Yıl 2019, Cilt 14 , Sayı 2, Sayfalar 352 - 366 2019-11-30

Çevreci Çözücüler ile Polivinilpirolidon Nanolif Üretimi
Fabrication of Polyvinylpyrrolidone Nanofibers with Green Solvents

Funda CENGİZ ÇALLIOĞLU [1] , Hülya KESİCİ GÜLER [2]


Bu çalışmada, çevreci elektro lif çekimi yaklaşımı ile ultra saf su, gül suyu, lavanta suyu, etanol, asetik asit ve aseton gibi farklı çevreci çözücüler ile biyouyumlu polivinilpirolidon (PVP) nanoliflerin üretiminin gerçekleştirilmiştir. Polimer çözeltiler iletkenlik, yüzey gerilimi ve viskozite ölçümleri ile karakterize edilmiştir. Morfolojik analizler Taramalı Elektron Mikroskopu (SEM) ile gerçekleştirilmiştir. PVP/ultra saf su, gül suyu ve lavanta suyu çözeltilerinin iletkenlik, yüzey gerilimi ve viskozite sonuçları; benzer iken PVP/ asetik asit çözeltisi en yüksek viskoziteye ve en düşük iletkenlik değerlerine sahiptir. Diğer taraftan PVP/etanol çözeltisi en düşük yüzey gerilimine sahiptir. En düşük ortalama lif çapı; ultra saf su, gül suyu ve lavanta suyu ile elde edilmiştir fakat boncuklu lifler gözlenmiştir. En düzgün nanolifler PVP/etanol çözeltisinden elde edilirken, ortalama lif çapının 724 nm civarında, diğer PVP çözeltilerden daha kalın olduğu gözlenmiştir. Bu nedenle çalışmanın diğer kısmında lif morfolojisini geliştirmek için etanol yardımcı çözücü olarak seçilmiştir. Ayrıca, çözelti iletkenliği, lif çapı ve nanolifli yüzey çapı arasında ilişki olduğu tespit edilmiş ve iletkenlik arttıkça, lif çapının azaldığı, nanolifli yüzey çapının ise arttığı belirlenmiştir.

In this study, biocompatible Polyvinylpyrrolidone (PVP) nanofibers were produced with ultra-pure water, rose water, lavender water, ethanol, acetone and acetic acid with green electrospinning approach. Polymer solutions were characterized with conductivity, surface tension and viscosity measurements. Morphological analyzes were carried out with Scanning Electron Microscope (SEM). Conductivity, surface tension and viscosity results of PVP/ ultra-pure water, rose water and lavender water solutions were similar. On the other hand, PVP/acetic acid solution has the highest viscosity and lowest conductivity values and PVP/ethanol solution has got the lowest surface tension. In addition; the lowest average fiber diameters were obtained from ultra-pure water, rose water and lavender water solvents but there are some beads on the nanofiber structure. The smoothest nanofibers without beads were obtained from PVP/ethanol but it was observed that average fiber diameter is about 724 nm higher than other PVP solutions. Therefore, ethanol was chosen as a co-solvent to enhance fiber morphology for second part of study. Moreover; the relation between solution conductivity, nanofiber diameter and web diameter were determined and it was found that nanofibrous surface diameter increases and fiber diameter decreases with the increase of solution conductivity.

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Birincil Dil en
Konular Mühendislik, Kimya
Bölüm Makaleler
Yazarlar

Orcid: 0000-0002-6614-3616
Yazar: Funda CENGİZ ÇALLIOĞLU (Sorumlu Yazar)
Kurum: Süleyman Demirel Üniversitesi
Ülke: Turkey


Orcid: 0000-0002-5793-7772
Yazar: Hülya KESİCİ GÜLER
Kurum: Süleyman Demirel Üniversitesi
Ülke: Turkey


Teşekkür The authors would like to thank Assoc. Prof. Dr. Sabri Erbaş and Dr. Gürcan GÜLER for their contributions.
Tarihler

Yayımlanma Tarihi : 30 Kasım 2019

Bibtex @araştırma makalesi { sdufeffd589516, journal = {Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi}, issn = {}, eissn = {1306-7575}, address = {}, publisher = {Süleyman Demirel Üniversitesi}, year = {2019}, volume = {14}, pages = {352 - 366}, doi = {10.29233/sdufeffd.589516}, title = {Fabrication of Polyvinylpyrrolidone Nanofibers with Green Solvents}, key = {cite}, author = {CENGİZ ÇALLIOĞLU, Funda and KESİCİ GÜLER, Hülya} }
APA CENGİZ ÇALLIOĞLU, F , KESİCİ GÜLER, H . (2019). Fabrication of Polyvinylpyrrolidone Nanofibers with Green Solvents. Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi , 14 (2) , 352-366 . DOI: 10.29233/sdufeffd.589516
MLA CENGİZ ÇALLIOĞLU, F , KESİCİ GÜLER, H . "Fabrication of Polyvinylpyrrolidone Nanofibers with Green Solvents". Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi 14 (2019 ): 352-366 <https://dergipark.org.tr/tr/pub/sdufeffd/issue/50336/589516>
Chicago CENGİZ ÇALLIOĞLU, F , KESİCİ GÜLER, H . "Fabrication of Polyvinylpyrrolidone Nanofibers with Green Solvents". Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi 14 (2019 ): 352-366
RIS TY - JOUR T1 - Fabrication of Polyvinylpyrrolidone Nanofibers with Green Solvents AU - Funda CENGİZ ÇALLIOĞLU , Hülya KESİCİ GÜLER Y1 - 2019 PY - 2019 N1 - doi: 10.29233/sdufeffd.589516 DO - 10.29233/sdufeffd.589516 T2 - Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi JF - Journal JO - JOR SP - 352 EP - 366 VL - 14 IS - 2 SN - -1306-7575 M3 - doi: 10.29233/sdufeffd.589516 UR - https://doi.org/10.29233/sdufeffd.589516 Y2 - 2019 ER -
EndNote %0 Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi Fabrication of Polyvinylpyrrolidone Nanofibers with Green Solvents %A Funda CENGİZ ÇALLIOĞLU , Hülya KESİCİ GÜLER %T Fabrication of Polyvinylpyrrolidone Nanofibers with Green Solvents %D 2019 %J Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi %P -1306-7575 %V 14 %N 2 %R doi: 10.29233/sdufeffd.589516 %U 10.29233/sdufeffd.589516
ISNAD CENGİZ ÇALLIOĞLU, Funda , KESİCİ GÜLER, Hülya . "Fabrication of Polyvinylpyrrolidone Nanofibers with Green Solvents". Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi 14 / 2 (Kasım 2019): 352-366 . https://doi.org/10.29233/sdufeffd.589516
AMA CENGİZ ÇALLIOĞLU F , KESİCİ GÜLER H . Fabrication of Polyvinylpyrrolidone Nanofibers with Green Solvents. SDÜFEFFD. 2019; 14(2): 352-366.
Vancouver CENGİZ ÇALLIOĞLU F , KESİCİ GÜLER H . Fabrication of Polyvinylpyrrolidone Nanofibers with Green Solvents. Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi. 2019; 14(2): 366-352.