Mikro Ölçekli Sıfır Değerlikli Demir (mZVI) Partikülü ile Sulu Çözeltilerden C.I. Vat Green 1 Boyasının Gideriminin İncelenmesi

Burçin Yıldız

doi:10.35193/bseufbd.1131538

Mikro Ölçekli Sıfır Değerlikli Demir (mZVI) Partikülü ile Sulu Çözeltilerden C.I. Vat Green 1 Boyasının Gideriminin İncelenmesi

Abstract

Bu çalışma, sulardan C.I. Vat Green 1 boyar maddesinin adsorpsiyonu için mikro ölçekli sıfır değerlikli demirin (mZVI) uygulanabilirliğini göstermektedir. mZVI partikülleri SEM, EDX, BET yüzey alanı analizi ve pHzpc ile karakterize edilmiştir. Analizlerden kullanılan mZVI partiküllerinin yüzey özelliklerinde meydana gelen değişimler ise SEM ve EDX ile belirlenmiştir. 5.2 m2/g BET yüzey alanı ile yaklaşık 5 m’den küçük olan küresel partiküller, yüksek giderim verimini desteklemiştir. Analiz sonrasında partikül boyut ve şekilleri ile elementel bileşimde meydana gelen değişiklikler yüksek adsorpsiyon verimini doğruladığı gibi 5.73 olan pHzpc değeri de düşük pH’larda yüksek giderim veriminin gözlenmesini sağlamıştır. C.I. Vat Green 1’in giderim verimi ile adsorpsiyon kinetik ve izotermlerini değerlendirebilmek için çözelti pH’sı, demir dozajı, reaksiyon sıcaklığı, kirletici konsantrasyonu gibi parametreler kesikli deney serileri ile incelenmiştir. 3’ten büyük pH değerlerinde, 1 g/L’den büyük mZVI dozajlarında ve kirletici derişiminin arttığı durumlarda giderim verimi azalırken 1 g/L’ye kadar olan dozajlarda ve sıcaklık artışı ile verim artmıştır. Optimum pH, 3 ve optimum mZVI dozajı 1 g/L olarak belirlenmiştir. TOK sonuçları da giderim mekanizmasının adsorpsiyon olduğunu doğrulamıştır. Kinetik verilerin en iyi olarak pseudo ikinci dereceden modele uyduğu bulunmuştur. Adsorpsiyon denge verileri Langmuir modeli ile temsil edilmiş ve maksimum adsorpsiyon kapasitesi 36.50 mg/g olarak bulunmuştur.

Keywords

References

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Details

Primary Language

Turkish

Subjects

Engineering

Journal Section

Research Article

Authors

Burçin Yıldız ^*
0000-0001-9750-7278
Türkiye

Publication Date

May 31, 2023

Submission Date

June 16, 2022

Acceptance Date

February 13, 2023

Published in Issue

Year 2023 Volume: 10 Number: 1

DOI

https://doi.org/10.35193/bseufbd.1131538

IZ

https://izlik.org/JA68CG26KX

Cite

RIS / Bibtex

APA

Yıldız, B. (2023). Mikro Ölçekli Sıfır Değerlikli Demir (mZVI) Partikülü ile Sulu Çözeltilerden C.I. Vat Green 1 Boyasının Gideriminin İncelenmesi. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi, 10(1), 54-67. https://doi.org/10.35193/bseufbd.1131538

AMA

1.Yıldız B. Mikro Ölçekli Sıfır Değerlikli Demir (mZVI) Partikülü ile Sulu Çözeltilerden C.I. Vat Green 1 Boyasının Gideriminin İncelenmesi. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi. 2023;10(1):54-67. doi:10.35193/bseufbd.1131538

Chicago

Yıldız, Burçin. 2023. “Mikro Ölçekli Sıfır Değerlikli Demir (mZVI) Partikülü Ile Sulu Çözeltilerden C.I. Vat Green 1 Boyasının Gideriminin İncelenmesi”. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi 10 (1): 54-67. https://doi.org/10.35193/bseufbd.1131538.

EndNote

Yıldız B (May 1, 2023) Mikro Ölçekli Sıfır Değerlikli Demir (mZVI) Partikülü ile Sulu Çözeltilerden C.I. Vat Green 1 Boyasının Gideriminin İncelenmesi. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi 10 1 54–67.

IEEE

[1]B. Yıldız, “Mikro Ölçekli Sıfır Değerlikli Demir (mZVI) Partikülü ile Sulu Çözeltilerden C.I. Vat Green 1 Boyasının Gideriminin İncelenmesi”, Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi, vol. 10, no. 1, pp. 54–67, May 2023, doi: 10.35193/bseufbd.1131538.

ISNAD

Yıldız, Burçin. “Mikro Ölçekli Sıfır Değerlikli Demir (mZVI) Partikülü Ile Sulu Çözeltilerden C.I. Vat Green 1 Boyasının Gideriminin İncelenmesi”. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi 10/1 (May 1, 2023): 54-67. https://doi.org/10.35193/bseufbd.1131538.

JAMA

1.Yıldız B. Mikro Ölçekli Sıfır Değerlikli Demir (mZVI) Partikülü ile Sulu Çözeltilerden C.I. Vat Green 1 Boyasının Gideriminin İncelenmesi. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi. 2023;10:54–67.

MLA

Yıldız, Burçin. “Mikro Ölçekli Sıfır Değerlikli Demir (mZVI) Partikülü Ile Sulu Çözeltilerden C.I. Vat Green 1 Boyasının Gideriminin İncelenmesi”. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi, vol. 10, no. 1, May 2023, pp. 54-67, doi:10.35193/bseufbd.1131538.

Vancouver

1.Burçin Yıldız. Mikro Ölçekli Sıfır Değerlikli Demir (mZVI) Partikülü ile Sulu Çözeltilerden C.I. Vat Green 1 Boyasının Gideriminin İncelenmesi. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi. 2023 May 1;10(1):54-67. doi:10.35193/bseufbd.1131538

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