Yıl 2019, Cilt 1 , Sayı 2, Sayfalar 52 - 56 2019-12-25

APPLICATION OF DES (DEEP EUTECTIC SOLVENTS) TO WOOD EXTRACTIVES

Ayben KILIÇ-PEKGÖZLÜ [1] , Esra CEYLAN [2]



Deep eutectic solvents (DES), known as environmentally friendly, recyclable, non-poisonous, low volatile, non-flammable and harmless are first found by Abbott et al. in 2003. In the last decade, scientists are working with DES in different areas. Mainly, they focus on isolation of cellulose and lignin. Regard to extractives, to the best of our knowledge DES was not studied before. In this study, it was aimed to determine the extractive composition of Scotch pine with deep eutectic solvents.


Pinus sylvestris L. was used as wood material.  As deep eutectic solvent (DES) Choline chloride (Merck 5.00117), ethylene glycol (Merck 1.00949) and urea (Merck 1.08487) were used with molar ratio of choline chloride; ethylene glycol (1:2 m/m), and choline chloride: urea (1:2 m/m). Sequential soxhelet extraction was performed first with n-hexane and then acetone-water with 5 g wood sample for 6 hours. With DES two extractions were performed in an ultrasonic (UB) and hot-water bath (HWB) at 60°C for 30 min. 0.05 g wood samples were used for these extractions. Identification and quantification were done with GC-MS and FID-GC.


Similar results were obtained with DES and organic solvents. Fatty acids, resin acids and stilbenes are the main chemical groups. Oleic acid (1.4-9%), linoleic acid (1.6-8%) and levopimaric acid (0.6-17.7%) are dominant compounds, found in all extracts. Also, monomethyl pinosylvin (51.5%) was found in acetone: water mixture. DES can be an alternative to organic solvents in wood extraction.


Deep Eutectic Solvents( DES), Extractives
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Birincil Dil en
Bölüm Research Articles
Yazarlar

Orcid: 0000-0002-3640-6198
Yazar: Ayben KILIÇ-PEKGÖZLÜ (Sorumlu Yazar)
Kurum: BARTIN ÜNİVERSİTESİ, BARTIN ORMAN FAKÜLTESİ
Ülke: Turkey


Orcid: 0000-0002-5336-4698
Yazar: Esra CEYLAN
Kurum: BARTIN ÜNİVERSİTESİ, BARTIN ORMAN FAKÜLTESİ
Ülke: Turkey


Destekleyen Kurum Bartın University
Proje Numarası 2018-FEN-A-006
Teşekkür This study is a part of a project 2018-FEN-A-006 supported by Bartin University
Tarihler

Yayımlanma Tarihi : 25 Aralık 2019

Bibtex @konferans bildirisi { wie645347, journal = {Wood Industry and Engineering}, issn = {2687-6043}, eissn = {2687-6035}, address = {Karadeniz Teknik Üniversitesi Orman Endüstri Mühendisliği Bölümü 61080 Trabzon}, publisher = {Karadeniz Teknik Üniversitesi}, year = {2019}, volume = {1}, pages = {52 - 56}, doi = {}, title = {APPLICATION OF DES (DEEP EUTECTIC SOLVENTS) TO WOOD EXTRACTIVES}, key = {cite}, author = {Kılıç-pekgözlü, Ayben and Ceylan, Esra} }
APA Kılıç-pekgözlü, A , Ceylan, E . (2019). APPLICATION OF DES (DEEP EUTECTIC SOLVENTS) TO WOOD EXTRACTIVES . Wood Industry and Engineering , 1 (2) , 52-56 . Retrieved from https://dergipark.org.tr/tr/pub/wie/issue/50930/645347
MLA Kılıç-pekgözlü, A , Ceylan, E . "APPLICATION OF DES (DEEP EUTECTIC SOLVENTS) TO WOOD EXTRACTIVES" . Wood Industry and Engineering 1 (2019 ): 52-56 <https://dergipark.org.tr/tr/pub/wie/issue/50930/645347>
Chicago Kılıç-pekgözlü, A , Ceylan, E . "APPLICATION OF DES (DEEP EUTECTIC SOLVENTS) TO WOOD EXTRACTIVES". Wood Industry and Engineering 1 (2019 ): 52-56
RIS TY - JOUR T1 - APPLICATION OF DES (DEEP EUTECTIC SOLVENTS) TO WOOD EXTRACTIVES AU - Ayben Kılıç-pekgözlü , Esra Ceylan Y1 - 2019 PY - 2019 N1 - DO - T2 - Wood Industry and Engineering JF - Journal JO - JOR SP - 52 EP - 56 VL - 1 IS - 2 SN - 2687-6043-2687-6035 M3 - UR - Y2 - 2019 ER -
EndNote %0 Wood Industry and Engineering APPLICATION OF DES (DEEP EUTECTIC SOLVENTS) TO WOOD EXTRACTIVES %A Ayben Kılıç-pekgözlü , Esra Ceylan %T APPLICATION OF DES (DEEP EUTECTIC SOLVENTS) TO WOOD EXTRACTIVES %D 2019 %J Wood Industry and Engineering %P 2687-6043-2687-6035 %V 1 %N 2 %R %U
ISNAD Kılıç-pekgözlü, Ayben , Ceylan, Esra . "APPLICATION OF DES (DEEP EUTECTIC SOLVENTS) TO WOOD EXTRACTIVES". Wood Industry and Engineering 1 / 2 (Aralık 2019): 52-56 .
AMA Kılıç-pekgözlü A , Ceylan E . APPLICATION OF DES (DEEP EUTECTIC SOLVENTS) TO WOOD EXTRACTIVES. WI&E. 2019; 1(2): 52-56.
Vancouver Kılıç-pekgözlü A , Ceylan E . APPLICATION OF DES (DEEP EUTECTIC SOLVENTS) TO WOOD EXTRACTIVES. Wood Industry and Engineering. 2019; 1(2): 52-56.