The effect of alumina additive on the properties of sheep hydroxyapatite

Abstract

Bu çalışmada ağırlıkça %1-10 arasında değişmekte olan alumina (Al2O3) ilavesinin koyun femur kemiklerinden elde edilmiş olan hidroksiapatitin (SHA) özelliklerine etkisi incelenmiştir. SHA tüm sinterleme sıcaklıklarında dekompoze olmuş ve toplam dekompoze olma oranı artan sıcaklıkla %1.4'ten %4.1' e çıkmıştır. Al2O3 ilaveli SHA' lerde dekompoze olma oranı ise artan Al2O3 ve sinterleme sıcaklığı ile %60.1' e artmıştır. SHA' nın yoğunluğu (2,16±0,03' ten 2,98±0,02 g/cm3' e) ve sertliği (0,93±0,15 GPa' dan 3,90±0,27 GPa' ya) artan sıcaklık arttıkça artmış, ancak; en yüksek basma dayanımı (82±5,05 MPa) ve kırılma tokluğu (0,70±0,11 MPam1/2) 1200oC sıcaklıkta elde edilmiştir. SHA' ya %1 ve %2.5 oranında Al2O3 ilavesi, %5 ve %10' dan daha iyi özelliklerin elde edilmesine katkı sağladı; optimum Al2O3 oranı %2.5 ve sinterleme sıcaklığı 1200oC’ dır. %2.5 oranında Al2O3 ilavesi ile SHA' nın kırılma tokluğu değeri 0,70±0,11 MPam1/2' den 1,70±0,15 MPam1/2' ye, basma dayanımı 82.48±5.05 MPa' dan 207.85±5.85 MPa' ya yükselmiştir. SHA' nın kırılganlık indeksi artan sıcaklıkla 1.70±0.27'den 7.10±0.50 μ-1/2'ye yükseldi. SHA' ya Al2O3 ilavesiyle maksimum değer olarak 3,56±0,18 μ-1/2' ye yükseldi. 28 günlük daldırma süresi sonunda SHA yüzeyinin büyük bir kısmının, SHA-2.5Al2O3 kompozitinin yüzeyinin ise tamamının apatit tabakası ile kaplandığı belirlendi.

Keywords

• Sheep hydroxyapatite
• Alumina
• Sintering
• Property

Kaynakça

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