Year 2020, Volume 7 , Issue 2, Pages 994 - 1003 2020-12-30

Cr2O3 Nanoyapılarının Elektrokimyasal Sentezi ve Karakterizasyonu
Electrochemical Synthesis and Characterization of Cr2O3 Nanostructures

Ahmet Recep KORKMAZ [1] , Emir ÇEPNİ [2] , Hülya ÖZTÜRK DOĞAN [3]


Bu çalışmada krom(III) oksit (Cr2O3) nanoyapıları flor katkılı kalay oksit (FTO) kaplı cam elektrot yüzeyinde elektrokimyasal teknik kullanılarak sentezlenmiştir. Elektrolit çözeltisi olarak CrCl3 içeren ortamda öncelikle krom oksihidroksit türleri oluşturulmuş ve sonrasında ısıl işlem uygulanarak oksit formuna dönüşüm sağlanmıştır. Elektrokimyasal sentez üzerine indirgenme potansiyeli ve depozisyon süresinin etkisi incelenmiştir. Elektrokimyasal olarak biriktirilen Cr2O3 nanoyapılarının karakterizasyonu XRD, SEM ve EDS teknikleri kullanılarak gerçekleştirilmiştir. -1,4 V sabit potansiyelde hazırlanan Cr2O3 nanoyapılarının XRD spektrumunda Cr2O3’in (110) düzlemine ait kırınım piki elde edilmiştir. EDS spektrumu ise elementel olarak oldukça saf Cr2O3 nanoyapılarının sentezlendiğini desteklemiştir.

In this study, chromium (III) oxide (Cr2O3) nanostructures were synthesized using electrochemical technique on the surface of the fluorine-doped tin oxide (FTO) coated glass electrode. Firstly, chromium oxyhydroxide species were created in the aqueous electrolyte solution containing CrCl3, and then thermal annealing was applied to convert to oxide form. The effect of reduction potential and deposition time on electrochemical synthesis was investigated. The characterization of electrochemically deposited Cr2O3 nanostructures was carried out using XRD, SEM and EDS techniques. The diffraction peak of the Cr2O3 (110) plane was obtained in the XRD spectrum of Cr2O3 nanostructures prepared at -1,4 V constant potential. The EDS spectrum supported that elementally highly pure Cr2O3 nanostructures were synthesized.

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Primary Language tr
Subjects Basic Sciences
Journal Section Articles
Authors

Orcid: 0000-0003-3583-514X
Author: Ahmet Recep KORKMAZ
Institution: ATATÜRK ÜNİVERSİTESİ
Country: Turkey


Orcid: 0000-0001-8738-1157
Author: Emir ÇEPNİ
Institution: ATATÜRK ÜNİVERSİTESİ
Country: Turkey


Orcid: 0000-0002-4072-7744
Author: Hülya ÖZTÜRK DOĞAN (Primary Author)
Institution: ATATÜRK ÜNİVERSİTESİ
Country: Turkey


Thanks Bu çalışmanın gerçekleştirilmesinde laboratuvar alt yapısının kullanılmasına izin verdiği için Atatürk Üniversitesi Fen Fakültesi Dekanlığı’na teşekkür ederiz. Sentezlenen elektrotların karakterizasyonlarının yapılması için desteklerini esirgemeyen Atatürk Üniversitesi Doğu Anadolu Yüksek Teknoloji Araştırma Merkezi’ne de (DAYTAM) teşekkürlerimizi sunarız.
Dates

Application Date : April 20, 2020
Acceptance Date : October 15, 2020
Publication Date : December 30, 2020

APA Korkmaz, A , Çepni, E , Öztürk Doğan, H . (2020). Cr2O3 Nanoyapılarının Elektrokimyasal Sentezi ve Karakterizasyonu . Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi , 7 (2) , 994-1003 . DOI: 10.35193/bseufbd.723358