BibTex RIS Kaynak Göster

A study of organo-modified clay type on pet-clay based nanocomposite properties

Yıl 2014, , 33 - 46, 27.07.2014
https://doi.org/10.12748/uujms.201416498

Öz

Nowadays, there are many studies regarding with nanocomposite production including nano particles which aimed to gain many properties such as better strength, self-cleaning, and resistance to flammability into synthetic polymers. In nanocomposite production, the materials like clay, silica, metal oxides such as TiO2, Al2O3 are used. In present study, three different organically modified montmorillonite (MMT) clays of Cloisite 10A, 15A and 30B (3%) were added into polyethylene terephthalate (PET) polymer. Nanoclay and PET polymer were combined with melt blending method in terms of twin screw extruder. Internal and morphological properties of PET/clay nanocomposites were analyzed with scanning electron microscopy (SEM) images and XRD curves. And also, chemical and thermal properties of nanocomposite samples were studied. The findings and results of nanocomposites were compared with that of PET polymer. At the end of the study, the changes in PET polymer and the effect of clay type on material properties were determined.

Kaynakça

  • Litchfield DW and Baird DG. The rheology of high aspect ratio nano-particle filled liquids. Rheology Reviews, 2006: 1 – 60.
  • Lucilene Betega de Paivaa LB, Moralesa AR and Diaz FRV. Organoclays: properties, preparation and applications. Applied Clay Science, 2008; 42: 8 – 24. Pavlidou S and Papaspyrides CD. A review on polymer–layered silicate nanocomposites. Progress in Polymer Science, 2008; 33: 1119 – 1198.
  • Şen F, Palancıoğlu H and Aldaş K. Polymeric nanocomposites and their usage areas. Teknolojik Araştırmalar, 2010; 7: 111 – 118.
  • Benli B. Nanotechnology with clay based nanostructures since ancient ages. Kibited, 2008; 1(6): 143 – 162.
  • Karabulut M. Production and characterization of nanocomposite materials from recycled thermoplastics, Master Thesis, ODTÜ, Science Institute, Ankara, 124, 200 Kim S. PET Nanocomposites development with nanoscale materials, The University of Toledo, Doctor of Philosophy, 205, 2007.
  • Lithcfield D. The manufacture and mechanical properties of PET fibers filled with organically modified montmorillonite, Virginia Polytechnic Institute and State University, PhD thesis, 343, 2008.
  • Scaffaro R, Botta L, Ceraulo M and Mantia F. Effect of kind and content of organomodified clay on properties of PET nanocomposites. Journal of Applied Polymer Science, 2011; 122: 384 – 392.
  • Frounchi M and Dourbash A. Oxygen barrier properties of poly(ethyleneterephthalate) nanocomposite films. Macromolecule Material Engineering, 2009; 294: 68–74.
  • Barber G, Calhoun B and Moore R. Poly(ethylene Terephthalate) ionomer based clay nanocomposites produced via melt extrusion. Polymer, 2005; 46: 670667
  • Wang Y, Gao J, Ma Y and Agarwal U. Study on mechanical properties, thermal stability and crystallization behavior of PET/MMT nanocomposites. Composites, 2006: 99 – 407.
  • Solis AS, Rejon AG and Manero O. Production of nanocomposites of PETmontmorillonite clay by an extrusion process. Macromolecular Symp., 192, 281 – 292, 2003.
  • Gashti MP and Moradian S. Effect of nanoclay type on dyeability of polyethylene terephthalate/clay nanocomposites. Journal of Applied Polymer Science, 2012; 125(5):4109–4120.
  • Calcagno CIW, Mariani CM, Teixeira SR and Mauler RS. Morphology and crystallization behavior of the PP/PET nanocomposites. Journal of Applied Polymer Science, 2009; 111: 29 – 36.
  • Ghasemi H, Carreau PJ, Kamal MR and Calderon JU. Preparation and characterization of PET/clay nanocomposites by melt compounding. Polymer Engineering & Science, 2011; 51(6): 1178–1187.
  • Xiao W, Yu H, Han K and Yu M. Study on PET fiber modified by nanomaterials: improvement of dimensional thermal stability of PET fiber by forming PET/MMT nanocomposites. Journal of Applied Polymer Science, 2005; 96: 2247 – 2252.
  • Southern Clay Products Documents, 2013
  • Parvinzadeh M, Moradian S, Rashidi A and Yazdanshenas M. Surface characterization of polyethylene terephthalate/silica nanocomposites. Applied Surface Science, 2009: 2792 – 2802.
  • Yelkovan S and Yılmaz D. Analysis of the effects of nanoclay on PET nanocomposite properties. Autex Textile Conference, 22-24 May, DresdenGermany, 2013.
  • Alyamaç E. Impact modified poly(Ethylene Terephthalate)-organoclay nanocomposites, Master Thesis, ODTÜ, Science Institute, Ankara, 2004.
  • Çalımlı A. Nanokil-polimer kompozitlerin sentez ve karakterizasyonu. http://acikarsiv.ankara.edu.tr, 2013-21-01.
  • Bizarria MTM, Giraldi ALFM, Carvalho CM, Velasco JI, Avila MA and Mei LHI. Morphology and thermomechanical properties of recycled PET–organoclay nanocomposites. Journal of Applied Polymer Science, 2007; 104: 1839–1844. Todorov LV and Viana JC. Characterization of PET nanocomposites produced by different melt-based production methods. Journal of Applied Polymer Science, 2007;106: 1659 – 1669.
  • Ozen İ and Güneş S. Physical and dyeing properties of poly(ethylene terephthalate)/montmorillonite nanocomposite filament yarns. Polymer Engineering and Science, 2012.
  • Labde R. Preparation and characterization of polyethylene terephthalate/montmorillonite nanocomposites by in-situ polymerization method, The University of Toledo, Master of Science Degree in Chemical Engineering, 2010.
  • Lai MC, Chang KC, Huang WC, Hsu SC and Yeh JM. Effect of swelling agent on the physical properties of PET–clay nanocomposite materials prepared from melt intercalation approach.Journal of Physics and Chemistry of Solids, 2008; 69(56): 1371–1374.
  • Arik B, Bozaci E, Demir A and Özdoğan E. Thermogravimetric, microscopic and mechanical analyses of pbt and pet yarns. Tekstil Ve Konfeksiyon, 2013; 23(2): 101 – 107.

A study of organo-modified clay type on pet-clay based nanocomposite properties

Yıl 2014, , 33 - 46, 27.07.2014
https://doi.org/10.12748/uujms.201416498

Öz

Nowadays, there are many studies regarding with nanocomposite production including nano particles which aimed to gain many properties such as better strength, self-cleaning, and resistance to flammability into synthetic polymers. In nanocomposite production, the materials like clay, silica, metal oxides such as TiO2, Al2O3 are used. In present study, three different organically modified montmorillonite (MMT) clays of Cloisite 10A, 15A and 30B (3%) were added into polyethylene terephthalate (PET) polymer. Nanoclay and PET polymer were combined with melt blending method in terms of twin screw extruder. Internal and morphological properties of PET/clay nanocomposites were analyzed with scanning electron microscopy (SEM) images and XRD curves. And also, chemical and thermal properties of nanocomposite samples were studied. The findings and results of nanocomposites were compared with that of PET polymer. At the end of the study, the changes in PET polymer and the effect of clay type on material properties were determined.

Kaynakça

  • Litchfield DW and Baird DG. The rheology of high aspect ratio nano-particle filled liquids. Rheology Reviews, 2006: 1 – 60.
  • Lucilene Betega de Paivaa LB, Moralesa AR and Diaz FRV. Organoclays: properties, preparation and applications. Applied Clay Science, 2008; 42: 8 – 24. Pavlidou S and Papaspyrides CD. A review on polymer–layered silicate nanocomposites. Progress in Polymer Science, 2008; 33: 1119 – 1198.
  • Şen F, Palancıoğlu H and Aldaş K. Polymeric nanocomposites and their usage areas. Teknolojik Araştırmalar, 2010; 7: 111 – 118.
  • Benli B. Nanotechnology with clay based nanostructures since ancient ages. Kibited, 2008; 1(6): 143 – 162.
  • Karabulut M. Production and characterization of nanocomposite materials from recycled thermoplastics, Master Thesis, ODTÜ, Science Institute, Ankara, 124, 200 Kim S. PET Nanocomposites development with nanoscale materials, The University of Toledo, Doctor of Philosophy, 205, 2007.
  • Lithcfield D. The manufacture and mechanical properties of PET fibers filled with organically modified montmorillonite, Virginia Polytechnic Institute and State University, PhD thesis, 343, 2008.
  • Scaffaro R, Botta L, Ceraulo M and Mantia F. Effect of kind and content of organomodified clay on properties of PET nanocomposites. Journal of Applied Polymer Science, 2011; 122: 384 – 392.
  • Frounchi M and Dourbash A. Oxygen barrier properties of poly(ethyleneterephthalate) nanocomposite films. Macromolecule Material Engineering, 2009; 294: 68–74.
  • Barber G, Calhoun B and Moore R. Poly(ethylene Terephthalate) ionomer based clay nanocomposites produced via melt extrusion. Polymer, 2005; 46: 670667
  • Wang Y, Gao J, Ma Y and Agarwal U. Study on mechanical properties, thermal stability and crystallization behavior of PET/MMT nanocomposites. Composites, 2006: 99 – 407.
  • Solis AS, Rejon AG and Manero O. Production of nanocomposites of PETmontmorillonite clay by an extrusion process. Macromolecular Symp., 192, 281 – 292, 2003.
  • Gashti MP and Moradian S. Effect of nanoclay type on dyeability of polyethylene terephthalate/clay nanocomposites. Journal of Applied Polymer Science, 2012; 125(5):4109–4120.
  • Calcagno CIW, Mariani CM, Teixeira SR and Mauler RS. Morphology and crystallization behavior of the PP/PET nanocomposites. Journal of Applied Polymer Science, 2009; 111: 29 – 36.
  • Ghasemi H, Carreau PJ, Kamal MR and Calderon JU. Preparation and characterization of PET/clay nanocomposites by melt compounding. Polymer Engineering & Science, 2011; 51(6): 1178–1187.
  • Xiao W, Yu H, Han K and Yu M. Study on PET fiber modified by nanomaterials: improvement of dimensional thermal stability of PET fiber by forming PET/MMT nanocomposites. Journal of Applied Polymer Science, 2005; 96: 2247 – 2252.
  • Southern Clay Products Documents, 2013
  • Parvinzadeh M, Moradian S, Rashidi A and Yazdanshenas M. Surface characterization of polyethylene terephthalate/silica nanocomposites. Applied Surface Science, 2009: 2792 – 2802.
  • Yelkovan S and Yılmaz D. Analysis of the effects of nanoclay on PET nanocomposite properties. Autex Textile Conference, 22-24 May, DresdenGermany, 2013.
  • Alyamaç E. Impact modified poly(Ethylene Terephthalate)-organoclay nanocomposites, Master Thesis, ODTÜ, Science Institute, Ankara, 2004.
  • Çalımlı A. Nanokil-polimer kompozitlerin sentez ve karakterizasyonu. http://acikarsiv.ankara.edu.tr, 2013-21-01.
  • Bizarria MTM, Giraldi ALFM, Carvalho CM, Velasco JI, Avila MA and Mei LHI. Morphology and thermomechanical properties of recycled PET–organoclay nanocomposites. Journal of Applied Polymer Science, 2007; 104: 1839–1844. Todorov LV and Viana JC. Characterization of PET nanocomposites produced by different melt-based production methods. Journal of Applied Polymer Science, 2007;106: 1659 – 1669.
  • Ozen İ and Güneş S. Physical and dyeing properties of poly(ethylene terephthalate)/montmorillonite nanocomposite filament yarns. Polymer Engineering and Science, 2012.
  • Labde R. Preparation and characterization of polyethylene terephthalate/montmorillonite nanocomposites by in-situ polymerization method, The University of Toledo, Master of Science Degree in Chemical Engineering, 2010.
  • Lai MC, Chang KC, Huang WC, Hsu SC and Yeh JM. Effect of swelling agent on the physical properties of PET–clay nanocomposite materials prepared from melt intercalation approach.Journal of Physics and Chemistry of Solids, 2008; 69(56): 1371–1374.
  • Arik B, Bozaci E, Demir A and Özdoğan E. Thermogravimetric, microscopic and mechanical analyses of pbt and pet yarns. Tekstil Ve Konfeksiyon, 2013; 23(2): 101 – 107.
Toplam 25 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Bölüm Makaleler
Yazarlar

Sinem Yelkovan Bu kişi benim

Demet Yılmaz Bu kişi benim

Kasım Aksoy - Bu kişi benim

Yayımlanma Tarihi 27 Temmuz 2014
Yayımlandığı Sayı Yıl 2014

Kaynak Göster

APA Yelkovan, S., Yılmaz, D., & -, K. A. (2014). A study of organo-modified clay type on pet-clay based nanocomposite properties. Usak University Journal of Material Sciences, 3(1), 33-46. https://doi.org/10.12748/uujms.201416498
AMA Yelkovan S, Yılmaz D, - KA. A study of organo-modified clay type on pet-clay based nanocomposite properties. Usak University Journal of Material Sciences. Haziran 2014;3(1):33-46. doi:10.12748/uujms.201416498
Chicago Yelkovan, Sinem, Demet Yılmaz, ve Kasım Aksoy -. “A Study of Organo-Modified Clay Type on Pet-Clay Based Nanocomposite Properties”. Usak University Journal of Material Sciences 3, sy. 1 (Haziran 2014): 33-46. https://doi.org/10.12748/uujms.201416498.
EndNote Yelkovan S, Yılmaz D, - KA (01 Haziran 2014) A study of organo-modified clay type on pet-clay based nanocomposite properties. Usak University Journal of Material Sciences 3 1 33–46.
IEEE S. Yelkovan, D. Yılmaz, ve K. A. -, “A study of organo-modified clay type on pet-clay based nanocomposite properties”, Usak University Journal of Material Sciences, c. 3, sy. 1, ss. 33–46, 2014, doi: 10.12748/uujms.201416498.
ISNAD Yelkovan, Sinem vd. “A Study of Organo-Modified Clay Type on Pet-Clay Based Nanocomposite Properties”. Usak University Journal of Material Sciences 3/1 (Haziran 2014), 33-46. https://doi.org/10.12748/uujms.201416498.
JAMA Yelkovan S, Yılmaz D, - KA. A study of organo-modified clay type on pet-clay based nanocomposite properties. Usak University Journal of Material Sciences. 2014;3:33–46.
MLA Yelkovan, Sinem vd. “A Study of Organo-Modified Clay Type on Pet-Clay Based Nanocomposite Properties”. Usak University Journal of Material Sciences, c. 3, sy. 1, 2014, ss. 33-46, doi:10.12748/uujms.201416498.
Vancouver Yelkovan S, Yılmaz D, - KA. A study of organo-modified clay type on pet-clay based nanocomposite properties. Usak University Journal of Material Sciences. 2014;3(1):33-46.