Çevresel Su Numunelerinde Eser Miktardaki Cu(II) İyonunun Seçici Spektrofotometrik Tayini

Berrin Topuz

doi:10.18185/erzifbed.469433

Çevresel Su Numunelerinde Eser Miktardaki Cu(II) İyonunun Seçici Spektrofotometrik Tayini

Abstract

Mikrokristal naftalin (MN) üzerinde pH 3.0-8.0 aralığında potasyum 2,6-dimetilmorfolinditiyokarbamat (KMDMMDTC) ligantı kullanılarak büyük hacimli sulu çözeltilerden Cu(II) iyonu önderiştirilmiştir. Cu(II)-DMMDTC kompleksi içeren MN, 5 mL asetonda çözülerek Cu(II) iyonu kör çözeltiye karşı 431 nm’de spektrofotometrik metot ile tayin edildi. pH, numune çözeltisinin hacmi, DMMDTC yüklü MN miktarı, çalkalama süresi, yabancı iyon etkisi gibi katı faz ekstraksiyon (SPE) metodunun temel parametreleri incelendi. Aseton çözeltisinde 0,09 µgmL^-1 tayin sınırı ile lineer kalibrasyon aralığı 0,05-5,0 µgmL^-1’dir. Sudaki potansiyel yabancı iyonların etkisi araştırıldı ve önerilen metot ilaç ve çevresel numunelerden Cu(II) iyonunun tayini için uygulanarak % 90 üzerinde geri kazanım değerleri elde edildi. Doğruluk, sertifikalı referans madde NW-TMDA-70.2 analizi ve geri kazanım deneyleri ile değerlendirildi.

Keywords

Potasyum-2-6-dimetilmorfolinditiyokarbamat,SPE metot,Eser Cu(II) tayini.

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Details

Primary Language

Turkish

Subjects

Engineering

Journal Section

Research Article

Authors

Berrin Topuz
Türkiye

Publication Date

March 24, 2019

Submission Date

October 11, 2018

Acceptance Date

March 14, 2019

Published in Issue

Year 2019 Volume: 12 Number: 1

DOI

https://doi.org/10.18185/erzifbed.469433

IZ

https://izlik.org/JA77CW47RZ

Cite

RIS / Bibtex

APA

Topuz, B. (2019). Çevresel Su Numunelerinde Eser Miktardaki Cu(II) İyonunun Seçici Spektrofotometrik Tayini. Erzincan University Journal of Science and Technology, 12(1), 367-378. https://doi.org/10.18185/erzifbed.469433

AMA

1.Topuz B. Çevresel Su Numunelerinde Eser Miktardaki Cu(II) İyonunun Seçici Spektrofotometrik Tayini. Erzincan University Journal of Science and Technology. 2019;12(1):367-378. doi:10.18185/erzifbed.469433

Chicago

Topuz, Berrin. 2019. “Çevresel Su Numunelerinde Eser Miktardaki Cu(II) İyonunun Seçici Spektrofotometrik Tayini”. Erzincan University Journal of Science and Technology 12 (1): 367-78. https://doi.org/10.18185/erzifbed.469433.

EndNote

Topuz B (March 1, 2019) Çevresel Su Numunelerinde Eser Miktardaki Cu(II) İyonunun Seçici Spektrofotometrik Tayini. Erzincan University Journal of Science and Technology 12 1 367–378.

IEEE

[1]B. Topuz, “Çevresel Su Numunelerinde Eser Miktardaki Cu(II) İyonunun Seçici Spektrofotometrik Tayini”, Erzincan University Journal of Science and Technology, vol. 12, no. 1, pp. 367–378, Mar. 2019, doi: 10.18185/erzifbed.469433.

ISNAD

Topuz, Berrin. “Çevresel Su Numunelerinde Eser Miktardaki Cu(II) İyonunun Seçici Spektrofotometrik Tayini”. Erzincan University Journal of Science and Technology 12/1 (March 1, 2019): 367-378. https://doi.org/10.18185/erzifbed.469433.

JAMA

1.Topuz B. Çevresel Su Numunelerinde Eser Miktardaki Cu(II) İyonunun Seçici Spektrofotometrik Tayini. Erzincan University Journal of Science and Technology. 2019;12:367–378.

MLA

Topuz, Berrin. “Çevresel Su Numunelerinde Eser Miktardaki Cu(II) İyonunun Seçici Spektrofotometrik Tayini”. Erzincan University Journal of Science and Technology, vol. 12, no. 1, Mar. 2019, pp. 367-78, doi:10.18185/erzifbed.469433.

Vancouver

1.Berrin Topuz. Çevresel Su Numunelerinde Eser Miktardaki Cu(II) İyonunun Seçici Spektrofotometrik Tayini. Erzincan University Journal of Science and Technology. 2019 Mar. 1;12(1):367-78. doi:10.18185/erzifbed.469433

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