Mikro Ölçekli Sıfır Değerlikli Demir (mZVI) Partikülü ile Sulu Çözeltilerden C.I. Vat Green 1 Boyasının Gideriminin İncelenmesi

Year 2023, , 54 - 67, 31.05.2023

Burçin Yıldız

https://doi.org/10.35193/bseufbd.1131538

Cited By: 1

Abstract

Bu çalışma, sulardan C.I. Vat Green 1 boyar maddesinin adsorpsiyonu için mikro ölçekli sıfır değerlikli demirin (mZVI) uygulanabilirliğini göstermektedir. mZVI partikülleri SEM, EDX, BET yüzey alanı analizi ve pHzpc ile karakterize edilmiştir. Analizlerden kullanılan mZVI partiküllerinin yüzey özelliklerinde meydana gelen değişimler ise SEM ve EDX ile belirlenmiştir. 5.2 m2/g BET yüzey alanı ile yaklaşık 5 m’den küçük olan küresel partiküller, yüksek giderim verimini desteklemiştir. Analiz sonrasında partikül boyut ve şekilleri ile elementel bileşimde meydana gelen değişiklikler yüksek adsorpsiyon verimini doğruladığı gibi 5.73 olan pHzpc değeri de düşük pH’larda yüksek giderim veriminin gözlenmesini sağlamıştır. C.I. Vat Green 1’in giderim verimi ile adsorpsiyon kinetik ve izotermlerini değerlendirebilmek için çözelti pH’sı, demir dozajı, reaksiyon sıcaklığı, kirletici konsantrasyonu gibi parametreler kesikli deney serileri ile incelenmiştir. 3’ten büyük pH değerlerinde, 1 g/L’den büyük mZVI dozajlarında ve kirletici derişiminin arttığı durumlarda giderim verimi azalırken 1 g/L’ye kadar olan dozajlarda ve sıcaklık artışı ile verim artmıştır. Optimum pH, 3 ve optimum mZVI dozajı 1 g/L olarak belirlenmiştir. TOK sonuçları da giderim mekanizmasının adsorpsiyon olduğunu doğrulamıştır. Kinetik verilerin en iyi olarak pseudo ikinci dereceden modele uyduğu bulunmuştur. Adsorpsiyon denge verileri Langmuir modeli ile temsil edilmiş ve maksimum adsorpsiyon kapasitesi 36.50 mg/g olarak bulunmuştur.

Keywords

Tekstil atıksuyu, Vat Green 1, Mikro ölçekli demir, Adsorpsiyon

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