Araştırma Makalesi
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The fine structure levels for ground states of negative ions of nitrogen and phosphorus

Yıl 2013, Cilt: 17 Sayı: 1, 139 - 146, 01.04.2013

Öz

The fine structure levels for negative ions (anions) of nitrogen and phosphorus have been investigated using multiconfiguration Hartree-Fock method within the framework of Breit-Pauli Hamiltonian (MCHF+BP). Nitrogen and phosphorus have half-filled outer shell in ground state 1s2s 2p S and 1s2s 2p 3s 3p S, respectively. It has been stated in most works that the negative ion of nitrogen is instable whereas the negative ion of phosphorus is stable. The results obtained have been compared with other works.

Kaynakça

  • ANDERSSON, P., LINDAHL, A.O., ALFREDSSON, C., ROGSTRÖM, L., DIEHL, C., PEGG, D.J., HANSTORP, D., The electron affinity of phosphorus, J. Phys. B: At. Mol. Opt. Phys., 40. 4097– 4107, 2007
  • NIST(http://physics.nist.gov/PhysRefData/ASD/inde x.html) HOTOP, H., LINEBERGER, W.C., Binding energies in atomic negative ions, J. Phys. Chem. Ref. Data, 4, 539–576, 1975
  • DAVIDSON, E.R., HAGSTROM, S.A., CHAKRAVORTY, S.J., UMAR, V.M., FISCHER, C.F., Ground-state correlation energies for two- to tenelectron atomic ions, Phys. Rev. A, 44, 7071–7083, 1991
  • WIJUSUNDERA, W.P., LITHERLAND, A.E., A theoretical study of some negative ions of interest to accelerator mass spectrometry, Nuclear Instruments and Methods in Physics Research B, 123, 527-531,1997
  • KOGA, T., AOKI, H., DE LA VEGA, G., J.M., TATEWAKI, H., Atomic ionization potentials and electron affinities with relativistic and mass corrections, Theor. Chem. Acc., 96, 248-255, 1997
  • COWAN, R.D., FISCHER, C.F., HANSEN, J.E., KEMPTER V., Excited states of the negative nitrogen ion: energies and lifetimes, J. Phys. B: At. Mol. Opt. Phys. 30, 1457–1466, 1997
  • GUTSEV, G.L., JENA, P., BARLETT, R.J., Electric quadrupole moments and electron affinities of atoms from H to Cl: a coupled-cluster study, Chemical Physics Letters, 291, 547–552, 1998
  • CHEN, G., ONG, P.P., TING,L., DFT approach for electron affinity of negative atomic ions, Chemical Physics Letters, 290, 211–215,1998
  • WIJESUNDERA, W. P., PARPIA, F. A., Negative ions of carbon, nitrogen, and phosphorus, Phys. Rev. A, 57, 3462–3468, 1998
  • PIANGOS, N.A., NICOLAIDESY, C.A., Very highly excited bound states of atomic negative ions having all their electrons with unpaired spins, J. Phys. B: At. Mol. Opt. Phys., 31, L147–L154, 1998
  • BIÉMONT, E. , FRÉMAT, Y. , QUINET, P. , Ionization potentials of atoms and ions from lithium to tin (Z=50), Atomic Data and Nuclear Data Tables, 71, 117–146 ,1999
  • ANDERSEN, T., HAUGEN, H.K., HOTOP, H., Binding Energies in Atomic Negative Ions: III, J. Phys. Chem. Ref. Data, 28, 1511-1533, 1999 KLOPPER, W. , BACHORZ, R.A., Sub-meV accuracy in first-principles computations of the ionization potentials and electron affinities of the atoms H to Ne, Physical Review A, 81, 022503, 2010
  • WOON, D.E., DUNNING,JR, T.H., Calculation of the Electron Affinities of the Second Row Atoms: Al– Cl, J. Chem. Phys. 99, 3730–3737, 1993
  • WANG, J., SMITH, JR,V.H., 1/Z Expansions for isoelectronic systems from He through Ar, Phys. Rev. A, 52, 1060–1066, 1995
  • PELÁEZ, R.J., BLONDEL, C., VANDEVRAYE, M., DRAG, C., DELSART, C., Photodetachment microscopy to an excited spectral term and the electron affinity of phosphorus, J. Phys. B: At. Mol. Opt. Phys., 44, 195009, 2011
  • FISCHER, C.F., BRAGE, T., JÖNSSON, P., Computational atomic structure-an MCHF approach, (Bristol and Philadelphia), 1997
  • FISCHER, C.F., The atomic structure package, Comp.Phy. Commun., 128,635-636, 2000
  • PEKERIS C.L., Ground state of two-electron atoms, Phys. Rev., 112, 1649-1658, 1958
  • EDLEN, B., Isoelectronic extrapolation of electron affinities, J. Chem. Phys. 33, 98-105, 1960 FELDMAN, D., Infrared photodetachment thereshold measurements: Li and P , Z. Phys. A: Hadrons and Nuclei, 277, 19-25, 1976
  • SLATER , J., LINEBERGER, W.C., Highresolution photodetachment studies of P and Te , Phys. Rev. A, 15, 22772282, 1977
  • OLIVERIA, DE G., MARTIN, J.M.L., PRAFT, D.E. F., GEERLINGS, P., Electron affinities of the first and second-row atoms: benchmark ab initio and density-functional calculations, Phys., Rev. A, 60, 1034-1045, 1999
  • LINDGREN, L., MORRISON, J., Atomic Manybody Theory. (Springer-Verlag, Berlin), 1982

Azot ve fosforun negatif iyonlarının temel hallerinin ince yapı seviyeleri

Yıl 2013, Cilt: 17 Sayı: 1, 139 - 146, 01.04.2013

Öz

The fine structure levels for negative ions (anions) of nitrogen and phosphorus have been investigated using multiconfiguration Hartree-Fock method within the framework of Breit-Pauli Hamiltonian (MCHF+BP). Nitrogen and phosphorus have half-filled outer shell in ground state 1s22s22p3 4S and 1s22s22p33s23p3 4S, respectively. It has been stated in most works that the negative ion of nitrogen is instable whereas the negative ion of phosphorus is stable. The results obtained have been compared with other works.

Kaynakça

  • ANDERSSON, P., LINDAHL, A.O., ALFREDSSON, C., ROGSTRÖM, L., DIEHL, C., PEGG, D.J., HANSTORP, D., The electron affinity of phosphorus, J. Phys. B: At. Mol. Opt. Phys., 40. 4097– 4107, 2007
  • NIST(http://physics.nist.gov/PhysRefData/ASD/inde x.html) HOTOP, H., LINEBERGER, W.C., Binding energies in atomic negative ions, J. Phys. Chem. Ref. Data, 4, 539–576, 1975
  • DAVIDSON, E.R., HAGSTROM, S.A., CHAKRAVORTY, S.J., UMAR, V.M., FISCHER, C.F., Ground-state correlation energies for two- to tenelectron atomic ions, Phys. Rev. A, 44, 7071–7083, 1991
  • WIJUSUNDERA, W.P., LITHERLAND, A.E., A theoretical study of some negative ions of interest to accelerator mass spectrometry, Nuclear Instruments and Methods in Physics Research B, 123, 527-531,1997
  • KOGA, T., AOKI, H., DE LA VEGA, G., J.M., TATEWAKI, H., Atomic ionization potentials and electron affinities with relativistic and mass corrections, Theor. Chem. Acc., 96, 248-255, 1997
  • COWAN, R.D., FISCHER, C.F., HANSEN, J.E., KEMPTER V., Excited states of the negative nitrogen ion: energies and lifetimes, J. Phys. B: At. Mol. Opt. Phys. 30, 1457–1466, 1997
  • GUTSEV, G.L., JENA, P., BARLETT, R.J., Electric quadrupole moments and electron affinities of atoms from H to Cl: a coupled-cluster study, Chemical Physics Letters, 291, 547–552, 1998
  • CHEN, G., ONG, P.P., TING,L., DFT approach for electron affinity of negative atomic ions, Chemical Physics Letters, 290, 211–215,1998
  • WIJESUNDERA, W. P., PARPIA, F. A., Negative ions of carbon, nitrogen, and phosphorus, Phys. Rev. A, 57, 3462–3468, 1998
  • PIANGOS, N.A., NICOLAIDESY, C.A., Very highly excited bound states of atomic negative ions having all their electrons with unpaired spins, J. Phys. B: At. Mol. Opt. Phys., 31, L147–L154, 1998
  • BIÉMONT, E. , FRÉMAT, Y. , QUINET, P. , Ionization potentials of atoms and ions from lithium to tin (Z=50), Atomic Data and Nuclear Data Tables, 71, 117–146 ,1999
  • ANDERSEN, T., HAUGEN, H.K., HOTOP, H., Binding Energies in Atomic Negative Ions: III, J. Phys. Chem. Ref. Data, 28, 1511-1533, 1999 KLOPPER, W. , BACHORZ, R.A., Sub-meV accuracy in first-principles computations of the ionization potentials and electron affinities of the atoms H to Ne, Physical Review A, 81, 022503, 2010
  • WOON, D.E., DUNNING,JR, T.H., Calculation of the Electron Affinities of the Second Row Atoms: Al– Cl, J. Chem. Phys. 99, 3730–3737, 1993
  • WANG, J., SMITH, JR,V.H., 1/Z Expansions for isoelectronic systems from He through Ar, Phys. Rev. A, 52, 1060–1066, 1995
  • PELÁEZ, R.J., BLONDEL, C., VANDEVRAYE, M., DRAG, C., DELSART, C., Photodetachment microscopy to an excited spectral term and the electron affinity of phosphorus, J. Phys. B: At. Mol. Opt. Phys., 44, 195009, 2011
  • FISCHER, C.F., BRAGE, T., JÖNSSON, P., Computational atomic structure-an MCHF approach, (Bristol and Philadelphia), 1997
  • FISCHER, C.F., The atomic structure package, Comp.Phy. Commun., 128,635-636, 2000
  • PEKERIS C.L., Ground state of two-electron atoms, Phys. Rev., 112, 1649-1658, 1958
  • EDLEN, B., Isoelectronic extrapolation of electron affinities, J. Chem. Phys. 33, 98-105, 1960 FELDMAN, D., Infrared photodetachment thereshold measurements: Li and P , Z. Phys. A: Hadrons and Nuclei, 277, 19-25, 1976
  • SLATER , J., LINEBERGER, W.C., Highresolution photodetachment studies of P and Te , Phys. Rev. A, 15, 22772282, 1977
  • OLIVERIA, DE G., MARTIN, J.M.L., PRAFT, D.E. F., GEERLINGS, P., Electron affinities of the first and second-row atoms: benchmark ab initio and density-functional calculations, Phys., Rev. A, 60, 1034-1045, 1999
  • LINDGREN, L., MORRISON, J., Atomic Manybody Theory. (Springer-Verlag, Berlin), 1982
Toplam 22 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Konular Mühendislik
Bölüm Araştırma Makalesi
Yazarlar

Leyla Özdemir Bu kişi benim

Nurgül Atik Bu kişi benim

Gülay Günday Konan Bu kişi benim

Yayımlanma Tarihi 1 Nisan 2013
Gönderilme Tarihi 10 Mayıs 2012
Kabul Tarihi 13 Aralık 2012
Yayımlandığı Sayı Yıl 2013 Cilt: 17 Sayı: 1

Kaynak Göster

APA Özdemir, L., Atik, N., & Konan, G. G. (2013). Azot ve fosforun negatif iyonlarının temel hallerinin ince yapı seviyeleri. Sakarya University Journal of Science, 17(1), 139-146. https://doi.org/10.16984/saufbed.81654
AMA Özdemir L, Atik N, Konan GG. Azot ve fosforun negatif iyonlarının temel hallerinin ince yapı seviyeleri. SAUJS. Nisan 2013;17(1):139-146. doi:10.16984/saufbed.81654
Chicago Özdemir, Leyla, Nurgül Atik, ve Gülay Günday Konan. “Azot Ve Fosforun Negatif iyonlarının Temel Hallerinin Ince Yapı Seviyeleri”. Sakarya University Journal of Science 17, sy. 1 (Nisan 2013): 139-46. https://doi.org/10.16984/saufbed.81654.
EndNote Özdemir L, Atik N, Konan GG (01 Nisan 2013) Azot ve fosforun negatif iyonlarının temel hallerinin ince yapı seviyeleri. Sakarya University Journal of Science 17 1 139–146.
IEEE L. Özdemir, N. Atik, ve G. G. Konan, “Azot ve fosforun negatif iyonlarının temel hallerinin ince yapı seviyeleri”, SAUJS, c. 17, sy. 1, ss. 139–146, 2013, doi: 10.16984/saufbed.81654.
ISNAD Özdemir, Leyla vd. “Azot Ve Fosforun Negatif iyonlarının Temel Hallerinin Ince Yapı Seviyeleri”. Sakarya University Journal of Science 17/1 (Nisan 2013), 139-146. https://doi.org/10.16984/saufbed.81654.
JAMA Özdemir L, Atik N, Konan GG. Azot ve fosforun negatif iyonlarının temel hallerinin ince yapı seviyeleri. SAUJS. 2013;17:139–146.
MLA Özdemir, Leyla vd. “Azot Ve Fosforun Negatif iyonlarının Temel Hallerinin Ince Yapı Seviyeleri”. Sakarya University Journal of Science, c. 17, sy. 1, 2013, ss. 139-46, doi:10.16984/saufbed.81654.
Vancouver Özdemir L, Atik N, Konan GG. Azot ve fosforun negatif iyonlarının temel hallerinin ince yapı seviyeleri. SAUJS. 2013;17(1):139-46.

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