Araştırma Makalesi
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Role of Mechanical Activation in Enhancing Li and Co Recovery from Spent Li-ion Batteries through Citric Acid Leaching

Yıl 2024, Cilt: 28 Sayı: 5, 1000 - 1009
https://doi.org/10.16984/saufenbilder.1506764

Öz

This study investigates the effect of mechanical activation parameters such as mechanical activation rotation speed (0-550 rpm), mechanical activation time (15-75 min), and solid/ball ratio (1/20-1/50) on the leaching efficiencies in the recycling of lithium-ion batteries. In addition to mechanical activation, the study explores the use of organic acids, specifically citric acid, as leaching agents to enhance metal recovery. A green and innovative recycling process is developed, focusing on optimal conditions of 15 minutes activation time, 450 rpm rotational speed, and a 1/20 solid/ball ratio. The synergistic effect of mechanical activation and organic acid leaching is examined to optimize the process for sustainability and efficiency in recovering valuable metals from lithium-ion batteries. Results indicate that these parameters significantly influence leaching efficiencies, with the highest yields achieved under the identified conditions. This research contributes to advancing sustainable practices in battery recycling by integrating mechanical activation and organic acid leaching as effective and environmentally friendly approaches. The findings highlight the potential of these methods in advancing green technology and materials science, paving the way for more efficient and eco-friendly battery recycling processes.

Destekleyen Kurum

Sakarya University Science Research Projects Coordinators

Proje Numarası

SAU BAP 2022-6-23-63

Teşekkür

We would like to thank Exitcom A.Ş. for providing us with the waste batteries used in this study.

Kaynakça

  • D. J. Garole, R. Hossain, V. J. Garole, V. Sahajwalla, J. Nerkar, D. P. Dubal, “Recycle, Recover and Repurpose Strategy of Spent Li-ion Batteries and Catalysts: Current Status and Future Opportunities,” ChemSusChem, vol. 13, pp. 3079-3100, 2020.
  • G. Harper, R. Sommerville, E. Kendrick, L. Driscoll, P. Slater, R. Stolkin, A. Walton, P. Christensen, O. Heidrich, S. Lambert, A. Abbott, K. Ryder, L. Gaines, P. Anderson, “Recycling lithium-ion batteries from electric vehicles,” Nature, vol. 575, pp. 75-86, 2019.
  • Y. Miao, L. Liu, Y. Zhang, Q. Tan, J. Li, “An overview of global power lithium-ion batteries and associated critical metal recycling,” Journal of Hazardous Materials, vol. 425, pp. 1279001-14, 2022.
  • M. Jiao, Y. Wang, C. Ye, C. Wang, W. Zhang, C. Liang, "High-capacity SiOx (0≤x≤2) as promising anode materials for next-generation lithium-ion batteries," Journal of Alloys and Compounds, vol. 482, pp.155774 1-21, 2020.
  • X. Zhang, S. Han, P. Xiao, C. Fan, W. Zhang, “Thermal reduction of graphene oxide mixed with hard carbon and their high performance as lithium ion battery anode,” Carbon, vol. 100, pp. 600-607, 2016.
  • S. L. Chou, Y. Pan, J. Z. Wang, H. K. Liu, S. X. Dou, “Small things make a big difference: Binder effects on the performance of Li and Na batteries,” Physical Chemistry Chemical Physics, vol. 16, pp. 20347-20359, 2014.
  • E. Asadi Dalini, G. Karimi, S. Zandevakili, M. Goodarzi, “A Review on Environmental, Economic and Hydrometallurgical Processes of Recycling Spent Lithium-ion Batteries,” Mineral Processing and Extractive Metallurgy Review, vol. 42, no. 7, pp. 451-472, 2020.
  • Y. Yang, G. Huang, S. Xu, Y. He, X. Liu, “Thermal treatment process for the recovery of valuable metals from spent lithium-ion batteries,” Hydrometallurgy, vol. 165, pp. 390-396, 2016.
  • R. Golmohammadzadeh, F. Rashchi, E. Vahidi, “Recovery of lithium and cobalt from spent lithium-ion batteries using organic acids: Process optimization and kinetic aspects,” Waste Management, vol. 64, pp. 244-254, 2017.
  • G. Mishra, R. Jha, A. Meshram, K. K. Singh, "A review on recycling of lithium-ion batteries to recover critical metals," Journal of Environmental Chemical Engineering, vol. 10 (6), pp. 108534 1-15, 2022.
  • M. Joulié, E. Billy, R. Laucournet, D. Meyer, “Current collectors as reducing agent to dissolve active materials of positive electrodes from Li-ion battery wastes,” Hydrometallurgy, vol. 169, pp. 426-432, 2017.
  • W. Gao, C. Liu, H. Cao, X. Zheng, X. Lin, H. Wang, Y. Zhang, Z. Sun, “Comprehensive evaluation on effective leaching of critical metals from spent lithium-ion batteries,” Waste Management, vol. 75, pp.477-485, 2018.
  • R. C. Wang, Y. C. Lin, S. H. Wu, “A novel recovery process of metal values from the cathode active materials of the lithium-ion secondary batteries,” Hydrometallurgy, vol. 99, pp. 194-201, 2009.
  • L. Li, R. Chen, F. Sun, F. Wu, J. Liu, “Preparation of LiCoO2 films from spent lithium-ion batteries by a combined recycling process,” Hydrometallurgy, vol. 108, pp. 220-225, 2011.
  • D. A. Ferreira, L. M. Z. Prados, D. Majuste, M. B. Mansur, “Hydrometallurgical separation of aluminium, cobalt, copper and lithium from spent Li-ion batteries,” Journal of Power Sources, vol. 187, pp. 238-246, 2009.
  • E. Gratz, Q. Sa, D. Apelian, Y. Wang, “A closed loop process for recycling spent lithium ion batteries,” Journal of Power Sources, vol. 262, pp. 255-262, 2014.
  • Y. Guo, F. Li, H. Zhu, G. Li, J. Huang, W. He, “Leaching lithium from the anode electrode materials of spent lithium-ion batteries by hydrochloric acid (HCl),” Waste Management, vol. 51, pp. 227-233, 2016.)
  • L. Li, W. Qu, X. Zhang, J. Lu, R. Chen, F. Wu, K. Amine, “Succinic acid-based leaching system: A sustainable process for recovery of valuable metals from spent Li-ion batteries,” Journal of Power Sources, vol. 282, pp. 544-551, 2015.
  • Q. Sa, E. Gratz, M. He, W. Lu, D. Apelian, Y. Wang, “Synthesis of high performance LiNi1/3Mn1/3Co1/3O2 from lithium ion battery recovery stream,” Journal of Power Sources, vol. 282, pp. 140-154, 2015.
  • L. Yao, Y. Feng, G. Xi, “A new method for the synthesis of LiNi1/3Co1/3Mn1/3O2 from waste lithium ion batteries,” RSC Advances, vol. 5, pp. 44107-44114, 2015.
  • X. Zheng, Z. Zhu, X. Lin, Y. Zhang, Y. He, H. Cao, Z. Sun, “A Mini-Review on Metal Recycling from Spent Lithium Ion Batteries,” Engineering, vol. 4, pp. 361-370, 2018.
  • L. Li, J. Ge, F. Wu, R. Chen, S. Chen, B. Wu, “Recovery of cobalt and lithium from spent lithium ion batteries using organic citric acid as leachant,” Journal of Hazardous Materials, vol. 176, pp. 288-293, 2010.
  • P. Balaz, “Mechanical activation in hydrometallurgy,” International Journal of Mineral Processing, vol. 72, pp. 341-354, 2003.
  • D. Tromans, J. A. Meech, “Enhanced Dissolution of Minerals: Stored Energy,” Amorphism and Mechanical Activation, vol. 14, no. 7, 1359-1377, 2001.
  • X. Zeng, J. Li, N. Singh, “Recycling of spent lithium-ion battery: A critical review,” Critical Reviews in Environmental Science and Technology, vol. 44, pp. 1129-1165, 2014.
  • J. Guan, H. Xiao, X. Lou, Y. Guo, X. Luo, Y. Li, C. Yan, X. Yan, G. Gao, H. Yuan, J. Dai, R. Su, W. Gu, Z. Guo, “Enhanced Hydrometallurgical Recovery of Valuable Metals from Spent Lithium-ion Batteries by Mechanical Activation Process,” ES Energy & Environment, vol. 1, pp. 80-88, 2018.
  • S. Zhang, C. Zhang, X. Zhang, E. Ma, “A mechanochemical method for one-step leaching of metals from spent LIBs,” Waste Management, vol. 161, pp. 245-253, 2023.
  • Y. Yang, X. Zheng, H. Cao, C. Zhao, X. Lin, P. Ning, Y. Zhang, W. Jin, Z. Sun, “A Closed-Loop Process for Selective Metal Recovery from Spent Lithium Iron Phosphate Batteries through Mechanochemical Activation,” ACS Sustainable Chemistry & Engineering, vol. 5, pp. 9972-9980, 2017.
  • B. Musariri, G. Akdogan, C. Dorfling, S. Bradshaw, “Evaluating organic acids as alternative leaching reagents for metal recovery from lithium ion batteries,” Minerals Engineering, vol. 137, pp. 108-117, 2019.
  • M. Wang, Q. Tan, J. Li, “Unveiling the Role and Mechanism of Mechanochemical Activation on Lithium Cobalt Oxide Powders from Spent Lithium-Ion Batteries,” Environmental Science and Technology, vol. 52, pp. 13136-13143, 2018.
  • N. V. Kosova, V. F. Anufrienko, T. V. Larina, A. Rougier, L. Aymard, J. M. Tarascon, “Disordering and electronic state of cobalt ions in mechanochemically synthesized LiCoO2,” Journal of Solid State Chemistry, vol. 165, pp. 56-64, 2002.
  • J. Guan, H. Xiao, X. Lou, Y. Guo, X. Luo, Y. Li, C. Yan, X. Yan, G. Gao, H. Yuan, J. Dai, R. Su, W. Gu, Z. Guo, “Enhanced Hydrometallurgical Recovery of Valuable Metals from Spent Lithium-ion Batteries by Mechanical Activation Process,” ES Energy & Environment, vol. 1, 80-88, 2018.
  • J. Guan, Y. Li, Y. Guo, R. Su, G. Gao, H. Song, H. Yuan, B. Liang, Z. Guo, “Mechanochemical Process Enhanced Cobalt and Lithium Recycling from Wasted Lithium-Ion Batteries,” ACS Sustainable Chemistry & Engineering, vol. 5, pp. 1026-1032, 2017.
  • L. Li, J. Ge, R. Chen, F. Wu, S. Chen, X. Zhang, “Environmental friendly leaching reagent for cobalt and lithium recovery from spent lithium-ion batteries,” Waste Management, vol. 30, pp. 2615-2621, 2010.
Yıl 2024, Cilt: 28 Sayı: 5, 1000 - 1009
https://doi.org/10.16984/saufenbilder.1506764

Öz

Proje Numarası

SAU BAP 2022-6-23-63

Kaynakça

  • D. J. Garole, R. Hossain, V. J. Garole, V. Sahajwalla, J. Nerkar, D. P. Dubal, “Recycle, Recover and Repurpose Strategy of Spent Li-ion Batteries and Catalysts: Current Status and Future Opportunities,” ChemSusChem, vol. 13, pp. 3079-3100, 2020.
  • G. Harper, R. Sommerville, E. Kendrick, L. Driscoll, P. Slater, R. Stolkin, A. Walton, P. Christensen, O. Heidrich, S. Lambert, A. Abbott, K. Ryder, L. Gaines, P. Anderson, “Recycling lithium-ion batteries from electric vehicles,” Nature, vol. 575, pp. 75-86, 2019.
  • Y. Miao, L. Liu, Y. Zhang, Q. Tan, J. Li, “An overview of global power lithium-ion batteries and associated critical metal recycling,” Journal of Hazardous Materials, vol. 425, pp. 1279001-14, 2022.
  • M. Jiao, Y. Wang, C. Ye, C. Wang, W. Zhang, C. Liang, "High-capacity SiOx (0≤x≤2) as promising anode materials for next-generation lithium-ion batteries," Journal of Alloys and Compounds, vol. 482, pp.155774 1-21, 2020.
  • X. Zhang, S. Han, P. Xiao, C. Fan, W. Zhang, “Thermal reduction of graphene oxide mixed with hard carbon and their high performance as lithium ion battery anode,” Carbon, vol. 100, pp. 600-607, 2016.
  • S. L. Chou, Y. Pan, J. Z. Wang, H. K. Liu, S. X. Dou, “Small things make a big difference: Binder effects on the performance of Li and Na batteries,” Physical Chemistry Chemical Physics, vol. 16, pp. 20347-20359, 2014.
  • E. Asadi Dalini, G. Karimi, S. Zandevakili, M. Goodarzi, “A Review on Environmental, Economic and Hydrometallurgical Processes of Recycling Spent Lithium-ion Batteries,” Mineral Processing and Extractive Metallurgy Review, vol. 42, no. 7, pp. 451-472, 2020.
  • Y. Yang, G. Huang, S. Xu, Y. He, X. Liu, “Thermal treatment process for the recovery of valuable metals from spent lithium-ion batteries,” Hydrometallurgy, vol. 165, pp. 390-396, 2016.
  • R. Golmohammadzadeh, F. Rashchi, E. Vahidi, “Recovery of lithium and cobalt from spent lithium-ion batteries using organic acids: Process optimization and kinetic aspects,” Waste Management, vol. 64, pp. 244-254, 2017.
  • G. Mishra, R. Jha, A. Meshram, K. K. Singh, "A review on recycling of lithium-ion batteries to recover critical metals," Journal of Environmental Chemical Engineering, vol. 10 (6), pp. 108534 1-15, 2022.
  • M. Joulié, E. Billy, R. Laucournet, D. Meyer, “Current collectors as reducing agent to dissolve active materials of positive electrodes from Li-ion battery wastes,” Hydrometallurgy, vol. 169, pp. 426-432, 2017.
  • W. Gao, C. Liu, H. Cao, X. Zheng, X. Lin, H. Wang, Y. Zhang, Z. Sun, “Comprehensive evaluation on effective leaching of critical metals from spent lithium-ion batteries,” Waste Management, vol. 75, pp.477-485, 2018.
  • R. C. Wang, Y. C. Lin, S. H. Wu, “A novel recovery process of metal values from the cathode active materials of the lithium-ion secondary batteries,” Hydrometallurgy, vol. 99, pp. 194-201, 2009.
  • L. Li, R. Chen, F. Sun, F. Wu, J. Liu, “Preparation of LiCoO2 films from spent lithium-ion batteries by a combined recycling process,” Hydrometallurgy, vol. 108, pp. 220-225, 2011.
  • D. A. Ferreira, L. M. Z. Prados, D. Majuste, M. B. Mansur, “Hydrometallurgical separation of aluminium, cobalt, copper and lithium from spent Li-ion batteries,” Journal of Power Sources, vol. 187, pp. 238-246, 2009.
  • E. Gratz, Q. Sa, D. Apelian, Y. Wang, “A closed loop process for recycling spent lithium ion batteries,” Journal of Power Sources, vol. 262, pp. 255-262, 2014.
  • Y. Guo, F. Li, H. Zhu, G. Li, J. Huang, W. He, “Leaching lithium from the anode electrode materials of spent lithium-ion batteries by hydrochloric acid (HCl),” Waste Management, vol. 51, pp. 227-233, 2016.)
  • L. Li, W. Qu, X. Zhang, J. Lu, R. Chen, F. Wu, K. Amine, “Succinic acid-based leaching system: A sustainable process for recovery of valuable metals from spent Li-ion batteries,” Journal of Power Sources, vol. 282, pp. 544-551, 2015.
  • Q. Sa, E. Gratz, M. He, W. Lu, D. Apelian, Y. Wang, “Synthesis of high performance LiNi1/3Mn1/3Co1/3O2 from lithium ion battery recovery stream,” Journal of Power Sources, vol. 282, pp. 140-154, 2015.
  • L. Yao, Y. Feng, G. Xi, “A new method for the synthesis of LiNi1/3Co1/3Mn1/3O2 from waste lithium ion batteries,” RSC Advances, vol. 5, pp. 44107-44114, 2015.
  • X. Zheng, Z. Zhu, X. Lin, Y. Zhang, Y. He, H. Cao, Z. Sun, “A Mini-Review on Metal Recycling from Spent Lithium Ion Batteries,” Engineering, vol. 4, pp. 361-370, 2018.
  • L. Li, J. Ge, F. Wu, R. Chen, S. Chen, B. Wu, “Recovery of cobalt and lithium from spent lithium ion batteries using organic citric acid as leachant,” Journal of Hazardous Materials, vol. 176, pp. 288-293, 2010.
  • P. Balaz, “Mechanical activation in hydrometallurgy,” International Journal of Mineral Processing, vol. 72, pp. 341-354, 2003.
  • D. Tromans, J. A. Meech, “Enhanced Dissolution of Minerals: Stored Energy,” Amorphism and Mechanical Activation, vol. 14, no. 7, 1359-1377, 2001.
  • X. Zeng, J. Li, N. Singh, “Recycling of spent lithium-ion battery: A critical review,” Critical Reviews in Environmental Science and Technology, vol. 44, pp. 1129-1165, 2014.
  • J. Guan, H. Xiao, X. Lou, Y. Guo, X. Luo, Y. Li, C. Yan, X. Yan, G. Gao, H. Yuan, J. Dai, R. Su, W. Gu, Z. Guo, “Enhanced Hydrometallurgical Recovery of Valuable Metals from Spent Lithium-ion Batteries by Mechanical Activation Process,” ES Energy & Environment, vol. 1, pp. 80-88, 2018.
  • S. Zhang, C. Zhang, X. Zhang, E. Ma, “A mechanochemical method for one-step leaching of metals from spent LIBs,” Waste Management, vol. 161, pp. 245-253, 2023.
  • Y. Yang, X. Zheng, H. Cao, C. Zhao, X. Lin, P. Ning, Y. Zhang, W. Jin, Z. Sun, “A Closed-Loop Process for Selective Metal Recovery from Spent Lithium Iron Phosphate Batteries through Mechanochemical Activation,” ACS Sustainable Chemistry & Engineering, vol. 5, pp. 9972-9980, 2017.
  • B. Musariri, G. Akdogan, C. Dorfling, S. Bradshaw, “Evaluating organic acids as alternative leaching reagents for metal recovery from lithium ion batteries,” Minerals Engineering, vol. 137, pp. 108-117, 2019.
  • M. Wang, Q. Tan, J. Li, “Unveiling the Role and Mechanism of Mechanochemical Activation on Lithium Cobalt Oxide Powders from Spent Lithium-Ion Batteries,” Environmental Science and Technology, vol. 52, pp. 13136-13143, 2018.
  • N. V. Kosova, V. F. Anufrienko, T. V. Larina, A. Rougier, L. Aymard, J. M. Tarascon, “Disordering and electronic state of cobalt ions in mechanochemically synthesized LiCoO2,” Journal of Solid State Chemistry, vol. 165, pp. 56-64, 2002.
  • J. Guan, H. Xiao, X. Lou, Y. Guo, X. Luo, Y. Li, C. Yan, X. Yan, G. Gao, H. Yuan, J. Dai, R. Su, W. Gu, Z. Guo, “Enhanced Hydrometallurgical Recovery of Valuable Metals from Spent Lithium-ion Batteries by Mechanical Activation Process,” ES Energy & Environment, vol. 1, 80-88, 2018.
  • J. Guan, Y. Li, Y. Guo, R. Su, G. Gao, H. Song, H. Yuan, B. Liang, Z. Guo, “Mechanochemical Process Enhanced Cobalt and Lithium Recycling from Wasted Lithium-Ion Batteries,” ACS Sustainable Chemistry & Engineering, vol. 5, pp. 1026-1032, 2017.
  • L. Li, J. Ge, R. Chen, F. Wu, S. Chen, X. Zhang, “Environmental friendly leaching reagent for cobalt and lithium recovery from spent lithium-ion batteries,” Waste Management, vol. 30, pp. 2615-2621, 2010.
Toplam 34 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Malzeme Üretim Teknolojileri
Bölüm Araştırma Makalesi
Yazarlar

Hasan Algül 0000-0002-4348-8865

Figen Algül 0000-0002-0314-1613

Proje Numarası SAU BAP 2022-6-23-63
Erken Görünüm Tarihi 14 Ekim 2024
Yayımlanma Tarihi
Gönderilme Tarihi 28 Haziran 2024
Kabul Tarihi 2 Eylül 2024
Yayımlandığı Sayı Yıl 2024 Cilt: 28 Sayı: 5

Kaynak Göster

APA Algül, H., & Algül, F. (2024). Role of Mechanical Activation in Enhancing Li and Co Recovery from Spent Li-ion Batteries through Citric Acid Leaching. Sakarya University Journal of Science, 28(5), 1000-1009. https://doi.org/10.16984/saufenbilder.1506764
AMA Algül H, Algül F. Role of Mechanical Activation in Enhancing Li and Co Recovery from Spent Li-ion Batteries through Citric Acid Leaching. SAUJS. Ekim 2024;28(5):1000-1009. doi:10.16984/saufenbilder.1506764
Chicago Algül, Hasan, ve Figen Algül. “Role of Mechanical Activation in Enhancing Li and Co Recovery from Spent Li-Ion Batteries through Citric Acid Leaching”. Sakarya University Journal of Science 28, sy. 5 (Ekim 2024): 1000-1009. https://doi.org/10.16984/saufenbilder.1506764.
EndNote Algül H, Algül F (01 Ekim 2024) Role of Mechanical Activation in Enhancing Li and Co Recovery from Spent Li-ion Batteries through Citric Acid Leaching. Sakarya University Journal of Science 28 5 1000–1009.
IEEE H. Algül ve F. Algül, “Role of Mechanical Activation in Enhancing Li and Co Recovery from Spent Li-ion Batteries through Citric Acid Leaching”, SAUJS, c. 28, sy. 5, ss. 1000–1009, 2024, doi: 10.16984/saufenbilder.1506764.
ISNAD Algül, Hasan - Algül, Figen. “Role of Mechanical Activation in Enhancing Li and Co Recovery from Spent Li-Ion Batteries through Citric Acid Leaching”. Sakarya University Journal of Science 28/5 (Ekim 2024), 1000-1009. https://doi.org/10.16984/saufenbilder.1506764.
JAMA Algül H, Algül F. Role of Mechanical Activation in Enhancing Li and Co Recovery from Spent Li-ion Batteries through Citric Acid Leaching. SAUJS. 2024;28:1000–1009.
MLA Algül, Hasan ve Figen Algül. “Role of Mechanical Activation in Enhancing Li and Co Recovery from Spent Li-Ion Batteries through Citric Acid Leaching”. Sakarya University Journal of Science, c. 28, sy. 5, 2024, ss. 1000-9, doi:10.16984/saufenbilder.1506764.
Vancouver Algül H, Algül F. Role of Mechanical Activation in Enhancing Li and Co Recovery from Spent Li-ion Batteries through Citric Acid Leaching. SAUJS. 2024;28(5):1000-9.

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