Preparation, Characterization and İnvestigation of Swelling Behavior of HEMA-Based Amphiphilic Semi-IPN Cryogels Containing Polymeric Linoleic Acid

Cansu Meltem Gürel; Koray Şarkaya; Abdulkadir Allı

doi:10.29130/dubited.970641

TR EN

Polimerik Linoleik Asit Içeren HEMA Bazlı Amfifilik Yarı IPN Kriyojellerin Hazırlanması, Karakterizasyonu ve Şişme Davranışının Araştırılması

Abstract

Bu çalışmada, bitkisel yağ bazlı bir polimerik yağ asidi olan polimerik linoleik asit (PLina) ve yaygın olarak tercih edilen 2-hidroksietil metakrilat (HEMA) monomeri ile oluşturulacak yeni bir polimerik kriyojel sisteminin sentezlenmesi ve karakterize edilmesi amaçlanmıştır. Bu amaçla, öncelikle polimerik lineloik asit için sırasıyla otooksidasyon ve hidroksilasyon reaksiyonları gerçekleştirilmiştir. Hidroksillenmiş polimerik lineloik asit ve HEMA monomer, çapraz bağlayıcı olarak MBAA varlığında bir kriyojenik jelleşme reaksiyonuna tabi tutuldu. Elde edilen yeni kriyojeller, FTIR, SEM, BET, TGA analizleri ile karakterize edilmiştir. Sentezlenen PLinaOH-HEMA kriyojellerinin sudaki şişme davranışı kinetik çalışmalarla sonuçlandırılmıştır. Öte yandan, tüm kriyojellerin çözücü alımı için potansiyellerini görmek için araştırmak için bazı polar ve polar olmayan diğer çözücüler kullanıldı.

Keywords

Kriyojel, Amfifilik, Yarı-IPN, Polimerik lineloik asit

Project Number

2019.05.03.1024

Preparation, Characterization and İnvestigation of Swelling Behavior of HEMA-Based Amphiphilic Semi-IPN Cryogels Containing Polymeric Linoleic Acid

Abstract

In this study, it was aimed to synthesize and characterize a new polymeric cryogel system to be formed with polymeric linoleic acid (PLina), a vegetable oil-based polymeric fatty acid, and the widely preferred 2-hydroxyethyl methacrylate (HEMA) monomer. cryogels. For this purpose, firstly, autoxidation and hydroxylation reactions were carried out for polymeric lineloic acid, respectively. Hydroxylated polymeric lineloic acid (PLina-OH) and HEMA monomer were subjected to a cryogenic gelation reaction in the presence of N,N′-methylene bisacrylamide (MBAA) as crosslinking agent. The obtained new cryogel was characterized by FTIR, SEM, BET, TGA analyses. The swelling behavior of the synthesized PLinaOH-HEMA cryogels in water was concluded with kinetic studies. In the other hands, some of polar and non-polar other solvents was used for investigation of all cryogels to see their potentials for solvent uptake.

Keywords

Cryogel, Amphiphilic, Semi-IPN, Polimeric lineloic acid

Supporting Institution

Düzce University Scientific Research Projects

Project Number

2019.05.03.1024

Thanks

This study was supported by Düzce University Scientific Research Projects (Grant/Award Number: 2019.05.03.1024).

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Details

Primary Language

English

Subjects

Engineering

Journal Section

Research Article

Authors

Cansu Meltem Gürel This is me
0000-0003-3486-2074
Türkiye

Koray Şarkaya ^*
0000-0003-0177-5134
Türkiye

Abdulkadir Allı
0000-0002-7164-5629
Türkiye

Publication Date

January 31, 2022

Submission Date

July 13, 2021

Acceptance Date

July 29, 2021

Published in Issue

Year 2022 Volume: 10 Number: 1

DOI

https://doi.org/10.29130/dubited.970641

IZ

https://izlik.org/JA47NR83CH

APA

Gürel, C. M., Şarkaya, K., & Allı, A. (2022). Preparation, Characterization and İnvestigation of Swelling Behavior of HEMA-Based Amphiphilic Semi-IPN Cryogels Containing Polymeric Linoleic Acid. Duzce University Journal of Science and Technology, 10(1), 154-169. https://doi.org/10.29130/dubited.970641

AMA

1.Gürel CM, Şarkaya K, Allı A. Preparation, Characterization and İnvestigation of Swelling Behavior of HEMA-Based Amphiphilic Semi-IPN Cryogels Containing Polymeric Linoleic Acid. DUBİTED. 2022;10(1):154-169. doi:10.29130/dubited.970641

Chicago

Gürel, Cansu Meltem, Koray Şarkaya, and Abdulkadir Allı. 2022. “Preparation, Characterization and İnvestigation of Swelling Behavior of HEMA-Based Amphiphilic Semi-IPN Cryogels Containing Polymeric Linoleic Acid”. Duzce University Journal of Science and Technology 10 (1): 154-69. https://doi.org/10.29130/dubited.970641.

EndNote

Gürel CM, Şarkaya K, Allı A (January 1, 2022) Preparation, Characterization and İnvestigation of Swelling Behavior of HEMA-Based Amphiphilic Semi-IPN Cryogels Containing Polymeric Linoleic Acid. Duzce University Journal of Science and Technology 10 1 154–169.

IEEE

[1]C. M. Gürel, K. Şarkaya, and A. Allı, “Preparation, Characterization and İnvestigation of Swelling Behavior of HEMA-Based Amphiphilic Semi-IPN Cryogels Containing Polymeric Linoleic Acid”, DUBİTED, vol. 10, no. 1, pp. 154–169, Jan. 2022, doi: 10.29130/dubited.970641.

ISNAD

Gürel, Cansu Meltem - Şarkaya, Koray - Allı, Abdulkadir. “Preparation, Characterization and İnvestigation of Swelling Behavior of HEMA-Based Amphiphilic Semi-IPN Cryogels Containing Polymeric Linoleic Acid”. Duzce University Journal of Science and Technology 10/1 (January 1, 2022): 154-169. https://doi.org/10.29130/dubited.970641.

JAMA

1.Gürel CM, Şarkaya K, Allı A. Preparation, Characterization and İnvestigation of Swelling Behavior of HEMA-Based Amphiphilic Semi-IPN Cryogels Containing Polymeric Linoleic Acid. DUBİTED. 2022;10:154–169.

MLA

Gürel, Cansu Meltem, et al. “Preparation, Characterization and İnvestigation of Swelling Behavior of HEMA-Based Amphiphilic Semi-IPN Cryogels Containing Polymeric Linoleic Acid”. Duzce University Journal of Science and Technology, vol. 10, no. 1, Jan. 2022, pp. 154-69, doi:10.29130/dubited.970641.

Vancouver

1.Cansu Meltem Gürel, Koray Şarkaya, Abdulkadir Allı. Preparation, Characterization and İnvestigation of Swelling Behavior of HEMA-Based Amphiphilic Semi-IPN Cryogels Containing Polymeric Linoleic Acid. DUBİTED. 2022 Jan. 1;10(1):154-69. doi:10.29130/dubited.970641

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