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Investigation of Under-Load Wear Behavior and Some Properties of Mg-2Zn Alloy with REE Addition

Yıl 2025, Cilt: 10 Sayı: 2, 549 - 561, 24.12.2025
https://doi.org/10.33484/sinopfbd.1700424

Öz

Magnesium (Mg) alloys are the lightest of engineering alloys and are increasingly used in fields such as aerospace, automotive, construction materials, and implant applications. In this study, Mg-2Zn magnesium alloy with good strength, formability, and absorption properties was used. To improve the mechanical properties of the cast Mg-2Zn alloy, two different alloys were obtained by adding 0.5% of the popular light Rare Earth Element (REE) La (lanthanum). The effects of La on the alloys were investigated using OM (Metallographic Examination), SEM (Scanning Electron Microscope), hardness, tensile, and wear tests. When the research results were examined, it was found that the addition of the La element to the Mg-2Zn alloy modified the Mg grain structure. Since the La element can dissolve in the Mg alloy, the addition of La weakened the texture. The La element dissolved in the matrix formed non-basal texture components. While the yield strength decreased by 17.62%, the tensile strength increased by 4.13%, and the elongation increased by 61.31%, demonstrating excellent performance. The hardness value increased by 48.53%. Under a 20 N load, the wear value decreased by 41.68% with the addition of La. The results of the study clearly demonstrate the benefit of adding low levels of the rare earth element La to the properties of Mg-2Zn light metal alloys.

Proje Numarası

KBÜBAP-23-DS-131

Kaynakça

  • Xu, T. Yang, Y. Peng, X. Song, J., & Pan, F. (2019). Overview of advancement and development trend on magnesium alloy. Journal of Magnesium and Alloys., 7(3), 536–544. https://doi.org/10.1016/j.jma.2019.08.001
  • Mordike, B., & Ebert, T. (2001). Magnesium: Properties applications potential. Materials Science and Engineering: A, 302(1), 37–45. https://doi.org/10.1016/S0921-5093(00)01351-4
  • Gören, H. A. Ünal, M. Türen, Y., & Ahlatçı, H. (2021). ZM21 Magnezyum alaşımına lantan ve kalsiyum ilavesinin mikroyapı, mekanik ve hadde özelliklerine etkisi. Bilecik Şeyh Edebali Üniversitesi Fen Bilim. Dergisi, 8(2), 1024–1031. https://doi.org/10.35193/bseufbd.1003822
  • Zhang, E. Yin, D. Xu, L. Yang, L., & Yang, K. (2009). Microstructure, mechanical and corrosion properties and biocompatibility of Mg–Zn–Mn alloys for biomedical application. Materials Science and Engineering: C, 29(3), 987–993. https://doi.org/10.1016/j.msec.2008.08.024
  • Calado, L. M. Carmezim, M. J., & Montemor, M. F. (2022). Rare earth based magnesium alloys A review on WE series. Frontiers in Materials, 8, 1-18. https://doi.org/10.3389/fmats.2021.804906
  • Li, X. Liu, C. Wang, J., & Zhang, C. (2021). Tailoring the strength and formability of Mg alloys through rare earth element additions (Gd and Dy) and dynamic recrystallizations. Materials Today Communications, 28, 102627. https://doi.org/10.1016/j.mtcomm.2021.102627
  • Li, H. Wang, P. Lin, G., & Huang, J. (2021). The role of rare earth elements in biodegradable metals: A review, Acta Biomaterialia, 129, 33–42. https://doi.org/10.1016/j.actbio.2021.05.014
  • Tekin, R. Demir, B., & Saud, A. N. (2025). Tribological behavior of MgZn alloys produced by powder metallurgy: influence of Zn in dry and simulated body fluid environments. Journal of Materials Engineering and Performance, 34, 27901–27924. https://doi.org/10.1007/s11665-025-11192-8
  • Bairagi, D., & Mandal, S. (2022). A comprehensive review on biocompatible Mg-based alloys as temporary orthopaedic implants: Current status, challenges, and future prospects. Journal of Magnesium and Alloys, 10(3) 627–669. https://doi.org/10.1016/j.jma.2021.09.005
  • Elen, L., & Çevik Elen, N. (2025). Effect of cooling rate on microstructure, mechanical and wear properties of Mg-2Zn and Mg-2Zn-1Mn alloys, Canadian Metallurgical Quarterly, 64(1), 61–76. https://doi.org/10.1080/00084433.2024.2331372
  • Koç, E., & Turan,M. E. (2019). Effect of Zn content and heat treatment on tribological behavior of biodegradable Mg-xZn alloys in simulated body fluid. Materials Research Express, 6(8), 0865b5. doi: 10.1088/2053-1591/ab1955.
  • Rokhlin, L. L. (2003). Magnesium Alloys Containing Rare Earth Metals. CRC Press, London, (pp. 256). https://doi.org/10.1201/9781482265163
  • Du, Y. Z. Qiao, X. G. Zheng, M. Y. Wu, K., & Xu, S. W. (2015). Development of high-strength, low-cost wrought Mg–2.5mass% Zn alloy through micro-alloying with Ca and La. Materials & Design, 85, 549–557. https://doi.org/10.1016/j.matdes.2015.07.029
  • Wu, W. Wang, Y. Zeng, X. Chen, L., & Liu, Z. (2003). Effect of neodymium on mechanical behavior of Mg-Zn-Zr magnesium alloy. Journal of Materials Science Letters, 22(6), 445–447. https://doi.org/10.1023/A:1022911728702
  • Alwakwak, M. A. I., Esen, I., Ahlatcı, H., & Keskin, E. (2023). Effect of Rare Earth Elements (Y, La) on Microstructural Characterization and Corrosion Behavior of Ternary Mg-Y-La Alloys. Materials (Basel), 16(14) 5141. https://doi.org/10.3390/ma16145141
  • Zhang, S., Shaoxiang, Z., Xiaonong, Z., Changli, Z., Jianan, L., Yang, S., Chaoying, X., Hairong, T., Yan, Z., Yaohua, H., Yao, J., & Yujun, B. (2010). Research on an Mg–Zn alloy as a degradable biomaterial. Acta Biomaterialia, 6(2), 626–640. https://doi.org/10.1016/j.actbio.2009.06.028
  • Zhang, Q., Tong, L., Cheng, L., Jiang, Z., Meng, J. & Zhang, H. (2015). Effect of Ce/La microalloying on microstructural evolution of Mg-Zn-Ca alloy during solution treatment. Journal of Rare Earths, 33(1), 70–76. https://doi.org/10.1016/S1002-0721(14)60385-9
  • Du, Y. Ge, Y., & Jiang, B. (2019). Dynamic Precipitation Behavior of a Mg-Zn-Ca-La Alloy During Deformation. JOM, 71(7), 2202–2208. https://doi.org/10.1007/s11837-019-03468-x
  • Berche, A., Benigni, P., Rogez, J., & Record, M.-C. (2014). Thermodynamic investigations in the solid state of the lanthanum–magnesium–zinc system. Intermetallics. 45, 46–52. https://doi.org/10.1016/j.intermet.2013.10.003
  • Peng, Q., Wang, J., Wu, Y., Meng, J., & Wang, L. (2008). The effect of La or Ce on ageing response and mechanical properties of cast Mg–Gd–Zr alloys. Materials Characterization, 59(4), 435–439. https://doi.org/10.1016/j.matchar.2007.02.013
  • Du, Y., Zheng, M., Qiao, X., Peng, W., & Jiang, B. (2016). Effect of La addition on the microstructure and mechanical properties of Mg–6wt% Zn alloys, Materials Science and Engineering: A, 673, 47-54, https://doi.org/10.1016/j.msea.2016.07.022
  • Prasad, A., Jain, J., & Gosvami, N. N. (2021). Effect of minor La addition on wear behaviour of Mg-10Dy alloy. Wear, 486–487, 204121. https://doi.org/10.1016/j.wear.2021.204121

NTE katkılı Mg-2Zn Alaşımının Yük Altında Aşınma Davranışı ve Bazı Özelliklerinin İncelenmesi

Yıl 2025, Cilt: 10 Sayı: 2, 549 - 561, 24.12.2025
https://doi.org/10.33484/sinopfbd.1700424

Öz

Magnezyum (Mg) alaşımları, mühendislik alaşımlarının en hafifi olarak havacılık, otomotiv, yapı malzemeleri ve implant uygulamaları gibi alanlarda artan kullanım oranına sahiptir. Bu araştırmada iyi mukavemet, şekillendirilebilirlik ve absorpsiyon özelliklere sahip Mg-2Zn magnezyum alaşımı kullanılmıştır. Döküm Mg-2Zn alaşımın mekanik özelliklerini geliştirmek için %0.5 oranında popüler hafif Nadir Toprak Elementi (NTE) La (lantan) eklenerek iki farklı alaşım elde edilmiştir. Alaşımlar üzerinde La’nın etkileri, OM (Metalografik İnceleme), SEM (Taramalı Elektron Mikroskobu), sertlik, çekme ve aşınma testleri ile araştırılmıştır. Araştırma sonuçları incelendiğinde Mg-2Zn alaşımına La elementinin eklenmesiyle Mg tane yapısı modifiye edilmiştir. La elementi Mg alaşımı içerisinde çözünebildiği için, La ilavesi dokuyu zayıflatmıştır. Matriste çözünen La elementi bazal olmayan doku bileşenleri meydana getirmiştir. Akma dayanımı %17.62 düşerken, çekme dayanımı %4.13 artmıştır, % uzama ise %61.31 artarak çok iyi performans sergilemiştir. Sertlik değeri %48.53 artmıştır. 20 N yük altında, La ilavesi ile aşınma değeri %41.68 oranında azalmıştır. Araştırmanın sonuçları Mg-2Zn hafif metal alaşımının özellikleri üzerinde nadir toprak elementi olan La’nın düşük oranlarda ilavesinin faydasını açıkça göstermiştir.

Etik Beyan

Çalışma, etik kurul izni veya herhangi bir özel izin gerektirmemektedir.

Destekleyen Kurum

Çalışma, Karabük Üniversitesi BAP Koordinasyon Birimi tarafından KBÜBAP-23-DS-131 numaralı proje ile desteklenmiştir.

Proje Numarası

KBÜBAP-23-DS-131

Teşekkür

Yazarlar Karabük Üniversitesi BAP Koordinasyon Birimine teşekkür ederler.

Kaynakça

  • Xu, T. Yang, Y. Peng, X. Song, J., & Pan, F. (2019). Overview of advancement and development trend on magnesium alloy. Journal of Magnesium and Alloys., 7(3), 536–544. https://doi.org/10.1016/j.jma.2019.08.001
  • Mordike, B., & Ebert, T. (2001). Magnesium: Properties applications potential. Materials Science and Engineering: A, 302(1), 37–45. https://doi.org/10.1016/S0921-5093(00)01351-4
  • Gören, H. A. Ünal, M. Türen, Y., & Ahlatçı, H. (2021). ZM21 Magnezyum alaşımına lantan ve kalsiyum ilavesinin mikroyapı, mekanik ve hadde özelliklerine etkisi. Bilecik Şeyh Edebali Üniversitesi Fen Bilim. Dergisi, 8(2), 1024–1031. https://doi.org/10.35193/bseufbd.1003822
  • Zhang, E. Yin, D. Xu, L. Yang, L., & Yang, K. (2009). Microstructure, mechanical and corrosion properties and biocompatibility of Mg–Zn–Mn alloys for biomedical application. Materials Science and Engineering: C, 29(3), 987–993. https://doi.org/10.1016/j.msec.2008.08.024
  • Calado, L. M. Carmezim, M. J., & Montemor, M. F. (2022). Rare earth based magnesium alloys A review on WE series. Frontiers in Materials, 8, 1-18. https://doi.org/10.3389/fmats.2021.804906
  • Li, X. Liu, C. Wang, J., & Zhang, C. (2021). Tailoring the strength and formability of Mg alloys through rare earth element additions (Gd and Dy) and dynamic recrystallizations. Materials Today Communications, 28, 102627. https://doi.org/10.1016/j.mtcomm.2021.102627
  • Li, H. Wang, P. Lin, G., & Huang, J. (2021). The role of rare earth elements in biodegradable metals: A review, Acta Biomaterialia, 129, 33–42. https://doi.org/10.1016/j.actbio.2021.05.014
  • Tekin, R. Demir, B., & Saud, A. N. (2025). Tribological behavior of MgZn alloys produced by powder metallurgy: influence of Zn in dry and simulated body fluid environments. Journal of Materials Engineering and Performance, 34, 27901–27924. https://doi.org/10.1007/s11665-025-11192-8
  • Bairagi, D., & Mandal, S. (2022). A comprehensive review on biocompatible Mg-based alloys as temporary orthopaedic implants: Current status, challenges, and future prospects. Journal of Magnesium and Alloys, 10(3) 627–669. https://doi.org/10.1016/j.jma.2021.09.005
  • Elen, L., & Çevik Elen, N. (2025). Effect of cooling rate on microstructure, mechanical and wear properties of Mg-2Zn and Mg-2Zn-1Mn alloys, Canadian Metallurgical Quarterly, 64(1), 61–76. https://doi.org/10.1080/00084433.2024.2331372
  • Koç, E., & Turan,M. E. (2019). Effect of Zn content and heat treatment on tribological behavior of biodegradable Mg-xZn alloys in simulated body fluid. Materials Research Express, 6(8), 0865b5. doi: 10.1088/2053-1591/ab1955.
  • Rokhlin, L. L. (2003). Magnesium Alloys Containing Rare Earth Metals. CRC Press, London, (pp. 256). https://doi.org/10.1201/9781482265163
  • Du, Y. Z. Qiao, X. G. Zheng, M. Y. Wu, K., & Xu, S. W. (2015). Development of high-strength, low-cost wrought Mg–2.5mass% Zn alloy through micro-alloying with Ca and La. Materials & Design, 85, 549–557. https://doi.org/10.1016/j.matdes.2015.07.029
  • Wu, W. Wang, Y. Zeng, X. Chen, L., & Liu, Z. (2003). Effect of neodymium on mechanical behavior of Mg-Zn-Zr magnesium alloy. Journal of Materials Science Letters, 22(6), 445–447. https://doi.org/10.1023/A:1022911728702
  • Alwakwak, M. A. I., Esen, I., Ahlatcı, H., & Keskin, E. (2023). Effect of Rare Earth Elements (Y, La) on Microstructural Characterization and Corrosion Behavior of Ternary Mg-Y-La Alloys. Materials (Basel), 16(14) 5141. https://doi.org/10.3390/ma16145141
  • Zhang, S., Shaoxiang, Z., Xiaonong, Z., Changli, Z., Jianan, L., Yang, S., Chaoying, X., Hairong, T., Yan, Z., Yaohua, H., Yao, J., & Yujun, B. (2010). Research on an Mg–Zn alloy as a degradable biomaterial. Acta Biomaterialia, 6(2), 626–640. https://doi.org/10.1016/j.actbio.2009.06.028
  • Zhang, Q., Tong, L., Cheng, L., Jiang, Z., Meng, J. & Zhang, H. (2015). Effect of Ce/La microalloying on microstructural evolution of Mg-Zn-Ca alloy during solution treatment. Journal of Rare Earths, 33(1), 70–76. https://doi.org/10.1016/S1002-0721(14)60385-9
  • Du, Y. Ge, Y., & Jiang, B. (2019). Dynamic Precipitation Behavior of a Mg-Zn-Ca-La Alloy During Deformation. JOM, 71(7), 2202–2208. https://doi.org/10.1007/s11837-019-03468-x
  • Berche, A., Benigni, P., Rogez, J., & Record, M.-C. (2014). Thermodynamic investigations in the solid state of the lanthanum–magnesium–zinc system. Intermetallics. 45, 46–52. https://doi.org/10.1016/j.intermet.2013.10.003
  • Peng, Q., Wang, J., Wu, Y., Meng, J., & Wang, L. (2008). The effect of La or Ce on ageing response and mechanical properties of cast Mg–Gd–Zr alloys. Materials Characterization, 59(4), 435–439. https://doi.org/10.1016/j.matchar.2007.02.013
  • Du, Y., Zheng, M., Qiao, X., Peng, W., & Jiang, B. (2016). Effect of La addition on the microstructure and mechanical properties of Mg–6wt% Zn alloys, Materials Science and Engineering: A, 673, 47-54, https://doi.org/10.1016/j.msea.2016.07.022
  • Prasad, A., Jain, J., & Gosvami, N. N. (2021). Effect of minor La addition on wear behaviour of Mg-10Dy alloy. Wear, 486–487, 204121. https://doi.org/10.1016/j.wear.2021.204121
Toplam 22 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Konular Malzeme Üretim Teknolojileri, Malzeme Mühendisliği (Diğer)
Bölüm Araştırma Makalesi
Yazarlar

Halil Ahmet Gören 0000-0003-4455-4024

Mehmet Ünal 0000-0003-3836-4566

Proje Numarası KBÜBAP-23-DS-131
Gönderilme Tarihi 16 Mayıs 2025
Kabul Tarihi 14 Ekim 2025
Yayımlanma Tarihi 24 Aralık 2025
Yayımlandığı Sayı Yıl 2025 Cilt: 10 Sayı: 2

Kaynak Göster

APA Gören, H. A., & Ünal, M. (2025). NTE katkılı Mg-2Zn Alaşımının Yük Altında Aşınma Davranışı ve Bazı Özelliklerinin İncelenmesi. Sinop Üniversitesi Fen Bilimleri Dergisi, 10(2), 549-561. https://doi.org/10.33484/sinopfbd.1700424


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