Pd/BP2000 Nanocomposites: Efficient Catalyst for Hydrolytic Dehydrogenation of Ammonia-borane

Yıl 2022, Cilt: 26 Sayı: 1, 195 - 202, 28.02.2022

Melike Sevim

https://doi.org/10.16984/saufenbilder.1029399

Öz

In current work, the activity of BP2000 supported Pd nanoparticles (NPs) were researched based on hydrolysis of ammonia borane (AB) reaction. Borane-tert-butylamine used for reduction of palladium (II) acetylacetonate for synthesize procedure of Pd NPs under mild conditions. As prepared Pd NPs were assembled on the BP2000, by liquid-phase self-assembly method. X-ray diffraction (XRD), transmission electron microscopy (TEM) and inductively coupled plasma-mass spectroscopy (ICP-MS) -advanced analytical techniques- were performed for detailed characterization. BP2000-supported Pd NPs were exhibited excellent activity and stability for the hydrolysis of AB. Pd/BP2000 nanocatalyst were showed the enhance catalytic activity that calculated turnover frequency (TOF) of 20.4 min−1. The detailed report clarified the kinetics of Pd/BP2000 nanocatalyst parameters on catalyst amount, AB concentration, temperature and reusability. After the hydrolysis of AB with Pd/BP2000 nanocatalyst, activation energy of reaction was calculated to be 41.5 kJ mol−1.

Anahtar Kelimeler

palladium, BP2000, nanoparticles, ammonia-borane., hydrogen

Kaynakça

• [1] M. Grasemann and G. Laurenczy, “Formic acid as a hydrogen source–recent developments and future trends,’’ Energy & Environmental Science, vol. 5, no. 8, pp. 8171-8181, 2012.
• [2] Y. Chen, J. L. Fulton, J. C. Linehan, and T. Autrey, “In situ XAFS and NMR study of rhodium-catalyzed dehydrogenation of dimethylamine borane,’’ Journal of the American Chemical Society, vol.127, no.10 pp. 3254-3255, 2005.
• [3] Z. Wen, Q. Fu, J. Wu, G. Fan, “Ultrafine Pd Nanoparticles Supported on Soft Nitriding Porous Carbon for Hydrogen Production from Hydrolytic Dehydrogenation of Dimethyl Amine-Borane,’’ Nanomaterials, vol.10, no.8 pp.1612, 2020.
• [4] S. Karaboga, S. Özkar, “Ceria supported ruthenium nanoparticles: Remarkable catalyst for H2 evolution from dimethylamine borane,’’ International Journal of Hydrogen Energy, vol.44, no.48 pp.26296-26307, 2020.
• [5] L. L. Al-mahamad, “Gold nanoparticles as a catalyst for dehydrogenation reaction of dimethylamine borane at room temperature, ’’International Journal of Hydrogen Energy, vol.45, no.21, pp.11916-11922, 2020.
• [6] N. Cao, J. Su, W. Luo, and G. Cheng, “Hydrolytic dehydrogenation of ammonia borane and methylamine borane catalyzed by graphene supported Ru@ Ni core–shell nanoparticles,’’ International journal of hydrogen energy, vol. 39, no.1, pp. 426-435, 2014.
• [7] M. C. Denney, V. Pons, T. J. Hebden, D. M. Heinekey, and K. I. Goldberg, “Efficient catalysis of ammonia borane dehydrogenation,’’ Journal of the American Chemical Society, vol. 128, no. 37, pp. 12048-12049, 2006.
• [8] A. Al-Kukhun, H. T. Hwang, and A. Varma, “Mechanistic studies of ammonia borane dehydrogenation,’’ International journal of hydrogen energy, vol. 38, no. 1, pp. 169-179, 2013.
• [9] O. Metin, V. Mazumder, S. Ozkar, and S. Sun, “Monodisperse nickel nanoparticles and their catalysis in hydrolytic dehydrogenation of ammonia borane, ’’Journal of the American Chemical Society, vol. 132, no. 5, pp. 1468-1469, 2010.
• [10] W. W. Zhan, Q. L. Zhu, and Q. Xu, “Dehydrogenation of ammonia borane by metal nanoparticle catalysts,’’ Acs Catalysis, vol. 6, no. 10, pp. 6892-6905, 2016.
• [11] M. Chandra, and Q. Xu, “A high- performance hydrogen generation system: Transition metal-catalyzed dissociation and hydrolysis of ammonia–borane,’’ Journal of Power Sources, vol. 156, no. 2, pp. 190-194, 2006.
• [12] M. Chandra, and Q. Xu, “Room temperature hydrogen generation from aqueous ammonia-borane using noble metal nano-clusters as highly active catalysts,’’ Journal of Power Sources, vol. 168, no. 1, pp.135-142, 2007.
• [13] Y. T. Li, X. L. Zhang, Z. K. Peng, P. Liu, and X. C. Zheng, “Highly efficient hydrolysis of ammonia borane using ultrafine bimetallic RuPd nanoalloys encapsulated in porous g-C3N4, ’’ Fuel, vol. 277, no.1 pp. 118243, 2020.
• [14] C. Du, Q. Ao, N. Cao, L. Yang, W. Luo, and G. Cheng, “Facile synthesis of monodisperse ruthenium nanoparticles supported on graphene for hydrogen generation from hydrolysis of ammonia borane,’’ International Journal of Hydrogen Energy, vol. 40, no. 18, pp. 6180-6187, 2015.
• [15] S. Akbayrak, Y. Tonbul, and S. Özkar, “Ceria supported rhodium nanoparticles: superb catalytic activity in hydrogen generation from the hydrolysis of ammonia borane,’’Applied Catalysis B: Environmental, vol. 198, pp. 162-170, 2016.
• [16] F. Zhong, Q. Wang, C. Xu, Y. Wang, B. Xu, Y. Zhang, and G. Fan, “Catalytically active rhodium nanoparticles stabilized by nitrogen doped carbon for the hydrolysis of ammonia borane,’’ International Journal of Hydrogen Energy, vol. 43, no. 49, pp. 22273-22280, 2018.
• [17] M. Yuan, Z. Cui, J. Yang, X. Cui, M. Tian, D. Xu, Z. Dong, “Ultrafine platinum nanoparticles modified on cotton derived carbon fibers as a highly efficient catalyst for hydrogen evolution from ammonia borane,’’ International Journal of Hydrogen Energy, vol. 42, no.49, pp.29244-29253, 2017.
• [18] S. Akbayrak, and S. Özkar, “Cobalt ferrite supported platinum nanoparticles: Superb catalytic activity and outstanding reusability in hydrogen generation from the hydrolysis of ammonia borane,’’ Journal of Colloid and Interface Science, vol. 596, pp.100-107, 2021.
• [19] M. Rakap, “PVP-stabilized Ru–Rh nanoparticles as highly efficient catalysts for hydrogen generation from hydrolysis of ammonia borane,’’ Journal of Alloys and Compounds, vol. 649, pp. 1025-1030, 2015.
• [20] N. Tunç, B. Abay, and Rakap, M. “Hydrogen generation from hydrolytic dehydrogenation of hydrazine borane by poly (N-vinyl-2-pyrrolidone)-stabilized palladium nanoparticles,’’ Journal of Power Sources, vol. 299, pp. 403-407, 2015.
• [21] X. Chen, X. J. Xu, X. C. Zheng, X. X. Guan, and P. Liu, “Chitosan supported palladium nanoparticles: The novel catalysts for hydrogen generation from hydrolysis of ammonia borane,’’ Materials Research Bulletin, vol.103, pp. 89-95, 2018.
• [22] J. R. Deka, D. Saikia, P. H. Chen, K. T. Chen H. M. Kao, and Y. C. Yang, “Palladium nanoparticles encapsulated in carboxylic acid functionalized periodic mesoporous organosilicas as efficient and reusable heterogeneous catalysts for hydrogen generation from ammonia borane,’’ Materials Research Bulletin, vol. 125, pp. 110786, 2020.
• [23] A. Balanta, C. Godard, C. Claver, “Pd nanoparticles for C–C coupling reactions,’’ Chemical Society Reviews, vol. 40, no.10, pp.4973-4985, 2011.
• [24] M. T. Reetz, E. Westermann, “Phosphane‐free palladium‐catalyzed coupling reactions: the decisive role of Pd nanoparticles,’’ Angewandte Chemie International Edition, vol.39, no.1, pp.165-168, 2000.
• [25] Z. Zhang, Z. Wang, “Diatomite-supported Pd nanoparticles: an efficient catalyst for Heck and Suzuki reactions,’’ The Journal of organic chemistry, vol. 71, no.19, pp.7485-7487, 2006.
• [26] W. Sun, X. Lu, Y. Tong, Z. Zhang, J. Lei, G. Nie, and C. Wang, “Fabrication of highly dispersed palladium/graphene oxide nanocomposites and their catalytic properties for efficient hydrogenation of p-nitrophenol and hydrogen generation,’’ International journal of hydrogen energy, vol. 39, no. 17, pp. 9080-9086, 2014.
• [27] X. K. Tian, C. Yang, Z. X. Zhou, X. W. Liu, and Y. Li, “Active 3D Pd/graphene aerogel catalyst for hydrogen generation from the hydrolysis of ammonia-borane,’’ International Journal of Hydrogen Energy, vol. 41, no. 34, pp. 15225-15235, 2016.
• [28] H. Jia, Y. Zhu, X. Song, X. Zheng, and P. Liu, “Magnetic graphene oxide-ionic liquid grafted chitosan composites anchored Pd (0) nanoparticles: A robust heterogeneous catalyst with enhanced activity and superior reusability for hydrogen generation from ammonia borane,’’ International Journal of Hydrogen Energy, vol. 43, no. 43, pp. 19939-19946, 2018.
• [29] V. Mazumder, and S. Sun, “Oleylamine-mediated synthesis of Pd nanoparticles for catalytic formic acid oxidation,’’ Journal of the American Chemical Society, vol. 131, no. 13, pp. 4588-4589, 2009.
• [30] M. Celebi, K. Karakas, I. E. Ertas, M. Kaya, and M. Zahmakiran, “Palladium nanoparticles decorated graphene oxide: active and reusable nanocatalyst for the catalytic reduction of hexavalent chromium (VI),’’ ChemistrySelect, vol. 2, no. 27, pp. 8312-8319, 2017.