EFFECT OF VARIOUS IONIC SALTS ON THE ADSORPTION OF CR(VI) USING HUMIC ACID AS AN ADSORBENT

Yıl 2017, Cilt: 2 Sayı: 1(3) - Volume 2, Issue 1(3), 174 - 183, 01.06.2017

Erol Pehlivan Şerife Parlayıcı Masood Hussain Ahmet Avcı

Öz

Humic acids
are a principal component of humic substances, which are the major constituents
of soil (humas), peat and coal. It is a complex mixture of many different acids
containing carboxyl and phenolate groups so that the mixture behaves
functionally as a dibasic acid or, occasionally, as a tribasic acid.

Humic acid (HA) was tested in the aqueous medium to
remove hexavalent chromium Cr(VI) during this study. The extent of adsorption
of Cr(VI) on the surface of HA was examined on the basis of increasing quantity
of humic acid. An ionic interference study was also performed in order to check
the effect of various ionic salts on the adsorption process. Various salts of
calcium chloride (CaCl₂), potassium chloride (KCl) and sodium
chloride (NaCl) were tested on the adsorption of Cr(VI) while using humic acid
as an adsorbent. Interactions between HA and Cr(VI) were confirmed by using
Fourier transform infrared (FTIR) spectroscopy. Further characterization was
also performed using UV-Visible spectroscopy and Scanning Electron Microscopy
(SEM) analysis.

Keywords:
Humic acid, Peat, Ionic interference, Characterization, Adsorbent

Anahtar Kelimeler

EFFECT OF VARIOUS IONIC SALTS ON THE ADSORPTION OF CR(VI) USING HUMIC ACID AS AN ADSORBENT

Kaynakça

• Erol Pehlivan1*, Şerife Parlayıcı1, Masood Hussain2, 3, Ahmet Avcı3 1 Department of Chemical Engineering, Selcuk University, 42079 Konya, Turkey 2National Centre of Excellence in Analytical Chemistry Sindh University, Jamshoro 76080, Pakistan 3Department of Mechanical Engineering, Selcuk University, 42079 Konya, Turkey *Erol Pehlivan, Department of Chemical Engineering, Selcuk University, 42079 Konya, Turkey, Tel: + 90 332 22321287 e-mail: [e-mail]