Research Article
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Year 2022, Volume: 5 Issue: 1, 33 - 43, 31.03.2022
https://doi.org/10.35208/ert.1014814

Abstract

References

  • [1] A.K. Prajapati and P.K. Chaudhari, “Physicochemical treatment of distillery wastewater—a review”, Chemical Engineering Communications., Vol. 202(8), pp. 1098–1117, 2015.
  • [2] O. Sahu, B. Mazumdar, and P.K. Chaudhari, “Treatment of wastewater by electrocoagulation: a review”, Environmental Science and Pollution Research, Vol. 21(4), pp. 2397–2413, 2014.
  • [3] S. Tian, Y. Tu, J. Chen, G. Shao, Z. Zhou, and Z. Ren, “Persulfate enhanced electrochemical oxidation of phenol with CuFe2O4/ACF (activated carbon fibers) cathode”, Separation and Purification Technology, Vol. 279, 119727, 2021.
  • [4] B. S. Tawabini, K. V Plakas, M. Fraim, E. Safi, T. Oyehan, and A. J. Karabelas, “Assessing the efficiency of a pilot-scale GDE/BDD electrochemical system in removing phenol from high salinity waters”, Chemosphere, Vol. 239, pp. 124714, 2020.
  • [5] O.T. Can, “Fenol Çözeltisinin Farklı Elektrotlar Kullanılarak Elektrooksidasyonu”, Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, Vol. 9(2), pp. 952–957.
  • [6] Z. Isik, E. B. Arikan, Y. Ozay, H. D. Bouras and N. Dizge, “Electrocoagulation and electrooxidation pre-treatment effect on fungal treatment of pistachio processing wastewater”, Chemosphere, Vol. 244, pp 125383, 2020.
  • [7] Z. Pan, F. Yu, L. Li, M. Liu, C. Song, J. Yang, H. Li, C. Wanga, Y. Panb and T. Wang, “Electrochemical filtration carbon membrane derived from coal for wastewater treatment: Insights into the evolution of electrical conductivity and electrochemical performance during carbonization”, Separation and Purification Technology, Vol. 247, pp. 116948, 2020.
  • [8] L. Zhou, X. Yan, Y. Yan, T. Li, J. An, C. Liao, N. Li and X. Wang, “Electrode potential regulates phenol degradation pathways in oxygen-diffused microbial electrochemical system”, Chemical Engineering Journal, Vol. 381, pp. 122663, 2020.
  • [9] A.S. Fajardo, R.F. Rodrigues, R.C. Martins, L.M. Castro, and R.M. Quinta-Ferreira, “Phenolic wastewaters treatment by electrocoagulation process using Zn anode”, Chemical Engineering Journal, Vol. 275, pp. 331–341, 2015.
  • [10] E.S.Z. El-Ashtoukhy, Y.A. El-Taweel, O. Abdelwahab, and E.M. Nassef, “Treatment of petrochemical wastewater containing phenolic compounds by electrocoagulation using a fixed bed electrochemical reactor”, Int. J. Electrochem. Sci, Vol. 8(1), pp. 1534–1550, 2013.
  • [11] E. Bazrafshan, H. Biglari, and A.H. Mahvi, “Phenol removal by electrocoagulation process from aqueous solutions”, Fresenius Environmental Bulletin, Vol. 21(2), pp. 364–371, 2012.
  • [12] Y. Yavuz, A.S. Koparal, and Ü.B. Öğütveren, “Treatment of petroleum refinery wastewater by electrochemical methods”, Desalination, Vol. 258(1–3), pp. 201–205, 2010.
  • [13] M. Uğurlu, A. Gürses, Ç. Doğar, and M. Yalçın, “The removal of lignin and phenol from paper mill effluents by electrocoagulation”, Journal of Environmental Management, Vol. 87(3), pp. 420–428, 2008.
  • [14] Y. Yavuz and A.S. Koparal, “Electrochemical oxidation of phenol in a parallel plate reactor using ruthenium mixed metal oxide electrode”, Journal of Hazardous Materials, Vol. 136(2), pp. 296–302, 2006.
  • [15] N. Adhoum and L. Monser, “Decolourization and removal of phenolic compounds from olive mill wastewater by electrocoagulation”, Chemical Engineering and Processing - Process Intensification, Vol. 43(10), pp. 1281–1287, 2004.

Optimization of the effect of copper electrodes on the removal efficiency of 4-clorophenol from aqueous solution by electrocoagulation

Year 2022, Volume: 5 Issue: 1, 33 - 43, 31.03.2022
https://doi.org/10.35208/ert.1014814

Abstract

In this study, the investigation of 4-clorophenol (CP) removal from aqueous solutions using copper electrodes by electrocoagulation (EC) process was done. The effects of various experimental parameters such as pH, current density and exposure time, which affect the EC process, on 4-CP removal were investigated. To optimize the process, response surface methodology (RSM) Box Behnken Design was used by MINITAB program, a series of experimental sets were obtained and carried out. Afterward, 4-CP removal was analyzed and calculated. Results were entered into the MINITAB program as a response. At the end of the optimization, optimum operating conditions were determined as 74 mA/cm2, 45 min, 4.24 for current density, exposure times and pH, respectively. When the results were evaluated, approximately 92% phenol removal efficiencies were obtained. Additionally, according to the model results, it was understood that the factors with the greatest effect on 4-CP removal were the exposure time and current density and these had a linear effect, but the pH value did not have a significant effect.

References

  • [1] A.K. Prajapati and P.K. Chaudhari, “Physicochemical treatment of distillery wastewater—a review”, Chemical Engineering Communications., Vol. 202(8), pp. 1098–1117, 2015.
  • [2] O. Sahu, B. Mazumdar, and P.K. Chaudhari, “Treatment of wastewater by electrocoagulation: a review”, Environmental Science and Pollution Research, Vol. 21(4), pp. 2397–2413, 2014.
  • [3] S. Tian, Y. Tu, J. Chen, G. Shao, Z. Zhou, and Z. Ren, “Persulfate enhanced electrochemical oxidation of phenol with CuFe2O4/ACF (activated carbon fibers) cathode”, Separation and Purification Technology, Vol. 279, 119727, 2021.
  • [4] B. S. Tawabini, K. V Plakas, M. Fraim, E. Safi, T. Oyehan, and A. J. Karabelas, “Assessing the efficiency of a pilot-scale GDE/BDD electrochemical system in removing phenol from high salinity waters”, Chemosphere, Vol. 239, pp. 124714, 2020.
  • [5] O.T. Can, “Fenol Çözeltisinin Farklı Elektrotlar Kullanılarak Elektrooksidasyonu”, Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, Vol. 9(2), pp. 952–957.
  • [6] Z. Isik, E. B. Arikan, Y. Ozay, H. D. Bouras and N. Dizge, “Electrocoagulation and electrooxidation pre-treatment effect on fungal treatment of pistachio processing wastewater”, Chemosphere, Vol. 244, pp 125383, 2020.
  • [7] Z. Pan, F. Yu, L. Li, M. Liu, C. Song, J. Yang, H. Li, C. Wanga, Y. Panb and T. Wang, “Electrochemical filtration carbon membrane derived from coal for wastewater treatment: Insights into the evolution of electrical conductivity and electrochemical performance during carbonization”, Separation and Purification Technology, Vol. 247, pp. 116948, 2020.
  • [8] L. Zhou, X. Yan, Y. Yan, T. Li, J. An, C. Liao, N. Li and X. Wang, “Electrode potential regulates phenol degradation pathways in oxygen-diffused microbial electrochemical system”, Chemical Engineering Journal, Vol. 381, pp. 122663, 2020.
  • [9] A.S. Fajardo, R.F. Rodrigues, R.C. Martins, L.M. Castro, and R.M. Quinta-Ferreira, “Phenolic wastewaters treatment by electrocoagulation process using Zn anode”, Chemical Engineering Journal, Vol. 275, pp. 331–341, 2015.
  • [10] E.S.Z. El-Ashtoukhy, Y.A. El-Taweel, O. Abdelwahab, and E.M. Nassef, “Treatment of petrochemical wastewater containing phenolic compounds by electrocoagulation using a fixed bed electrochemical reactor”, Int. J. Electrochem. Sci, Vol. 8(1), pp. 1534–1550, 2013.
  • [11] E. Bazrafshan, H. Biglari, and A.H. Mahvi, “Phenol removal by electrocoagulation process from aqueous solutions”, Fresenius Environmental Bulletin, Vol. 21(2), pp. 364–371, 2012.
  • [12] Y. Yavuz, A.S. Koparal, and Ü.B. Öğütveren, “Treatment of petroleum refinery wastewater by electrochemical methods”, Desalination, Vol. 258(1–3), pp. 201–205, 2010.
  • [13] M. Uğurlu, A. Gürses, Ç. Doğar, and M. Yalçın, “The removal of lignin and phenol from paper mill effluents by electrocoagulation”, Journal of Environmental Management, Vol. 87(3), pp. 420–428, 2008.
  • [14] Y. Yavuz and A.S. Koparal, “Electrochemical oxidation of phenol in a parallel plate reactor using ruthenium mixed metal oxide electrode”, Journal of Hazardous Materials, Vol. 136(2), pp. 296–302, 2006.
  • [15] N. Adhoum and L. Monser, “Decolourization and removal of phenolic compounds from olive mill wastewater by electrocoagulation”, Chemical Engineering and Processing - Process Intensification, Vol. 43(10), pp. 1281–1287, 2004.
There are 15 citations in total.

Details

Primary Language English
Subjects Environmental Engineering
Journal Section Research Articles
Authors

Gulizar Kurtoglu Akkaya 0000-0003-4779-0428

Muhammed Kamil Öden 0000-0002-0573-5634

Publication Date March 31, 2022
Submission Date October 26, 2021
Acceptance Date January 4, 2022
Published in Issue Year 2022 Volume: 5 Issue: 1

Cite

APA Kurtoglu Akkaya, G., & Öden, M. K. (2022). Optimization of the effect of copper electrodes on the removal efficiency of 4-clorophenol from aqueous solution by electrocoagulation. Environmental Research and Technology, 5(1), 33-43. https://doi.org/10.35208/ert.1014814
AMA Kurtoglu Akkaya G, Öden MK. Optimization of the effect of copper electrodes on the removal efficiency of 4-clorophenol from aqueous solution by electrocoagulation. ERT. March 2022;5(1):33-43. doi:10.35208/ert.1014814
Chicago Kurtoglu Akkaya, Gulizar, and Muhammed Kamil Öden. “Optimization of the Effect of Copper Electrodes on the Removal Efficiency of 4-Clorophenol from Aqueous Solution by Electrocoagulation”. Environmental Research and Technology 5, no. 1 (March 2022): 33-43. https://doi.org/10.35208/ert.1014814.
EndNote Kurtoglu Akkaya G, Öden MK (March 1, 2022) Optimization of the effect of copper electrodes on the removal efficiency of 4-clorophenol from aqueous solution by electrocoagulation. Environmental Research and Technology 5 1 33–43.
IEEE G. Kurtoglu Akkaya and M. K. Öden, “Optimization of the effect of copper electrodes on the removal efficiency of 4-clorophenol from aqueous solution by electrocoagulation”, ERT, vol. 5, no. 1, pp. 33–43, 2022, doi: 10.35208/ert.1014814.
ISNAD Kurtoglu Akkaya, Gulizar - Öden, Muhammed Kamil. “Optimization of the Effect of Copper Electrodes on the Removal Efficiency of 4-Clorophenol from Aqueous Solution by Electrocoagulation”. Environmental Research and Technology 5/1 (March 2022), 33-43. https://doi.org/10.35208/ert.1014814.
JAMA Kurtoglu Akkaya G, Öden MK. Optimization of the effect of copper electrodes on the removal efficiency of 4-clorophenol from aqueous solution by electrocoagulation. ERT. 2022;5:33–43.
MLA Kurtoglu Akkaya, Gulizar and Muhammed Kamil Öden. “Optimization of the Effect of Copper Electrodes on the Removal Efficiency of 4-Clorophenol from Aqueous Solution by Electrocoagulation”. Environmental Research and Technology, vol. 5, no. 1, 2022, pp. 33-43, doi:10.35208/ert.1014814.
Vancouver Kurtoglu Akkaya G, Öden MK. Optimization of the effect of copper electrodes on the removal efficiency of 4-clorophenol from aqueous solution by electrocoagulation. ERT. 2022;5(1):33-4.