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Performance Modeling of the Fenton Process Used as a Single Unit for Treating Raw Textile Effluent

Year 2024, , 679 - 693, 03.10.2024
https://doi.org/10.21605/cukurovaumfd.1560112

Abstract

This study investigates the direct application of the Fenton Oxidation Process (FOP) to untreated textile wastewater, specifically from a woven fabric production facility. Under optimized conditions (pH 3, 0.7 g/L Fe+2, 2 mM H2O2), the process achieved significant removal efficiencies: 81% Chemical Oxygen Demand (COD), 80% Suspended Solids (SS), and 93% color removal. Artificial Neural Networks (ANN) and NARX-ANN were utilized in Matlab R2020a to model FOP performance, employing Levenberg-Marquardt (trainlm) and Scaled Conjugate Gradient (trainscg) algorithms. With a 9-20-3 network topology, the ANN model demonstrated superior predictive capability, achieving an R2 of 0.9843.

References

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  • 23. Ribeiro, J.P., Marques, C.C., Portugal, I., Nunes, M.I., 2020a. Fenton processes for AOX removal from a kraft pulp bleaching industrial wastewater: optimization of operating conditions and cost assessment. Journal of Environmental Chemical Engineering, 8(4), 104032.
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Ham Tekstil Atık Sularının Arıtılması İçin Tek Bir Ünite Olarak Kullanılan Fenton Prosesinin Performans Modellemesi

Year 2024, , 679 - 693, 03.10.2024
https://doi.org/10.21605/cukurovaumfd.1560112

Abstract

Bu çalışma, Fenton Oksidasyon Prosesinin (FOP) doğrudan arıtılmamış tekstil atık suyuna uygulanmasını, özellikle dokuma kumaş üretim tesisinden gelen atık suyu hedef alarak incelemektedir. Optimize edilmiş koşullar (pH 3, 0.7 g/L Fe+2, 2 mM H2O2) altında, proses %81 Kimyasal Oksijen İhtiyacı (KOİ), %80 Askıda Katı Madde (AKM) ve %93 renk giderimi gibi önemli verimlilikler sağlamıştır. FOP performansını modellemek amacıyla Matlab R2020a'da Yapay Sinir Ağları (YSA) ve NARX-YSA modelleri, Levenberg-Marquardt (trainlm) ve Ölçeklenmiş Eşlenik Gradyan (trainscg) algoritmaları kullanılarak oluşturulmuştur. 9-20-3 ağ topolojisine sahip YSA modeli, 0.9843 R2 değeri ile yüksek bir tahmin yeteneği göstermiştir.

References

  • 1. ABIT, 2018. Brazilian textile and apparel industry association. Brazilian Textile and Apparel Industry. Brasília, 44.
  • 2. Sher, F., Hanif, K., Iqbal, S.Z., Imran, M., 2020. Implications of advanced wastewater treatment: electrocoagulation and electroflocculation of effluent discharged from a wastewater treatment plant. Journal of Water Process Engineering, 33, 101101.
  • 3. Alkhagen, M., Samuelsson, Å., Aldaeus, F., Gimåker, M., Östmark, E., Swerin, A., 2015. Roadmap 2015 to 2025. Textile Materials from Cellulose. RISE–Research Institutes of Sweden.
  • 4. He, X., Qi, Z., Gao, J., Huang, K., Li, M., Springael, D., Zhang, X.X., 2020. Nonylphenol ethoxylates biodegradation increases estrogenicity of textile wastewater in biological treatment systems. Water Research, 184, 116137.
  • 5. Li, Y., Wang, Y., 2019. Double decoupling effectiveness of water consumption and wastewater discharge in china’s textile industry based on water footprint theory. PeerJ, 7, e6937.
  • 6. Antczak, A., Greta, M., Kopeć, A., Otto, J., 2019. Characteristics of the textile industry of two Asian powers: China and India. Prospects for Their Further Development on Global Markets. Fibers & Textiles in Eastern Europe.
  • 7. Mikac, L., Marić, I., Štefanić, G., Jurkin, T., Ivanda, M., Gotić, M., 2019. Radiolytic synthesis of manganese oxides and their ability to decolorize methylene blue in aqueous solutions. Applied Surface Science, 476, 1086-1095.
  • 8. Asgari, G., Shabanloo, A., Salari, M., Eslami, F., 2020. Sonophotocatalytic treatment of AB113 dye and real textile wastewater using ZnO/Persulfate: modeling by response surface methodology and artificial neural network. Environmental Research, 184, 109367.
  • 9. Jorfi, S., Pourfadakari, S., Kakavandi, B., 2018. A new approach in sono-photocatalytic degradation of recalcitrant textile wastewater using MgO@Zeolite nanostructure under UVA irradiation. Chemical Engineering Journal, 343, 95-107.
  • 10. Giwa, A., Yusuf, A., Balogun, H.A., Sambudi, N.S., Bilad, M.R., Adeyemi, I., Curcio, S., 2021. Recent advances in advanced oxidation processes for removal of contaminants from water: a comprehensive review. Process Safety and Environmental Protection.
  • 11. Doumic, L.I., Soares, P.A., Ayude, M.A., Cassanello, M., Boaventura, R.A., Vilar, V.J., 2015. Enhancement of a solar photo-fenton reaction by using ferrioxalate complexes for the treatment of a synthetic cotton-textile dyeing wastewater. Chemical Engineering Journal, 277, 86-96.
  • 12. Garrido-Cardenas, J.A., Esteban-García, B., Agüera, A., Sánchez-Pérez, J.A., Manzano-Agugliaro, F., 2020. Wastewater treatment by advanced oxidation process and their worldwide research trends. International Journal of Environmental Research and Public Health, 17(1), 170.
  • 13. Ma, S., Lee, S., Kim, K., Im, J., Jeon, H., 2021. Purification of organic pollutants in cationic thiazine and azo dye solutions using plasma-based advanced oxidation process via submerged multi-hole dielectric barrier discharge. Separation and Purification Technology, 255, 117715.
  • 14. Sampaio, E.F., Rodrigues, C.S., Lima, V.N., Madeira, L.M., 2021. Industrial wastewater treatment using a bubble photo-fenton reactor with continuous gas supply. Environmental Science and Pollution Research, 28(6), 6437-6449.
  • 15. Ribeiro, J.P., Marques, C.C., Portugal, I., Nunes, M.I., 2020b. AOX removal from pulp and paper wastewater by fenton and photo-fenton processes: a real case study. Energy Reports, 6, 770-775.
  • 16. Liu, R., Chiu, H.M., Shiau, C.S., Yeh, R.Y.L., Hung, Y.T., 2007. Degradation and sludge production of textile dyes by fenton and photo-fenton processes. Dyes and Pigments, 73(1), 1-6.
  • 17. Fenton, H.J.H., 1894. LXXIII-oxidation of tartaric acid in presence of iron. Journal of the Chemical Society, Transactions, 65, 899-910.
  • 18. Walling, C., 1975. Fenton's reagent revisited. Accounts of Chemical Research, 8(4), 125-131.
  • 19. Zhang, H., Choi, H.J., Huang, C.P., 2005. Optimization of fenton process for the treatment of landfill leachate. Journal of Hazardous Materials, 125(1-3), 166-174.
  • 20. Rodrigues, C.S., Neto, A.R., Duda, R.M., de Oliveira, R.A., Boaventura, R.A., Madeira, L.M., 2017. Combination of chemical coagulation, photo-fenton oxidation and biodegradation for the treatment of vinasse from sugar cane ethanol distillery. Journal of Cleaner Production, 142, 3634-3644.
  • 21. Barros, V.G., Rodrigues, C.S.D., Botello-Suarez, W.A., Dudu, R.M., Oliveira, R.A., Silva,E.S., Faria, J.L., Boaventura, R.A.R., Madeira, L.M., 2020. Treatment of biodigested coffee processing wastewater using fenton’s oxidation and coagulation/flocculation. Environmental Pollution, 259, 113796.
  • 22. Yu, X., Somoza-Tornos, A., Graells, M., Pérez-Moya, M., 2020. An experimental approach to the optimization of the dosage of hydrogen peroxide for fenton and photo-fenton processes. Science of the Total Environment, 743, 140402.
  • 23. Ribeiro, J.P., Marques, C.C., Portugal, I., Nunes, M.I., 2020a. Fenton processes for AOX removal from a kraft pulp bleaching industrial wastewater: optimization of operating conditions and cost assessment. Journal of Environmental Chemical Engineering, 8(4), 104032.
  • 24. Silva, L.G., Moreira, F.C., Cechinel, M.A.P., Mazur, L.P., de Souza, A.A.U., Souza, S.M.G.U., Vilar, V.J., 2020. Integration of fenton's reaction based processes and cation exchange processes in textile wastewater treatment as a strategy for water reuse. Journal of Environmental Management, 272, 111082.
  • 25. Elmolla, E.S., Chaudhuri, M., Eltoukhy, M.M., 2010. The use of artificial neural network (ANN) for modeling of COD removal from antibiotic aqueous solution by the fenton process. Journal of Hazardous Materials, 179(1-3), 127-134.
  • 26. Radwan, M., Alalm, M.G., Eletriby, H., 2018. Optimization and modeling of electro-fenton process for treatment of phenolic wastewater using nickel and sacrificial stainless steel anodes. Journal of Water Process Engineering, 22, 155-162.
  • 27. Talwar, S., Verma, A.K., Sangal, V.K., 2019. Modeling and optimization of fixed mode dual effect (photocatalysis and photo-fenton) assisted metronidazole degradation using ANN coupled with genetic algorithm. Journal of Environmental Management, 250, 109428.
  • 28. Gholizadeh, A.M., Zarei, M., Ebratkhahan, M., Hasanzadeh, A., 2021. Phenazopyridine degradation by electro-fenton process with magnetite nanoparticles-activated carbon cathode, artificial neural networks modeling. Journal of Environmental Chemical Engineering, 9(1), 104999.
  • 29. Baştürk, E., Alver, A., 2019. Modeling azo dye removal by sono-fenton processes using response surface methodology and artificial neural network approaches. Journal of Environmental Management, 248, 109300.
  • 30. Mohammadi, F., Bina, B., Karimi, H., Rahimi, S., Yavari, Z., 2020. Modeling and sensitivity analysis of the alkylphenols removal via moving bed biofilm reactor using artificial neural networks: comparison of levenberg marquardt and particle swarm optimization training algorithms. Biochemical Engineering Journal, 161, 107685.
  • 31. Ahmad, Z.U., Yao, L., Islam, F., Zappi, M.E., Gang, D.D., 2020. The use of artificial neural network (ANN) for modeling the adsorption of sunset yellow onto neodymium-modified ordered mesoporous carbon. Chemosphere, 256, 127081.
  • 32. Bousalah, D., Zazoua, H., Boudjemaa, A., Benmounah, A., Bachari, K., 2020. Degradation of indigotine food dye by fenton and photo-fenton processes. International Journal of Environmental Analytical Chemistry, 1-14.
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  • 41. Møller, M.F., 1993. A scaled conjugate gradient algorithm for fast supervised learning [J]. Neural Networks, 6(4), 525-534.
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There are 73 citations in total.

Details

Primary Language English
Subjects Environmental Engineering (Other)
Journal Section Articles
Authors

Selman Türkeş 0000-0001-6420-1002

Hakan Güney 0009-0003-6991-2569

Bülent Sarı 0000-0002-5171-9491

Olcayto Keskinkan 0000-0001-8995-756X

Publication Date October 3, 2024
Submission Date May 10, 2024
Acceptance Date September 27, 2024
Published in Issue Year 2024

Cite

APA Türkeş, S., Güney, H., Sarı, B., Keskinkan, O. (2024). Performance Modeling of the Fenton Process Used as a Single Unit for Treating Raw Textile Effluent. Çukurova Üniversitesi Mühendislik Fakültesi Dergisi, 39(3), 679-693. https://doi.org/10.21605/cukurovaumfd.1560112