Çevresel Su Numunelerinde Eser Miktardaki Cu(II) İyonunun Seçici Spektrofotometrik Tayini

Year 2019, , 367 - 378, 24.03.2019

Berrin Topuz

https://doi.org/10.18185/erzifbed.469433

Abstract

Mikrokristal naftalin (MN)
üzerinde pH 3.0-8.0 aralığında potasyum 2,6-dimetilmorfolinditiyokarbamat
(KMDMMDTC) ligantı kullanılarak büyük hacimli sulu çözeltilerden Cu(II) iyonu
önderiştirilmiştir. Cu(II)-DMMDTC 
kompleksi içeren MN, 5 mL asetonda çözülerek Cu(II) iyonu kör çözeltiye
karşı 431 nm’de spektrofotometrik metot ile tayin edildi. pH, numune
çözeltisinin hacmi, DMMDTC yüklü MN miktarı, çalkalama süresi, yabancı iyon
etkisi gibi katı faz ekstraksiyon (SPE) metodunun temel parametreleri
incelendi. Aseton çözeltisinde 0,09 µgmL^-1 tayin sınırı ile lineer
kalibrasyon aralığı 0,05-5,0 µgmL^-1’dir. Sudaki potansiyel yabancı
iyonların etkisi araştırıldı ve önerilen metot ilaç ve çevresel numunelerden Cu(II) iyonunun tayini için
uygulanarak % 90 üzerinde geri kazanım değerleri elde edildi. Doğruluk,
sertifikalı referans madde NW-TMDA-70.2 analizi ve geri kazanım deneyleri ile
değerlendirildi.

Keywords

Potasyum-2-6-dimetilmorfolinditiyokarbamat, SPE metot, Eser Cu(II) tayini.

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