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Hollow Fiber Liquid Phase Microextraction

Yıl 2013, Cilt: 17 Sayı: 1, 17 - 26, 01.04.2013

Erol Alver Ayla Demirci Mustafa Özcimder

Öz

Even though high precision analytical devices are developed in qualitative and quantitative determination of substance or substances in matrix samples (biological, environmental, food etc.), analytical devices mostly fail determining in matrix environment. Due to such reasons, clean-up process is needed to take (purification) and concentrate (enrichment) the substance in matrix environment. Liquid-liquid (LLE) extraction is commonly used in preparation of the samples. In recent years, liquid phase micro extraction (LPME) methods minimizing organic solvent used in liquidliquid extraction are developed. Of these methods, hollow fiber liquid phase micro extraction (HF–LPME) is widely used.

Anahtar Kelimeler

Hollow fiber liquid phase microextraction HF–LPME Sample preparation Organic pollutants

Kaynakça

  • Pestisit Su İkili Faz GC-MS 1 Pestisit Deniz suyu İkili Faz GC-MS Pestisit Sebze Üçlü Faz LC-MS 2 İnsektisit Su İkili Sistem GC-FTD 3 PAH Su İkili Faz GC-MS PAH Su Tepe Boşluklu GC-MS PAH Su, Toprak Üçlü Faz GC-FID 4 PAH Toprak İkili Faz GC-FID PAH Çam İğnesi İkili Faz GC-MS PAH Atık Su İkili faz GC-MS Fenoksi Herbisit İnek Sütü Üçlü Faz HPLC-UV 5 Triazin Herbisit Toprak İkili faz GC-MS Fungusit Portakal Suyu Üçlü Faz LC-MS Fenolik Asit Meyve Suyu Üçlü Faz HPLC-DAD 6 Nitrofenol Deniz Suyu Üçlü Faz LC-UV Fenol Su Üçlü Faz CE(MEKC) 7 Fenol Deniz suyu İkili faz GC-MS Aromatik amin Su Üçlü Faz CE Aromatik amin Su Üçlü Faz HPLC Florokinolon Su, Hayvan İdrarı Üçlü Faz HPLC-DAD/FD 8 Sülfonamit Su Üçlü Faz HPLC-DAD/FD İlaç İdrar, Plazma Üçlü Faz HPLC-UV İlaç İdrar, Plazma Üçlü Faz ESI-IMS 9 İlaç Kan Üçlü Faz LC-MS İlaç Arıtma Çamuru Üçlü Faz LC-MS İlaç Atık Su Üçlü Faz LC-MS-MS İlaç Su, Plazma Üçlü Faz CE İlaç İdrar, Plazma Üçlü Faz CE İlaç İdrar,Su Üçlü Faz CE-DAD/UV 10 Pb, Ni Su İkili Faz ETAAS 11 Cu, Zn, Pd, Cd, Hg, Pb, Bi Serum As(III), As(V) İçme Suyu, Saç İkili Faz ETAAS Uçuçu Selenyum Bileşikleri Su, toprak Metil-Hg Saç, Çamur İkili Faz GFAAS 13 1) GC-MS: Gaz Kromatograf- Kütle Spektrometresi 2) LC-MS: Sıvı Kromatograf- Kütle Spektrometresi 3) GC-FTD: Gaz Kromatograf-Termiyonik Detektör (Nitrojen-Fosfor Detektör, NPD) 4) GC-FID: Gaz Kromatograf-Alev İyonlaşma Detektörü 5) HPLC-UV: Yüksek Basınç Sıvı Kromatograf-UV Detektör 6) HPLC-DAD: Yüksek Basınç Sıvı Kromatograf-Diode Array Detektör 7) MEKC: Misel Elektrokinetik Kromatografi 8) HPLC-DAD/FD: Yüksek Basınç Sıvı Kromatograf-Diode Array/Floresan Detektör 9) ESI-IMS: Elektrosprey İyonizasyon-İyon Mobilite Spektrometresi 10) CE-DAD/Kapiler Elektroforez- Diode Array/UV Detektör 11) ETAAS: Elektrotermal Atomik Absorpsion Spektrometresi 12) ETV-ICP/MS: Elektrotermal Buharlaşma-İndüktif Optik Plazma Kütle Spektrometresi 13) GFAAS: Grafit Fırınlı Atomik Absorpsion Spektrometresi SONUÇ HF–LPME basit, hızlı, ucuz ve yüksek oranda seçici ve yüksek zenginleştirme faktörüne sahip bir yöntemdir. Oyuk fiber mikroekstraksiyon yöntemi çevresel, biyolojik, gıda örneklerinde ve asidik ve bazik ilaç analizlerinde zenginleştirmenin yanı sıra ön temizleme işlemini de aynı anda yaparak kullanılabilir. Fiber, alıcı fazın örnek çözelti ile doğrudan temasnı kestiğinden dolayı, şiddetli karıştırma hızlarında ekstraksiyon çözücüsü kaybını en az düzeylere indirir. Polipropilen fiber çok ucuz bir maliyete sahiptir. Bu nedenle, her analizde bir kez kullanılır. Fiberin her analizde bir kez kullanılması, önceki analizlerden kirlilik gelmesini engeller. Polipropilen hollow fiber küçük gözeneklere sahip olduğu için, matriks ortamdaki büyük molekül ağırlıklı kirliliklerin alıcı faza girmesini engelleyerek iyi bir ön temizleme işlemi yapar [2,13,22,29,67,71]. Yöntem, alıcı faz ile verici faz arasındaki membran bariyerin ekstraksiyon etkinliğini azaltması ve ekstraksiyon süresini uzatması, fiberin yüzeyinde hava kabarcıklarının oluşması ile ekstraksiyon etkinliği ve yinelenebilirliğin azaltması, gerçek örnek analizlerinde matriksin (kan, plazma, atık su) fiber üzerindeki gözenekleri tıkayabilmesi gibi dezavantajlara sahiptir [22,72,73]. KAYNAKLAR Krylov, V.A., Krylov, A.V, Mosyagin, P.V., Matkivskaya, Y.O., “Liquid–Phase Microextraction Preconcentration of Impurities”, Journal of Analytical Chemistry, 66, 331–350, (2011).
  • Psillakis, E., Kalogerakis, N., “Developments in liquid-phase microextraction”, Trends Anal. Chem., 22, 565–574, (2003).
  • Pena-Pereira, F., Lavilla, I., Bendicho, C., “Miniaturized preconcentration methods based on liquid-liquid extraction and their application in inorganic ultratrace analysis and speciation”, A review. Spectrochim. Acta, Part B 64, 1–15, (2009).
  • Mahugo-Santana, C., Sosa-Ferrera, Z., , TorresPadrón, M.E., Santana-Rodríguez, J.J., “Application of new approaches to liquid-phase microextraction for the determination of emerging pollutants”, Trends Anal. Chem, 30, 731–748, 20 C.F. Poole, “New trends in solid-phase extraction”, Trends Anal. Chem. 22, 362–373, (2003).
  • Arthur, C.L., Pawliszyn, J., “Solid phase microextraction with thermal desorption using fused silica optical fibers”, Anal. Chem., 62, 2145– 2148, (1990).
  • Malik, A. K., Kaur, V., Verma, N., “A review on solid phase microextraction—High performance liquid chromatography as a novel tool for the analysis of toxic metal ions”, Talanta, 68, 842–849, (2006).
  • Olariu, R-I., Vione, D., Grinberg, N., Arsene, C., “Sample preparation for trace analysis by chromatographic methods”, J. Liquid Chromatography & Related Technologies, 33, 1174–1207, (2010).
  • Dietz, C., Sanz, J., C´amara C., “Recent developments in solid-phase microextraction coatings and related techniques”, J. Chromatogr. A, 1103, 183–192, (2006).
  • Kumar, A., Gaurav, Malik, A.K., Tewary, D.K., Singh, . B., “A review on development of solid phase microextraction fibers by sol-gel methods and their applications” Anal. Chim. Acta, 610, 1–14 (2008).
  • Psillakis, E., Kalogerakis, N., “Solid-phase microextraction versus single-drop microextraction for the analysis of nitroaromatic explosives in water samples”, J. Chromatogr. A, 938, 113–120, (2001). H. Liu, P.K. Dasgupta, “Analytical Chemistry in a Drop. Solvent Extraction in a Microdrop”, Anal. Chem., 68, 1817-1826, (1996). Rasmussen, K.E., Pedersen-Bjergaard, S., “Developments in hollow fibre based, liquid-phase microextraction”, Trends Anal. Chem., 23, 1–10, (2004).
  • Jeannot, M.A., Cantwell, F.F., “Solvent microextraction into a single drop”, Anal. Chem., 68, 2236-2240, (1996).
  • He, Y., Lee, H.K., “Liquid phase microextraction in a single drop of organic solvent by using a conventional microsyringe”, Anal. Chem., 69, 4634–4640, (1997), L. Zhao, H.K. Lee, “Application of static liquidphase microextraction to the analysis of organochlorine pesticides in water”, J. Chromatogr. A, 919, 381–388, (2001).
  • Pedersen-Bjergaard, S., Rasmussen, K.E., “Liquidphase microextraction with porous hollow fibers, a miniaturized and highly flexible format for liquidliquid extraction”, J. Chromatogr. A, 1184, 132– 142, (2008).
  • Jeannot, M.A., Cantwell, F.F., “Mass transfer characteristics of solvent extraction into a single drop at the tip of a syringe needle”, Anal. Chem., 69, 235–239, (1997).
  • Theis, A.L., Waldack, A.J., Hansen, S.M., Jeannot, M.A., “Headspace solvent microextraction”, Anal. Chem. 73, 5651–5654, (2001).
  • Ma, M.H., Cantwell, F.F., “Solvent microextraction with simultaneous back-extraction for sample cleanup and preconcentration: Preconcentration into a single microdrop”, Anal. Chem., 71, 388– 393, (1999).
  • Liu, W.P., Lee, H.K., “Continuous-flow microextraction exceeding 1000-fold concentration of dilute analytes”, Anal. Chem., 72, 4462–4467, (2000).
  • Sarafraz-Yazdi, A., Amiri, A., “Liquid-phase microextraction”, Trends Anal. Chem., 29, 1–14, (2010).
  • Dadfarnia, S., Shabani, A.M.H., “Recent development in liquid phase microextraction for determination of trace level concentration of metals—A review”, Anal. Chim. Acta, 658, 107– 119, (2010).
  • K.E. Kramer, A.R.J. Andrews, “Screening method for 11-nor-Δ 9 -tetrahydrocannabinol-9-carboxylic acid in urine using hollow fiber membrane solvent microextraction with in-tube derivatization”, J. Chromatogr. B, 760, 27-36, (2001).
  • Pedersen-Bjergaard, S., Rasmussen, K.E., “Liquidliquid-liquid microextraction for sample preparation of biological fluids prior to capillary electrophoresis”, Anal. Chem. 71, 2650–2656, (1999).
  • De Jager, L.S., Andrews, A.R.J., “Preliminary studies of a fast screening method for cocaine and cocaine metabolites in urine using hollow fibre membrane solvent microextraction (HFMSME)”, Analyst, 126, 1298–1303, (2001).
  • Cuia, S., Tanb, S., Ouyang, G., Pawliszyn, J., “Automated polyvinylidene difluoride hollow fiber liquid-phase microextraction of flunitrazepam in plasma and urine samples for gas chromatography/tandem mass spectrometry”, J. Chromatogr. A, 1216, 2241–2247, (2009).
  • Li,Y., Xiong, Y., Fang, J., Wang, L., Liang, Q., “Application of hollow fiber liquid-phase microextraction in identification of oil spill sources”, J. Chromatogr. A, 1216, 6155–6161, (2009).
  • Pedersen-Bjergaard, S., Rasmussen, K.E., “Liquidphase microextraction with porous hollow fibers, a miniaturized and highly flexible format for liquid– liquid extraction”, J. Chromatogr. A, 1184, 132– 142, (2008).
  • Ho, T.S., Pedersen-Bjergaard, S., Rasmussen, K.E., “Recovery, enrichment and selectivity in liquidphase microextraction Comparison with conventional liquid-liquid extraction”, J. Chromatogr. A, 963, 3-17, (2002).
  • Pena-Pereira, F., Lavilla, I., Bendicho, C., “Liquidphase microextraction approaches combined with atomic detection”, Anal. Chim. Acta, 669, 1–16, (2010).
  • Lambropoulou, D.A., Albanis, T.A., “Application of hollow fiber liquid phase microextraction for the determination of insecticides in water”, J. Chromatogr. A, 1072, 55–61, (2005).
  • Zhao, L., Lee, H.K., “Liquid-Phase Microextraction Combined with Hollow Fiber as a Sample Preparation Technique Prior to Gas Chromatography/Mass Spectrometry”, Anal. Chem., 74, 2486-2492, (2002).
  • Jiang, X., Basheer, C., Zhang, J., Lee, H.K., “Dynamic hollow fiber-supported headspace liquid-phase microextraction”, J. Chromatogr. A, 1087, 289–294, (2005).
  • Hou, L., Shen, G., Lee, H.K., “Automated hollow fiber-protected dynamic liquid-phase microextraction of pesticides for gas chromatography - Mass spectrometric analysis”, J. Chromatogr. A, 985, 107–116, (2003).
  • Basheer, C., Lee, H.K., Obbard, J.P., “Determination of organochlorine pesticides in seawater using liquid-phase hollow fibre membrane microextraction and gas chromatography–mass spectrometry”, J. Chromatogr. A, 968, 191-199, (2002).
  • Yanga, Y., Chena, J., , Shia, Y.P., “Determination of aconitine, hypaconitine and mesaconitine in urine using hollow fiber liquid-phase microextraction combined with high-performance liquid chromatography”, J. Chromatogr. B, 878, 2811–2816, (2010).
  • Ebrahimzadeh, H., Yamini, Y., Firozjaei, H.A., Kamarei, F., Tavassoli,N., Rouini, M.R., “Hollow fiber-based liquid phase microextraction combined with high-performance liquid chromatography for the analysis of gabapentin in biological samples”, Anal. Chim. Acta 665, 221–226, (2010).
  • Saraji, M., Jafari, M.T., Sherafatmand, H., “Hollow fiber-based liquid–liquid–liquid microextraction combined with electrospray ionization-ion mobility spectrometry for the determination of pentazocine in biological samples”, J. Chromatogr. A, 1217, 5173–5178, (2010).
  • Ugland, H.G., Krogh, M., Reubsaet, L., “Threephase liquid-phase microextraction of weakly basic drugs from whole blood”, J. Chromatogr. B, 798, 127–135, (2003).
  • Payẚn, M.R., Lὀpez, M.A.B.,Fernẚndez-Torres, R., Gonzẚlez, J.A.O., Mochὀn, M.C., “Hollow fiberbased liquid phase microextraction (HF-LPME) as a new approach for the HPLC determination of fluoroquinolones in biological and environmental matrices”, J. Pharmaceutical and Biomedical Analysis, 55, 332–341, (2011).
  • Payẚn, M.R., Lὀpez, M.A.B.,Fernẚndez-Torres, R., Navarro, M.V., Mochὀn, M.C., “Hollow fiberbased liquid phase microextraction (HF-LPME) for a highly sensitive HPLC determination of sulfonamides and their main metabolites”, J. Chromatogr. B, 879, 197–204, (2011).
  • Saleh, A., Larsson, E., Yamini, Y., Jonsson, J.A., “Hollow fiber liquid phase microextraction as a preconcentration and clean-up step after pressurized hot water extraction for the determination of non-steroidal anti-inflammatory drugs in sewage sludge”, J. Chromatogr. A, 1218, 1331–1339, (2011).
  • Payẚn, M.R., Lὀpez, M.A.B.,Fernẚndez-Torres, R., Mochὀn, M.C., Ariza, J.L.G., “ Application of hollow fiber-based liquid-phase microextraction (HF-LPME) for the determination of acidic pharmaceuticals in wastewaters”, Talanta, 82, 854–858, (2010).
  • Saraji, M., Mousavi, F., “Use of hollow fibre-based liquid–liquid–liquid microextraction and highperformance liquid chromatography–diode array detection for the determination of phenolic acids in fruit juices”, Food Chemistry 123, 1310–1317, (2010).
  • Barahona, F., Gjelstad, A., Pedersen-Bjergaard, S., Rasmussen, K.E., “Hollow fiber-liquid-phase microextraction of fungicides from orange juices”, J. Chromatogr. A, 1217, 1989–1994, (2010).
  • Abulhassani, J., Manzoori, J.L., Amjadi, M., “Hollow fiber based-liquid phase microextraction using ionic liquid solvent for preconcentration of lead and nickel from environmental and biological samples prior to determination by electrothermal atomic absorption spectrometry”, J.Hazardous Materials, 176, 481–486, (2010).
  • Xia, L., Wu, Y., Hu, B., “Hollow-fiber liquid-phase microextraction prior to low-temperature electrothermal vaporization ICP-MS for trace element analysis in environmental and biological samples”, J. Mass Spectrom., 42, 803–810, (2007).
  • Jiang, H., Hu, B., Chen, B., Xia, L., “Hollow fiber liquid phase microextraction combined with electrothermal atomic absorption spectrometry for the speciation of arsenic (III) and arsenic (V) in fresh waters and human hair extracts”, Anal. Chim. Acta, 634, 15-21, (2009).
  • Li, G., Zhang, L., Zhang , Z., “ Determination of polychlorinated biphenyls in water using dynamic hollow fiber liquid-phase microextraction and gas chromatography–mass spectrometry” J. Chromatogr. A 1204, 119–122, (2008).
  • Esrafili, A., Yamini, Y., Ghambarian, M., Moradi , M., “Dynamic three-phase hollow fiber microextraction based on two immiscible organic solvents with automated movement of the acceptor phase”, J. Sep. Sci., 34, 98–106, (2011).
  • Hou, L., Wen, X., Tu, C., Lee, H.K., “Combination of liquid-phase microextraction and on-column stacking for trace analysis of amino alcohols by capillary electrophoresis”, J. Chromatogr. A, 979, 163-169, (2002).
  • Hou, L., Lee, H.K., “Dynamic Three-Phase Microextraction as a Sample Preparation Technique Prior to Capillary Electrophoresis”, Anal. Chem., 75, 2784–2789, (2003). Hansson, H., Nilsson , U., “ Assessment of a dynamic hollow-fibre liquid phase microextraction system for human blood plasma samples”, Talanta, 77, 1309–1314, (2009).
  • Ghasemi, E., Sillanpää, M., Najafi, N.M., “Headspace hollow fiber protected liquid-phase microextraction combined with gas chromatography–mass spectroscopy for speciation and determination of volatile organic compounds of selenium in environmental and biological samples”, J. Chromatogr. A, 1218, 380–386, (2011).
  • Huang, S.P., Huang, S.D., “Determination of organochlorine pesticides in water using solvent cooling assisted dynamic hollow-fiber-supported headspace liquid-phase microextraction”, J. Chromatogr. A, 1176, 19–25, (2007).
  • King, S., Meyer, S.J., Andrews. A.R.J., “Screening method for polycyclic aromatic hydrocarbons in soil using hollow fiber membrane solvent microextraction”, J. Chromatogr. A, 982, 201–208, (2002).
  • Ratola, N., Alvesa, A., Kalogerakisb, N., Psillakis, E., “Hollow-fibre liquid-phase microextraction: A simple and fast cleanup step used for PAHs determination in pine needles”, Anal. Chim. Acta, 618, 70–78, (2008).
  • Zhu, L., Tu, C., Lee, H.K. “Liquid-Phase Microextraction of Phenolic Compounds Combined with On-Line Preconcentration by Field-Amplified Sample Injection at Low pH in Micellar Electrokinetic Chromatography”, Anal. Chem., 73, 5655–5660, (2001).
  • Zhu, L., Zhu, L., Lee, H.K., “Liquid–liquid–liquid microextraction of nitrophenols with a hollow fiber membrane prior to capillary liquid chromatography”, J. Chromatogr. A, 924, 407–417, (2001).
  • Zhu, L., Ee, K.H., Zhao, L., L ee, H.K., “Analysis of phenoxy herbicides in bovine milk by means of liquid–liquid–liquid microextraction with a hollowfiber membrane”, J. Chromatogr. A, 963, 335–343, (2002).
  • Pedersen-Bjergaard, S., Rasmussen, K.E., Brekke, A., Ho, T.S., Halvorsen, T.G., “Liquid-phase microextraction of basic drugs – Selection of extraction mode based on computer calculated solubility data”, J. Sep. Sci., 28, 1195-1203, (2005). Ho, T.S., Halvorsen, T.G., Pedersen-Bjergaard, S., Rasmussen, K.E., “Liquid-phase microextraction of hydrophilic drugs by carrier-mediated transport”, J. Chromatogr. A, 998, 61–72, (2003).
  • Yazdi, A.S., Es’haghi, Z., “Two-step hollow fiberbased, liquid-phase microextraction combined with high-performance liquid chromatography: A new approach to determination of aromatic amines in water”, J. Chromatogr. A, 1082, 136–142, (2005).
  • Basheer, C., Lee, H.K., “Analysis of endocrine disrupting alkylphenols, chlorophenols and bisphenol-A using hollow fiber-protected liquidphase microextraction coupled with injection portderivatization gas chromatography–mass spectrometry”, J. Chromatogr. A, 1057, 163–169, (2004).
  • Charalabaki, M., Psillakis, E., Mantzavinos, D., Kalogerakis, N., “Analysis of polycyclic aromatic hydrocarbons in wastewater treatment plant effluents using hollow fibre liquid-phase microextraction”, Chemosphere, 60, 690–698, (2005).
  • Shen, G., Lee, H.K., “Hollow fiber-protected liquidphase microextraction of triazine herbicides”, Anal. Chem., 74, 648–654, (2002).
  • Romero-Gonzẚlez, R., Pastor-Montoro, E., Martinez-Vidal, J.L., Garrido-Frenich, A., “Application of hollow fiber supported liquid membrane extraction to the simultaneous determination of pesticide residues in vegetables by liquid chromatography/mass spectrometry”, Rapid Commun. Mass Spectrom., 20, 2701-2708, (2006).
  • Jiang, H., Hu, B., Chen, B., Zu, W., “Hollow fiber liquid phase microextraction combined with graphite furnace atomic absorption spectrometry for the determination of methylmercury in human hair and sludge samples”, Spectrochimica Acta Part B, 63, 770–776, (2008).
  • Pedersen-Bjergaard, S., Rasmussen, K.E., “Liquidphase microextraction and capillary electrophoresis of acidic drugs”, Electrophoresis, 21, 579–585, (2000).
  • Psillakis, E., Kalogerakis, N., “Hollow-fibre liquidphase microextraction of phthalate esters from water”, J. Chromatogr. A, 999, 145–153, (2003).
  • Zanjani, M.R.K., Yamini, Y., Shariati, S., Jönsson, J.A., “A new liquid-phase microextraction method based on solidification of floating organic drop”, Anal. Chim. Acta, 585, 286–293, (2007).
  • Alver, E., Demirci, A., Özcimder., Mikroestraksiyon Yöntemleri, Sigma, 30, 75-90, (2012)

Oyuk (Hollow) Fiber Sıvı Faz Mikroekstraksiyon

Yıl 2013, Cilt: 17 Sayı: 1, 17 - 26, 01.04.2013

Erol Alver Ayla Demirci Mustafa Özcimder

Öz

Even though high precision analytical devices are developed in qualitative and quantitative determination of substance or substances in matrix samples (biological, environmental, food etc.), analytical devices mostly fail determining in matrix environment. Due to such reasons, clean-up process is needed to take (purification) and concentrate (enrichment) the substance in matrix environment. Liquid-liquid (LLE) extraction is commonly used in preparation of the samples. In recent years, liquid phase micro extraction (LPME) methods minimizing organic solvent used in liquid-liquid extraction are developed. Of these methods, hollow fiber liquid phase micro extraction (HFLPME) is widely used.

Anahtar Kelimeler

Oyuk (hollow) fiber sıvı faz mikroekstraksiyon HF–LPME Örnek hazırlama Organik kirleticiler

Kaynakça

  • Pestisit Su İkili Faz GC-MS 1 Pestisit Deniz suyu İkili Faz GC-MS Pestisit Sebze Üçlü Faz LC-MS 2 İnsektisit Su İkili Sistem GC-FTD 3 PAH Su İkili Faz GC-MS PAH Su Tepe Boşluklu GC-MS PAH Su, Toprak Üçlü Faz GC-FID 4 PAH Toprak İkili Faz GC-FID PAH Çam İğnesi İkili Faz GC-MS PAH Atık Su İkili faz GC-MS Fenoksi Herbisit İnek Sütü Üçlü Faz HPLC-UV 5 Triazin Herbisit Toprak İkili faz GC-MS Fungusit Portakal Suyu Üçlü Faz LC-MS Fenolik Asit Meyve Suyu Üçlü Faz HPLC-DAD 6 Nitrofenol Deniz Suyu Üçlü Faz LC-UV Fenol Su Üçlü Faz CE(MEKC) 7 Fenol Deniz suyu İkili faz GC-MS Aromatik amin Su Üçlü Faz CE Aromatik amin Su Üçlü Faz HPLC Florokinolon Su, Hayvan İdrarı Üçlü Faz HPLC-DAD/FD 8 Sülfonamit Su Üçlü Faz HPLC-DAD/FD İlaç İdrar, Plazma Üçlü Faz HPLC-UV İlaç İdrar, Plazma Üçlü Faz ESI-IMS 9 İlaç Kan Üçlü Faz LC-MS İlaç Arıtma Çamuru Üçlü Faz LC-MS İlaç Atık Su Üçlü Faz LC-MS-MS İlaç Su, Plazma Üçlü Faz CE İlaç İdrar, Plazma Üçlü Faz CE İlaç İdrar,Su Üçlü Faz CE-DAD/UV 10 Pb, Ni Su İkili Faz ETAAS 11 Cu, Zn, Pd, Cd, Hg, Pb, Bi Serum As(III), As(V) İçme Suyu, Saç İkili Faz ETAAS Uçuçu Selenyum Bileşikleri Su, toprak Metil-Hg Saç, Çamur İkili Faz GFAAS 13 1) GC-MS: Gaz Kromatograf- Kütle Spektrometresi 2) LC-MS: Sıvı Kromatograf- Kütle Spektrometresi 3) GC-FTD: Gaz Kromatograf-Termiyonik Detektör (Nitrojen-Fosfor Detektör, NPD) 4) GC-FID: Gaz Kromatograf-Alev İyonlaşma Detektörü 5) HPLC-UV: Yüksek Basınç Sıvı Kromatograf-UV Detektör 6) HPLC-DAD: Yüksek Basınç Sıvı Kromatograf-Diode Array Detektör 7) MEKC: Misel Elektrokinetik Kromatografi 8) HPLC-DAD/FD: Yüksek Basınç Sıvı Kromatograf-Diode Array/Floresan Detektör 9) ESI-IMS: Elektrosprey İyonizasyon-İyon Mobilite Spektrometresi 10) CE-DAD/Kapiler Elektroforez- Diode Array/UV Detektör 11) ETAAS: Elektrotermal Atomik Absorpsion Spektrometresi 12) ETV-ICP/MS: Elektrotermal Buharlaşma-İndüktif Optik Plazma Kütle Spektrometresi 13) GFAAS: Grafit Fırınlı Atomik Absorpsion Spektrometresi SONUÇ HF–LPME basit, hızlı, ucuz ve yüksek oranda seçici ve yüksek zenginleştirme faktörüne sahip bir yöntemdir. Oyuk fiber mikroekstraksiyon yöntemi çevresel, biyolojik, gıda örneklerinde ve asidik ve bazik ilaç analizlerinde zenginleştirmenin yanı sıra ön temizleme işlemini de aynı anda yaparak kullanılabilir. Fiber, alıcı fazın örnek çözelti ile doğrudan temasnı kestiğinden dolayı, şiddetli karıştırma hızlarında ekstraksiyon çözücüsü kaybını en az düzeylere indirir. Polipropilen fiber çok ucuz bir maliyete sahiptir. Bu nedenle, her analizde bir kez kullanılır. Fiberin her analizde bir kez kullanılması, önceki analizlerden kirlilik gelmesini engeller. Polipropilen hollow fiber küçük gözeneklere sahip olduğu için, matriks ortamdaki büyük molekül ağırlıklı kirliliklerin alıcı faza girmesini engelleyerek iyi bir ön temizleme işlemi yapar [2,13,22,29,67,71]. Yöntem, alıcı faz ile verici faz arasındaki membran bariyerin ekstraksiyon etkinliğini azaltması ve ekstraksiyon süresini uzatması, fiberin yüzeyinde hava kabarcıklarının oluşması ile ekstraksiyon etkinliği ve yinelenebilirliğin azaltması, gerçek örnek analizlerinde matriksin (kan, plazma, atık su) fiber üzerindeki gözenekleri tıkayabilmesi gibi dezavantajlara sahiptir [22,72,73]. KAYNAKLAR Krylov, V.A., Krylov, A.V, Mosyagin, P.V., Matkivskaya, Y.O., “Liquid–Phase Microextraction Preconcentration of Impurities”, Journal of Analytical Chemistry, 66, 331–350, (2011).
  • Psillakis, E., Kalogerakis, N., “Developments in liquid-phase microextraction”, Trends Anal. Chem., 22, 565–574, (2003).
  • Pena-Pereira, F., Lavilla, I., Bendicho, C., “Miniaturized preconcentration methods based on liquid-liquid extraction and their application in inorganic ultratrace analysis and speciation”, A review. Spectrochim. Acta, Part B 64, 1–15, (2009).
  • Mahugo-Santana, C., Sosa-Ferrera, Z., , TorresPadrón, M.E., Santana-Rodríguez, J.J., “Application of new approaches to liquid-phase microextraction for the determination of emerging pollutants”, Trends Anal. Chem, 30, 731–748, 20 C.F. Poole, “New trends in solid-phase extraction”, Trends Anal. Chem. 22, 362–373, (2003).
  • Arthur, C.L., Pawliszyn, J., “Solid phase microextraction with thermal desorption using fused silica optical fibers”, Anal. Chem., 62, 2145– 2148, (1990).
  • Malik, A. K., Kaur, V., Verma, N., “A review on solid phase microextraction—High performance liquid chromatography as a novel tool for the analysis of toxic metal ions”, Talanta, 68, 842–849, (2006).
  • Olariu, R-I., Vione, D., Grinberg, N., Arsene, C., “Sample preparation for trace analysis by chromatographic methods”, J. Liquid Chromatography & Related Technologies, 33, 1174–1207, (2010).
  • Dietz, C., Sanz, J., C´amara C., “Recent developments in solid-phase microextraction coatings and related techniques”, J. Chromatogr. A, 1103, 183–192, (2006).
  • Kumar, A., Gaurav, Malik, A.K., Tewary, D.K., Singh, . B., “A review on development of solid phase microextraction fibers by sol-gel methods and their applications” Anal. Chim. Acta, 610, 1–14 (2008).
  • Psillakis, E., Kalogerakis, N., “Solid-phase microextraction versus single-drop microextraction for the analysis of nitroaromatic explosives in water samples”, J. Chromatogr. A, 938, 113–120, (2001). H. Liu, P.K. Dasgupta, “Analytical Chemistry in a Drop. Solvent Extraction in a Microdrop”, Anal. Chem., 68, 1817-1826, (1996). Rasmussen, K.E., Pedersen-Bjergaard, S., “Developments in hollow fibre based, liquid-phase microextraction”, Trends Anal. Chem., 23, 1–10, (2004).
  • Jeannot, M.A., Cantwell, F.F., “Solvent microextraction into a single drop”, Anal. Chem., 68, 2236-2240, (1996).
  • He, Y., Lee, H.K., “Liquid phase microextraction in a single drop of organic solvent by using a conventional microsyringe”, Anal. Chem., 69, 4634–4640, (1997), L. Zhao, H.K. Lee, “Application of static liquidphase microextraction to the analysis of organochlorine pesticides in water”, J. Chromatogr. A, 919, 381–388, (2001).
  • Pedersen-Bjergaard, S., Rasmussen, K.E., “Liquidphase microextraction with porous hollow fibers, a miniaturized and highly flexible format for liquidliquid extraction”, J. Chromatogr. A, 1184, 132– 142, (2008).
  • Jeannot, M.A., Cantwell, F.F., “Mass transfer characteristics of solvent extraction into a single drop at the tip of a syringe needle”, Anal. Chem., 69, 235–239, (1997).
  • Theis, A.L., Waldack, A.J., Hansen, S.M., Jeannot, M.A., “Headspace solvent microextraction”, Anal. Chem. 73, 5651–5654, (2001).
  • Ma, M.H., Cantwell, F.F., “Solvent microextraction with simultaneous back-extraction for sample cleanup and preconcentration: Preconcentration into a single microdrop”, Anal. Chem., 71, 388– 393, (1999).
  • Liu, W.P., Lee, H.K., “Continuous-flow microextraction exceeding 1000-fold concentration of dilute analytes”, Anal. Chem., 72, 4462–4467, (2000).
  • Sarafraz-Yazdi, A., Amiri, A., “Liquid-phase microextraction”, Trends Anal. Chem., 29, 1–14, (2010).
  • Dadfarnia, S., Shabani, A.M.H., “Recent development in liquid phase microextraction for determination of trace level concentration of metals—A review”, Anal. Chim. Acta, 658, 107– 119, (2010).
  • K.E. Kramer, A.R.J. Andrews, “Screening method for 11-nor-Δ 9 -tetrahydrocannabinol-9-carboxylic acid in urine using hollow fiber membrane solvent microextraction with in-tube derivatization”, J. Chromatogr. B, 760, 27-36, (2001).
  • Pedersen-Bjergaard, S., Rasmussen, K.E., “Liquidliquid-liquid microextraction for sample preparation of biological fluids prior to capillary electrophoresis”, Anal. Chem. 71, 2650–2656, (1999).
  • De Jager, L.S., Andrews, A.R.J., “Preliminary studies of a fast screening method for cocaine and cocaine metabolites in urine using hollow fibre membrane solvent microextraction (HFMSME)”, Analyst, 126, 1298–1303, (2001).
  • Cuia, S., Tanb, S., Ouyang, G., Pawliszyn, J., “Automated polyvinylidene difluoride hollow fiber liquid-phase microextraction of flunitrazepam in plasma and urine samples for gas chromatography/tandem mass spectrometry”, J. Chromatogr. A, 1216, 2241–2247, (2009).
  • Li,Y., Xiong, Y., Fang, J., Wang, L., Liang, Q., “Application of hollow fiber liquid-phase microextraction in identification of oil spill sources”, J. Chromatogr. A, 1216, 6155–6161, (2009).
  • Pedersen-Bjergaard, S., Rasmussen, K.E., “Liquidphase microextraction with porous hollow fibers, a miniaturized and highly flexible format for liquid– liquid extraction”, J. Chromatogr. A, 1184, 132– 142, (2008).
  • Ho, T.S., Pedersen-Bjergaard, S., Rasmussen, K.E., “Recovery, enrichment and selectivity in liquidphase microextraction Comparison with conventional liquid-liquid extraction”, J. Chromatogr. A, 963, 3-17, (2002).
  • Pena-Pereira, F., Lavilla, I., Bendicho, C., “Liquidphase microextraction approaches combined with atomic detection”, Anal. Chim. Acta, 669, 1–16, (2010).
  • Lambropoulou, D.A., Albanis, T.A., “Application of hollow fiber liquid phase microextraction for the determination of insecticides in water”, J. Chromatogr. A, 1072, 55–61, (2005).
  • Zhao, L., Lee, H.K., “Liquid-Phase Microextraction Combined with Hollow Fiber as a Sample Preparation Technique Prior to Gas Chromatography/Mass Spectrometry”, Anal. Chem., 74, 2486-2492, (2002).
  • Jiang, X., Basheer, C., Zhang, J., Lee, H.K., “Dynamic hollow fiber-supported headspace liquid-phase microextraction”, J. Chromatogr. A, 1087, 289–294, (2005).
  • Hou, L., Shen, G., Lee, H.K., “Automated hollow fiber-protected dynamic liquid-phase microextraction of pesticides for gas chromatography - Mass spectrometric analysis”, J. Chromatogr. A, 985, 107–116, (2003).
  • Basheer, C., Lee, H.K., Obbard, J.P., “Determination of organochlorine pesticides in seawater using liquid-phase hollow fibre membrane microextraction and gas chromatography–mass spectrometry”, J. Chromatogr. A, 968, 191-199, (2002).
  • Yanga, Y., Chena, J., , Shia, Y.P., “Determination of aconitine, hypaconitine and mesaconitine in urine using hollow fiber liquid-phase microextraction combined with high-performance liquid chromatography”, J. Chromatogr. B, 878, 2811–2816, (2010).
  • Ebrahimzadeh, H., Yamini, Y., Firozjaei, H.A., Kamarei, F., Tavassoli,N., Rouini, M.R., “Hollow fiber-based liquid phase microextraction combined with high-performance liquid chromatography for the analysis of gabapentin in biological samples”, Anal. Chim. Acta 665, 221–226, (2010).
  • Saraji, M., Jafari, M.T., Sherafatmand, H., “Hollow fiber-based liquid–liquid–liquid microextraction combined with electrospray ionization-ion mobility spectrometry for the determination of pentazocine in biological samples”, J. Chromatogr. A, 1217, 5173–5178, (2010).
  • Ugland, H.G., Krogh, M., Reubsaet, L., “Threephase liquid-phase microextraction of weakly basic drugs from whole blood”, J. Chromatogr. B, 798, 127–135, (2003).
  • Payẚn, M.R., Lὀpez, M.A.B.,Fernẚndez-Torres, R., Gonzẚlez, J.A.O., Mochὀn, M.C., “Hollow fiberbased liquid phase microextraction (HF-LPME) as a new approach for the HPLC determination of fluoroquinolones in biological and environmental matrices”, J. Pharmaceutical and Biomedical Analysis, 55, 332–341, (2011).
  • Payẚn, M.R., Lὀpez, M.A.B.,Fernẚndez-Torres, R., Navarro, M.V., Mochὀn, M.C., “Hollow fiberbased liquid phase microextraction (HF-LPME) for a highly sensitive HPLC determination of sulfonamides and their main metabolites”, J. Chromatogr. B, 879, 197–204, (2011).
  • Saleh, A., Larsson, E., Yamini, Y., Jonsson, J.A., “Hollow fiber liquid phase microextraction as a preconcentration and clean-up step after pressurized hot water extraction for the determination of non-steroidal anti-inflammatory drugs in sewage sludge”, J. Chromatogr. A, 1218, 1331–1339, (2011).
  • Payẚn, M.R., Lὀpez, M.A.B.,Fernẚndez-Torres, R., Mochὀn, M.C., Ariza, J.L.G., “ Application of hollow fiber-based liquid-phase microextraction (HF-LPME) for the determination of acidic pharmaceuticals in wastewaters”, Talanta, 82, 854–858, (2010).
  • Saraji, M., Mousavi, F., “Use of hollow fibre-based liquid–liquid–liquid microextraction and highperformance liquid chromatography–diode array detection for the determination of phenolic acids in fruit juices”, Food Chemistry 123, 1310–1317, (2010).
  • Barahona, F., Gjelstad, A., Pedersen-Bjergaard, S., Rasmussen, K.E., “Hollow fiber-liquid-phase microextraction of fungicides from orange juices”, J. Chromatogr. A, 1217, 1989–1994, (2010).
  • Abulhassani, J., Manzoori, J.L., Amjadi, M., “Hollow fiber based-liquid phase microextraction using ionic liquid solvent for preconcentration of lead and nickel from environmental and biological samples prior to determination by electrothermal atomic absorption spectrometry”, J.Hazardous Materials, 176, 481–486, (2010).
  • Xia, L., Wu, Y., Hu, B., “Hollow-fiber liquid-phase microextraction prior to low-temperature electrothermal vaporization ICP-MS for trace element analysis in environmental and biological samples”, J. Mass Spectrom., 42, 803–810, (2007).
  • Jiang, H., Hu, B., Chen, B., Xia, L., “Hollow fiber liquid phase microextraction combined with electrothermal atomic absorption spectrometry for the speciation of arsenic (III) and arsenic (V) in fresh waters and human hair extracts”, Anal. Chim. Acta, 634, 15-21, (2009).
  • Li, G., Zhang, L., Zhang , Z., “ Determination of polychlorinated biphenyls in water using dynamic hollow fiber liquid-phase microextraction and gas chromatography–mass spectrometry” J. Chromatogr. A 1204, 119–122, (2008).
  • Esrafili, A., Yamini, Y., Ghambarian, M., Moradi , M., “Dynamic three-phase hollow fiber microextraction based on two immiscible organic solvents with automated movement of the acceptor phase”, J. Sep. Sci., 34, 98–106, (2011).
  • Hou, L., Wen, X., Tu, C., Lee, H.K., “Combination of liquid-phase microextraction and on-column stacking for trace analysis of amino alcohols by capillary electrophoresis”, J. Chromatogr. A, 979, 163-169, (2002).
  • Hou, L., Lee, H.K., “Dynamic Three-Phase Microextraction as a Sample Preparation Technique Prior to Capillary Electrophoresis”, Anal. Chem., 75, 2784–2789, (2003). Hansson, H., Nilsson , U., “ Assessment of a dynamic hollow-fibre liquid phase microextraction system for human blood plasma samples”, Talanta, 77, 1309–1314, (2009).
  • Ghasemi, E., Sillanpää, M., Najafi, N.M., “Headspace hollow fiber protected liquid-phase microextraction combined with gas chromatography–mass spectroscopy for speciation and determination of volatile organic compounds of selenium in environmental and biological samples”, J. Chromatogr. A, 1218, 380–386, (2011).
  • Huang, S.P., Huang, S.D., “Determination of organochlorine pesticides in water using solvent cooling assisted dynamic hollow-fiber-supported headspace liquid-phase microextraction”, J. Chromatogr. A, 1176, 19–25, (2007).
  • King, S., Meyer, S.J., Andrews. A.R.J., “Screening method for polycyclic aromatic hydrocarbons in soil using hollow fiber membrane solvent microextraction”, J. Chromatogr. A, 982, 201–208, (2002).
  • Ratola, N., Alvesa, A., Kalogerakisb, N., Psillakis, E., “Hollow-fibre liquid-phase microextraction: A simple and fast cleanup step used for PAHs determination in pine needles”, Anal. Chim. Acta, 618, 70–78, (2008).
  • Zhu, L., Tu, C., Lee, H.K. “Liquid-Phase Microextraction of Phenolic Compounds Combined with On-Line Preconcentration by Field-Amplified Sample Injection at Low pH in Micellar Electrokinetic Chromatography”, Anal. Chem., 73, 5655–5660, (2001).
  • Zhu, L., Zhu, L., Lee, H.K., “Liquid–liquid–liquid microextraction of nitrophenols with a hollow fiber membrane prior to capillary liquid chromatography”, J. Chromatogr. A, 924, 407–417, (2001).
  • Zhu, L., Ee, K.H., Zhao, L., L ee, H.K., “Analysis of phenoxy herbicides in bovine milk by means of liquid–liquid–liquid microextraction with a hollowfiber membrane”, J. Chromatogr. A, 963, 335–343, (2002).
  • Pedersen-Bjergaard, S., Rasmussen, K.E., Brekke, A., Ho, T.S., Halvorsen, T.G., “Liquid-phase microextraction of basic drugs – Selection of extraction mode based on computer calculated solubility data”, J. Sep. Sci., 28, 1195-1203, (2005). Ho, T.S., Halvorsen, T.G., Pedersen-Bjergaard, S., Rasmussen, K.E., “Liquid-phase microextraction of hydrophilic drugs by carrier-mediated transport”, J. Chromatogr. A, 998, 61–72, (2003).
  • Yazdi, A.S., Es’haghi, Z., “Two-step hollow fiberbased, liquid-phase microextraction combined with high-performance liquid chromatography: A new approach to determination of aromatic amines in water”, J. Chromatogr. A, 1082, 136–142, (2005).
  • Basheer, C., Lee, H.K., “Analysis of endocrine disrupting alkylphenols, chlorophenols and bisphenol-A using hollow fiber-protected liquidphase microextraction coupled with injection portderivatization gas chromatography–mass spectrometry”, J. Chromatogr. A, 1057, 163–169, (2004).
  • Charalabaki, M., Psillakis, E., Mantzavinos, D., Kalogerakis, N., “Analysis of polycyclic aromatic hydrocarbons in wastewater treatment plant effluents using hollow fibre liquid-phase microextraction”, Chemosphere, 60, 690–698, (2005).
  • Shen, G., Lee, H.K., “Hollow fiber-protected liquidphase microextraction of triazine herbicides”, Anal. Chem., 74, 648–654, (2002).
  • Romero-Gonzẚlez, R., Pastor-Montoro, E., Martinez-Vidal, J.L., Garrido-Frenich, A., “Application of hollow fiber supported liquid membrane extraction to the simultaneous determination of pesticide residues in vegetables by liquid chromatography/mass spectrometry”, Rapid Commun. Mass Spectrom., 20, 2701-2708, (2006).
  • Jiang, H., Hu, B., Chen, B., Zu, W., “Hollow fiber liquid phase microextraction combined with graphite furnace atomic absorption spectrometry for the determination of methylmercury in human hair and sludge samples”, Spectrochimica Acta Part B, 63, 770–776, (2008).
  • Pedersen-Bjergaard, S., Rasmussen, K.E., “Liquidphase microextraction and capillary electrophoresis of acidic drugs”, Electrophoresis, 21, 579–585, (2000).
  • Psillakis, E., Kalogerakis, N., “Hollow-fibre liquidphase microextraction of phthalate esters from water”, J. Chromatogr. A, 999, 145–153, (2003).
  • Zanjani, M.R.K., Yamini, Y., Shariati, S., Jönsson, J.A., “A new liquid-phase microextraction method based on solidification of floating organic drop”, Anal. Chim. Acta, 585, 286–293, (2007).
  • Alver, E., Demirci, A., Özcimder., Mikroestraksiyon Yöntemleri, Sigma, 30, 75-90, (2012)
Toplam 67 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Konular Mühendislik
Bölüm Araştırma Makalesi
Yazarlar

Erol Alver Bu kişi benim

Ayla Demirci Bu kişi benim

Mustafa Özcimder Bu kişi benim

Yayımlanma Tarihi 1 Nisan 2013
Gönderilme Tarihi 16 Mayıs 2012
Kabul Tarihi 23 Aralık 2012
Yayımlandığı Sayı Yıl 2013 Cilt: 17 Sayı: 1

Kaynak Göster

APA Alver, E., Demirci, A., & Özcimder, M. (2013). Oyuk (Hollow) Fiber Sıvı Faz Mikroekstraksiyon. Sakarya University Journal of Science, 17(1), 17-26. https://doi.org/10.16984/saufbed.30590
AMA Alver E, Demirci A, Özcimder M. Oyuk (Hollow) Fiber Sıvı Faz Mikroekstraksiyon. SAUJS. Nisan 2013;17(1):17-26. doi:10.16984/saufbed.30590
Chicago Alver, Erol, Ayla Demirci, ve Mustafa Özcimder. “Oyuk (Hollow) Fiber Sıvı Faz Mikroekstraksiyon”. Sakarya University Journal of Science 17, sy. 1 (Nisan 2013): 17-26. https://doi.org/10.16984/saufbed.30590.
EndNote Alver E, Demirci A, Özcimder M (01 Nisan 2013) Oyuk (Hollow) Fiber Sıvı Faz Mikroekstraksiyon. Sakarya University Journal of Science 17 1 17–26.
IEEE E. Alver, A. Demirci, ve M. Özcimder, “Oyuk (Hollow) Fiber Sıvı Faz Mikroekstraksiyon”, SAUJS, c. 17, sy. 1, ss. 17–26, 2013, doi: 10.16984/saufbed.30590.
ISNAD Alver, Erol vd. “Oyuk (Hollow) Fiber Sıvı Faz Mikroekstraksiyon”. Sakarya University Journal of Science 17/1 (Nisan 2013), 17-26. https://doi.org/10.16984/saufbed.30590.
JAMA Alver E, Demirci A, Özcimder M. Oyuk (Hollow) Fiber Sıvı Faz Mikroekstraksiyon. SAUJS. 2013;17:17–26.
MLA Alver, Erol vd. “Oyuk (Hollow) Fiber Sıvı Faz Mikroekstraksiyon”. Sakarya University Journal of Science, c. 17, sy. 1, 2013, ss. 17-26, doi:10.16984/saufbed.30590.
Vancouver Alver E, Demirci A, Özcimder M. Oyuk (Hollow) Fiber Sıvı Faz Mikroekstraksiyon. SAUJS. 2013;17(1):17-26.
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