Year 2021, Volume , Issue 21, Pages 669 - 679 2021-01-31

Asidik Ortamda Korozyon İnhibitörü Görevi Üstlenen Üç Pozitif Azot Atomu İçeren Tri-Katyonik Yüzey Aktif Maddelerin Sentezi

Serkan ÖZTÜRK [1] , Melek Meltem ÖZKAZANLI [2] , İlayda AKYILDIZ [3] , Tuğçe KARA [4] , Fatih ÇELİK [5]


Birçok endüstri dalının önemli sorunlarından birisi korozyondur. Özellikle metal endüstrisinde, metal yüzeyini deforme eder ve böylece metalik özelliklerinin kaybolmasına yol açar. Korozyonun bu olumsuz etkisine karşı, bu çalışmada, 1.0 M HCl ortamında meydana gelen metal korozyonunu önlemek için yapısında üç pozitif grup içeren tri-katyonik yüzey aktif maddeler sentezlenmiştir. Yapıları spektroskopik yöntemler (IR ve NMR) ile aydınlatıldıktan sonra bu bileşiklerin asidik korozif ortamda korozyon inhibisyon etkinlikleri kütle kaybı yöntemiyle incelenmiştir. Bunun için değişik konsantrasyonlarda inhibitör içeren korozif çözeltilere metal kuponlar oda sıcaklığında 24 saat süre ile daldırılmıştır. Yapılan korozyon testleri sonucu, sentezlenen yüzey aktif maddelerin düşük karbon çeliğinin asidik ortamdaki korozyonuna karşı çok etkin oldukları tespit edilmiştir. Korozyon inhibisyon mekanizması ile ilişkilendirmek için, sentezlenen tri-katyonik yüzey aktif maddelerin, kritik misel konsantrasyonu, yüzey gerilimi, misel oluşum serbest enerjisi gibi fizikokimyasal parametreleri hesaplanmıştır. Ayrıca, metal yüzeyini korozyona karşı koruduğunu desteklemek adına taramalı elektron mikroskobu (SEM) ile metal yüzeyi görüntüleri alınmıştır.
Sentez, Tri-katyonik yüzey aktif madde, Korozyon inhibitörü, HCl
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Primary Language tr
Subjects Engineering
Journal Section Articles
Authors

Orcid: 0000-0002-9396-1403
Author: Serkan ÖZTÜRK (Primary Author)
Institution: BURSA ULUDAĞ ÜNİVERSİTESİ, FEN-EDEBİYAT FAKÜLTESİ, KİMYA BÖLÜMÜ, ORGANİK KİMYA ANABİLİM DALI
Country: Turkey


Orcid: 0000-0003-3873-8310
Author: Melek Meltem ÖZKAZANLI
Institution: BURSA ULUDAĞ ÜNİVERSİTESİ, FEN-EDEBİYAT FAKÜLTESİ, KİMYA BÖLÜMÜ
Country: Turkey


Orcid: 0000-0002-7753-4612
Author: İlayda AKYILDIZ
Institution: BURSA ULUDAĞ ÜNİVERSİTESİ, FEN-EDEBİYAT FAKÜLTESİ, KİMYA BÖLÜMÜ
Country: Turkey


Orcid: 0000-0003-0664-0132
Author: Tuğçe KARA
Institution: BURSA ULUDAĞ ÜNİVERSİTESİ, FEN-EDEBİYAT FAKÜLTESİ, KİMYA BÖLÜMÜ
Country: Turkey


Orcid: 0000-0001-9142-3946
Author: Fatih ÇELİK
Institution: BURSA ULUDAĞ ÜNİVERSİTESİ, FEN-EDEBİYAT FAKÜLTESİ, KİMYA BÖLÜMÜ
Country: Turkey


Dates

Publication Date : January 31, 2021

APA Öztürk, S , Özkazanlı, M , Akyıldız, İ , Kara, T , Çelik, F . (2021). Asidik Ortamda Korozyon İnhibitörü Görevi Üstlenen Üç Pozitif Azot Atomu İçeren Tri-Katyonik Yüzey Aktif Maddelerin Sentezi . Avrupa Bilim ve Teknoloji Dergisi , (21) , 669-679 . DOI: 10.31590/ejosat.792128