme Tarihi | 19 Mart 2018 |
Kabul Tarihi | 17 Nisan 2018 |
Yayımlandığı Sayı | Yıl 2018 |
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